Abstract
In situ cleaning of MOCVD-grown GaN/AlN/6H-SiC substrates using NH3-seeded supersonic molecular beams was investigated. Removal of surface carbon and oxygen contaminants was achieved by heating at 730°C under a hyperthermal NH 3 beam. Oxygen is removed primarily by thermal desorption; however, carbon removal requires an NH3 flux. Atomically smooth surfaces with regular steps are obtained after NH3 beam cleaning. Homoepitaxial growth of smooth, highly textured GaN films was accomplished at 700°C by employing a 0.61-eV NH3 beam and an effusive Ga source.
This is a preview of subscription content, access via your institution.
References
- 1.
D. A. Neumayer and J. G. Ekert, Chem. Mater. 8, 9 (1996).
- 2.
S. N. Mohammad and H. Morkoc, Prog. Quant. Electr. 20, 361 (1996).
- 3.
H. H. Lamb, K. K. Lai, V. Torres and R. F. Davis in Film Synthesis and Growth Using Energetic Beams, (Mater. Res. Soc. Proc. 388, 1995) pp. 265.
- 4.
J. J. Sumakeris, R. K. Chilukuri, R. F. Davis and H. H. Lamb in Gallium Nitride and Related Materials, (Mater. Res. Soc. Proc. 395, 1996) pp. 331.
- 5.
A. Sellidj, B. A. Ferguson, T. J. Mattord, B. G. Streetman and C. B. Mullins, Appl. Phys. Lett. 68, 3314 (1996).
- 6.
R. K. Chilukuri, S. Zhang, E. Chen, R. F. Davis and H. H. Lamb in III-V Nitride, (Mater. Res. Soc. Proc. 449, 1997) pp. 355.
- 7.
D. R. Miller, in Atomic and Molecular Beam Methods, edited by G. Scoles (Oxford University Press, 1988), p. 14.
- 8.
V. Torres, M. Meloni and R. B. Doak, (To be published).
- 9.
E. Bauer (personal communication).
- 10.
R. Held, D. E. Crawford, A. M. Johnston, A. M. Dabiran and P. I. Cohen, J. Electron Mater. 26, 272 (1997).
References
- 1
H. P. Maruska and J. J. Tietjen, Appl. Phys. Lett. 15, 327 (1969).
- 2
j. I. Pankove, E. A. Miller, and J. E. Berkeyheiser, RCA Rev. 32, 383 (1971).
- 3
H. M. Manasevit, F. M. Erdmann, and W. I. Simpson, J. Electrochem. Soc. 118, 1864 (1971)
- 4
I. Akasaki and I. Hayashi, Ind. Sci. Technolo. 17, 48 (1976) (in Japanese).
- 5
H. Amano, N. Sawaki, I. Akasaki, and Y. Toyoda, Appl. Phys. Lett. 48, 353 (1986).
- 6
S. Nakamura, J. J. Appl. Phys, 30, L1705 (1991).
- 7
M. A. Khan, J. N. Kuznia, J. M. Van Hove, N. Pan, and J. Carter, Appl. Phys. Lett. 60, 3027 (1992).
- 8
M. A. Khan, J. N. Kuznia, A. R. Bhattarai, and D. T. Olsen, Appl. Phys. Lett. 62, 1786 (1993).
- 9
M. A. Khan, A. R. Bhattarai, J. N. Kuznia, and D. T. Olsen, Appl. Phys. Lett. 63, 1214 (1993).
- 10
B. Gelmont, K. Kim, and M. Shur, J. Appl. Phys. 74, 1818 (1993).
- 11
S. C. Binari, L. B. Rowland, W. Kruppa, G. Kelner, K. Doverspike, and D. K. Gaskill, Electronics Lett. 30, 1248 (1994).
- 12
S. C. Binari, L. B. Rowland, G. Kelner, W. Kruppa, H. B. Dietrich, K. Doverspike, and D. K. Gaskill, in Compound Semiconductors 1994, eds. H. Goronkin and U. Mishra, (IOP Publishing, Bristol, 1995) p. 459.
- 12
M. A. Khan, J. N. Kuznia, D. T. Olsen, W. Schaff, J. Burm, and M. S. Shur, Appl. Phys. Lett. 65, 1121 (1994).
- 14
J. Pankove, S. S. Chang, H. C. Lee, R. J. Molnar, T. D. Moustakas, and B. Van Zeghbroeck, IEEE IEDM, San Francisco, CA, Dec 11-14, 1994, p. 389.
- 15
A. Ozgur, W. Kim, Z. Fan, A. Botchkarev, A. Salvador, S. N. Mohammad, B. Sverdlov, H. Morkoc, Electronics Lett. 31, 1389 (1995).
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Michel, A., Chen, E., Thomson, D. et al. Low-Temperature Homoepitaxial Growth of Gan Using Hyperthermal Molecular Beams. MRS Online Proceedings Library 512, 437–443 (1998). https://doi.org/10.1557/PROC-512-437
Published:
Issue Date: