Temperature Dependent Raman Scattering in CsTiOAsO4 Single Crystal

MRS Online Proceedings Library volume 398, pages661–666(1995)Cite this article

Abstract

The longitudinal (LO) and transverse (TO) A1 vibrational modes have been measured between 30-1200 cm−1 as a function of temperature (30–1240 K) for CsTiOAsO4 (CTA). The frequencies for all corresponding Raman components shifted to lower frequencies on increasing the temperature, however, there is no typical soft-mode like behavior observed in the measured frequency range. The relative intensities of the low frequency bands increase dramatically with increasing temperature due to high mobility of Cs+ ion. A higher symmetry structure taking place above 940K has been confirmed by changes in the phonon spectra.

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References

  1. 1

    G. Marnier, B. Boulanger and B. Menaert, J. Phys.: Condensed. Matter 1, 5509 (1989).

    CAS  Google Scholar 

  2. 2

    G.M. Loiacono, D.N. Loiacono and R.A. Stolzenberger, J. of Crystal Growth 131, 323 (1993).

    CAS  Article  Google Scholar 

  3. 3

    L.K. Cheng, L.-T. Cheng, J.D. Bierlein, F.C. Zumsteg and A.A. Ballman, Appl. Phys. Lett. 62, 346 (1993).

    CAS  Article  Google Scholar 

  4. 4

    J.D. Bierlein, H. Vanherzeele and A.A. Ballman, Appl. Phys. Lett. 54, 783 (1989).

    CAS  Article  Google Scholar 

  5. 5

    G.M. Loiacono, D.N. Loiacono, J.J. Zola R.A. Stolzenberger, T. McGee and R.G. Norwood, Appl. Phys. Lett. 61, 895 (1992).

    CAS  Article  Google Scholar 

  6. 6

    R. Farhi, P. Moch and R.V. Pisarev, Phase Tansitions 33, 65 (1991).

    CAS  Article  Google Scholar 

  7. 7

    G.E. Kugel, F. Bréhat, B. Wyncke, M.D. Fontana, G. Marnier, C. Carabatos and J. Mangin, J. Phys. C: Solid State Phys. 21, 5565 (1988).

    CAS  Article  Google Scholar 

  8. 8

    S. Furusawa, H. Hayasi, Y. Ishibashi, A. Miyamoto and T. Sasaki, J. of the Phys. Soc. of Jap. 60, 2470 (1991).

    CAS  Article  Google Scholar 

  9. 9

    G A. Kourouklis, A. Jayaraman and A.A. Ballman, Solid State Commun. 62, 379 (1987).

    CAS  Article  Google Scholar 

  10. 10

    Y.V. Shaldin and R. Poprawski, Ferroelectrics 106, 399 (1990).

    CAS  Article  Google Scholar 

  11. 11

    A.A. Ballman, H. Brown, D.H. Olson and CE. Rice, J. Cryst. Growth 75, 390 (1986).

    CAS  Article  Google Scholar 

  12. 12

    J.F Ryan, R.S. Katiyar and W. Taylor, Effet Raman Et Théorie, C2-49.

  13. 13

    D.L. Rousseau, R.P. Bauman and S.P.S. Porto, J. of Raman Spectroscopy 10, 253 (1981).

    CAS  Article  Google Scholar 

  14. 14

    G. Turrell, Infrared and Raman Spectra of Crystals, (Academic Press, 1972).

  15. 15

    P. Ayyub, M.S. Multani, V.R. Palkar and R. Viyayaraghavan, Phys. Rev. B 34, 8137 (1986).

    CAS  Article  Google Scholar 

  16. 16

    S. Sugai, Phys. Rev. B 35, 3621 (1987).

    Article  Google Scholar 

  17. 17

    G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules, (1975).

  18. 18

    V.C. Farmer, The Infrared Spectra of Minerals, (London, Mineralogical Soc, 1974).

    Google Scholar 

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Affiliations

  1. Department of Physics, University of Puerto Rico, Rio Piedras, PR, 00931-3343, USA

    A. R. Guo, Ruiwu Tao & R. S. Katiyar

  2. Department of Physics, Fu-Jen University, Taipei, Taiwan

    C.-S. Tu

  3. Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania, 16802, USA

    Ruyan Guo & A. S. Bhalla

Authors
  1. A. R. Guo
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  2. C.-S. Tu
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  3. Ruiwu Tao
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  4. R. S. Katiyar
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  5. Ruyan Guo
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  6. A. S. Bhalla
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Correspondence to A. R. Guo.

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Guo, A.R., Tu, CS., Tao, R. et al. Temperature Dependent Raman Scattering in CsTiOAsO4 Single Crystal. MRS Online Proceedings Library 398, 661–666 (1995). https://doi.org/10.1557/PROC-398-661

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