Abstract
The electrical bandgap of microcrystalline silicon (μc-Si:H) p type layers used in a-Si:H alloy solar cells and the band edge discontinuities between μc-Si:H and a-Si:H alloys have been determined by internal photoemission measurements. The bandgap of μc-Si:H is found to be in the range of 1.50 to 1.57 eV, and the discontinuities at the conduction and the valence band edges are 0 to 0.07 and 0.26 to 0.35 eV, respectively. Use of these parameters in the numerical simulation of single-junction a-Si:H and a-SiGe:H alloy solar cells is found to predict experimental results of solar cell performance.
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References
- 1.
J. Yang and S. Guha, Appl. Phys. Lett. 61, 2917 (1992).
- 2.
S. Guha, J. Yang, A. Banerjee, T. Glatfelter, K. Hoffinan, S. R. Ovshinsky, M. Izu, H. C. Ovshinsky, and X. Deng, Mat. Res. Soc. Symp. Proc. 336, 645 (1994).
- 3.
S. Guha, J. Yang, P. Nath, and M. Hack, Appl. Phys. Lett. 49, 218 (1986).
- 4.
F. Evangelisti, J. Non-Cryst. Solids 77&78, 969 (1985).
- 5.
H. Matsuura and H. Okushi, in Amorphous & Microcrystalline Semiconductor Devices, Vol. II, ed. by J. Kanicki, Artech House (1992), p. 517.
- 6.
H. Mimura and Y. Hatanaka, Appl. Phys. Lett. 50, 326 (1987).
- 7.
M. Cuniot and Y. Marfaing, Philos. Mag. B 57, 291 (1988).
- 8.
S. Guha et al., Final Report, SERI/TP-211-3918, National Renewable Energy Laboratory, Golden, Colorado, 1990.
- 9.
E. O. Kane, Phys. Rev. 127, 131(1962).
- 10.
S. Lee, J. K. Arch, S. J. Fonash, and C. R. Wronski, Proc. 21st IEEE PVSC, 1624(1990).
- 11.
I. Chen and C. R. Wronski, J. Non-Cryst. Solids, to be published.
- 12.
X. Xu, J. Yang, A. Banerjee, S. Guha, K. Vasanth, and S. Wagner, to be published.
- 13.
J. K. Arch, F. A. Rubinelli, J. Y. Hou, and S. J. Fonash, J. Appl. Phys. 69, 7057 (1991).
- 14.
A. Banerjee, X. Xu, J. Yang, and S. Guha, to be presented in this conference.
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Xu, X., Banerjee, A., Yang, J. et al. Band Discontinuity Effect on a-Si:H and a-SiGe:H Solar Cells. MRS Online Proceedings Library 377, 651–656 (1995). https://doi.org/10.1557/PROC-377-651
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