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Some Natural Three-and Lower-Dimensional Semiconductor Systems with Metal-Halide Units

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Abstract

The structural, optical and related properties (i.e. photoluminescence, photoconductivity etc.) of some natural three- and lower-dimensional semiconductor systems based on metal halides are briefly reviewed and some new results are reported. A blue shift of the excitonic bands was observed by decreasing the dimensionality or the size of the materials active part. The results are similar to those obtained from conventional semiconductor systems (e.g. GaAs, CdS, PbI2) by decreasing artificially the dimensionality or decreasing the size.

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References

  1. See for example C. Weisbuch and B. Vinter, Quantum Semiconductor Structures, (Acad.Press, London, 1991); D.S. Chemla, Physics Today, June 1993, p.46.

    Google Scholar 

  2. G.C. Papavassiliou, in Nanophase Materials, edited by G.C. Hadjipanayis and R.W. Siegel (Kluwer Acad. Publ., The Netherlands, 1994), p. 493.

  3. X. Zhang and M.G. Kanatzidis, J.Am.Chem.Soc. 116, 1890 (1994); Z.Zhang, M. Greenbaltt and J.B. Goodenough, J.Sol.St. Chem. 108, 402 (1994).

    Article  CAS  Google Scholar 

  4. G.C. Papavassiliou, in Mixed Valency Systems, edited by K. Prassides (Kluwer Acad. Publ., The Netherlands, 1991) p. 395; M.Shirai, Synth.Metals 55-57, 3389 (1993).

  5. G.C. Papavassiliou and I.B. Koutselas, Synth. Metals, in press (1995).

    Google Scholar 

  6. G.C. Papavassiliou, I. B. Koutselas, A. Terzis and M.-H. Whangbo, Sol.St.Commun. 91, 695 (1994).

    Article  CAS  Google Scholar 

  7. G.C. Papavassiliou, I.B. Koutselas, D.J. Lagouvardos, J. Kapoutsis, A. Terzis and G.I. Papaioannou, Mol. Cryst. Liq. Cryst., in press (1994).

    Google Scholar 

  8. G.C. Papavassiliou, I.B. Koutselas, and D.J. Lagouvardos, Z.Naturforsch. 48b, 1013 (1993).

    Article  Google Scholar 

  9. G.C. Papavassiliou, A.P. Patsis, D.J. Lagouvardos, and I.B. Koutselas, Synth. Metals 55–57, 3889 (1993).

    Article  Google Scholar 

  10. N.A. Gippius, E. A. Muljarov, S.C. Tikhodeev, T. Ishihara, and L.V. Keldysh, Mat.Res. Soc. Symp. Proc. 328, 775 (1994); J.Physique C5, 3,437(1993).

    Article  CAS  Google Scholar 

  11. X. Hong. T. Ishihara, and A.V. Nurmikko, Phys.Rev. B45, 6961 (1992).

    Article  Google Scholar 

  12. M. Era, S. Morimoto, T. Tsutsui, and S. Saito, Appl.Phys.Lett. 65, 676 (1994); Synth. Metals, in press (1995).

    Article  CAS  Google Scholar 

  13. M. Hirasawa, T. Ishihara and T. Goto, J. Phys. Soc. Jpn., in press.

  14. M. Hirasawa, T. Ishihara, T. Goto, K. Ushida and N. Miura, Physica B, in press.

  15. T. Kataoka, T. Kondo, R. Ito, S. Sasaki, K. Ushida and N. Miura, Physica B, in press.

  16. T. Ishihara, J.Lumin. 60–61, 269 (1994).

    Article  Google Scholar 

  17. D.B. Mitzi, C.A. Field, W.T.A. Harrison and A.M. Guloy, Nature 369, 467 (1994).

    Article  CAS  Google Scholar 

  18. T. Hiroshima and E. Hanamura, Nonlinear Optics, 1, 81 (1991).

    Google Scholar 

  19. J. Calabrese, N.L. Jones, R.L. Harlow, N. Herron, D.L. Thorn and X. Wang, J.Am.Chem.Soc. 113 2328 (1991).

    Article  CAS  Google Scholar 

  20. S.S. Nagapetyan, Y.I. Dolzhenko, E.R. Avakelova, V.M. Koskin, Y.T. Struchkov and V.E. Shklover, Russ.J.Inorg.Chem 33, 1614 (1988).

    Google Scholar 

  21. E.I. Zhilyaeva et al, Synth.Metals, in press.

  22. H. Arend, W. Huber, F.H. Mischgofsky and G.K.R. KanLeeuwen-, J.Cryst.Growth 43, 213 (1978).

    Article  CAS  Google Scholar 

  23. B.L. Evans in Optical and Electrical Properties edited by P.A. Lee, (D.Reidel Pub.Co, Dordrecht-Holland, 1976), p.2.

  24. A.S. Voloshinovskii, Phys.Sol.St. 35, 1588 (1994).

    Google Scholar 

  25. M. Fujita, H. Nakagawa, K. Fukui, H. Matsumoto, T. Miyanaga and M. Watanabe, J.Phys.Soc.Jpn. 60, 4393 (1991).

    Article  CAS  Google Scholar 

  26. LANDOLT-BÖRNSTEIN, Numerical Data and Functional Relationships in Science and Technology, New Series, edited by O. Madelung (Springer-Verlag, Berlin, 1982–1983) Vol. 17a-f.

  27. A.S. Voloshinovskii, S.V. Myagkota, N.S. Pidsyvailo, and Z.A. Khapko, Opt.Spectrosc. 52, 457 (1982).

    Google Scholar 

  28. K. Heidrich, H. KUnzel, and J. Treasch, Sol.St.Comm. 25, 887 (1978).

    Article  CAS  Google Scholar 

  29. H.J. Haupt, K. Heidrich, H. KUnzel and P. Mauersberger, Z. Physik. Chem.Neue Folge 110, 63 (1978).

    Article  CAS  Google Scholar 

  30. S.K. Bose, S. Satpathy, and O. Jepsen, Phys.Rev. B 47, 4276 (1993).

    Article  CAS  Google Scholar 

  31. B.R. Vincent, K.N. Robentson, T.S. Cameron, and O. Knop, Can.J.Chem. 65, 1042(1987); G.K.Möller, Kgl.Danske Videnskab Selsab Mat.- Fys.Medd. 32, 1 (1960).

    Article  CAS  Google Scholar 

  32. G.C. Papavassiliou, ref. 5 therein and unpublished results.

  33. K. Tang Zi, Y. Nozue, and T. Goto, J.Phys.Soc.Jpn. 61, 2943 (1982).

    Article  Google Scholar 

  34. C.J. Sandroff, D.M. Hwang and W.M. Chung, Phys.Rev. B 33, 5953(1986).

    Article  Google Scholar 

  35. E. Lifshitz, M. Yasen, K. Bykev, I. Dag and R. Chain, J.Phys.Chem. 98, 1459 (1994).

    Article  CAS  Google Scholar 

  36. T. Goto, S. Saito, and M. Tanaka, Sol.St.Commun. 80, 331 (1991).

    Article  CAS  Google Scholar 

  37. V. Mehretra, S. Lombardo, M. Thompson and E. Giannelis, Phys.Rev. B44, 5786 (1991).

    Article  Google Scholar 

  38. K. Oldenburg and A. Vogler, Z. Naturforsch. 48b, 1519 (1993).

    Article  Google Scholar 

  39. G.C. Papavassiliou and I.B. Koutselas Z.Naturforsch. 49b, 849 (1994).

    Article  Google Scholar 

  40. T. Kawai and S. Shimanuki, Phys.Stat.Sol. (b) 177, K43 (1993).

    Article  CAS  Google Scholar 

  41. J.A. Duffy in Bonding and Energy Levels and Bands in Inorganic Solids, (Longman Sci.Tech., New York, 1990), p.62.

    Google Scholar 

  42. T. Yoshinari, T. Nanba, S. Shimanuki, M. Fujisawa and K. Aoyagi, J.phys.Soc.Jpn. 61, 2224 (1992); G.C. Papavassiliou, unpublished results for (C6-2)2CuBr4.

    Article  CAS  Google Scholar 

  43. N. Watanabe, N. Kajima, T. Ban and I. Tsujikawa, J.Phys.C.Sol.St.Phys. 21, 4295 (1988).

    Google Scholar 

  44. T. Yoshinari, et al, J.Phys.Soc.Jpn. 58, 2276 (1989).

    Article  CAS  Google Scholar 

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Papavassiliou, G.C., Koutselas, I.B., Terzis, A. et al. Some Natural Three-and Lower-Dimensional Semiconductor Systems with Metal-Halide Units. MRS Online Proceedings Library 358, 283 (1994). https://doi.org/10.1557/PROC-358-283

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