Studies of Ultra Micro Indented Multilayered Sol-Gel Zirconia Films

Abstract

The deformation behavior of sol-gel derived zirconia films during ultra micro indentation has been investigated. The sol-gel films were deposited using a multiple stage coating procedure onto stainless steel substrates. The indentation process was carried out using both pointed indenters, such as a Berkovich, as well as spherical indenters. The use of different indenter types enables the determination of hardness, elastic modulus as well as the elastic-plastic or elastic-brittle transition of the films. The mechanical behavior of thin films is strongly influenced by the interaction between the substrate and the film. In brittle materials, the stress singularities induced by the indentation process cannot readily be reduced by long range plastic flow and may cause cracking. Therefore, a great deal of attention has been paid to post-indentation observations of the films, in particular examinations of the surface morphology for visible traces of the film behavior during indentation.

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References

  1. 1.

    L. L. Hench and J. K. West, Chemical Review, 33 (1990)

  2. 2.

    M. Shane and M. L. Mecartney, J. Mater. Sci., 25, 1537 (1990)

    CAS  Article  Google Scholar 

  3. 3.

    K. Izumi, M. Murakami, T. Deguchi, A. Morita, N. Touge and T. Minami, J. Am. Ceram. Soc, 8, 1465 (1989)

    Article  Google Scholar 

  4. 4.

    M. Ghanashyam Krishna, K. Marasimha Rao and S. Mohan, Thin Solid Films, 193/194 690 (1990)

    Article  Google Scholar 

  5. 5.

    B. D. Fabes and W. C. Oliver, J. Non-Cryst. Sol., 121, 348 (1990)

    CAS  Article  Google Scholar 

  6. 6.

    S.M. Melpolder, A. W. West and C. C. Bauer in Thin Films: Stresses and Mechanical properties III, edited by W. D. Nix, J.C. Bravman, E. Arzt and L. Ben Freud (Mater. Res. Soc. Proc. 239, Pittsburgh, PA, 1992)

  7. 7.

    M. Anast, J. M. Bell, T. M. Bell and B. Ben-Nissan, J. Mater. Sci. Lett., 11, 1483 (1992)

    CAS  Article  Google Scholar 

  8. 8.

    T. J. Bell, J. S. Field and M. V. Swain, Thin Solid Films, 220, 289 (1992)

    Article  Google Scholar 

  9. 9.

    W. C. Oliver and G. M. Pharr, J. Mater. Res. 7, 1564 (1992)

    CAS  Article  Google Scholar 

  10. 10.

    P.J. Burnett and D. S. Rickerby, Thin Solid Films, 148, 51 (1987)

    CAS  Article  Google Scholar 

  11. 11.

    J. L. Loubet, J. M. Georges and P. Kapsa, in Mechanics of Coatings, edited by. D. Dowson, C. M. Taylor and M. Godet (Elsevier, Amsterdam, 1990) p 429

    Google Scholar 

  12. 12.

    J. B. Davis, H. C. Cao, G. Bao and A. G. Evans, Acta Metall. Mater., 39, 1019 (1991)

    CAS  Article  Google Scholar 

  13. 13.

    E. R. Weppelmann, X.-Z. Hu and M.V. Swain, J. Adhesion Sci. Tech., 8, 1 (1994)

    Article  Google Scholar 

  14. 14.

    T. F. Page and S. V. Hainsworth, Surf. Coat. Tech., 61, 201 (1993)

    CAS  Article  Google Scholar 

  15. 15.

    L. Spiccia, B. O. West, J. Cullen, D. de Villiers, I. Watkins, J. M. Bell, B. Ben-Nissan, M. Anast, and G. R. Johnston, in Proc. AustCeram 90, edited by P. Darragh and R. Stead (Perth, WA, 1990) p 445

  16. 16.

    J. C. Debsikar, J. Non-Cryst. Sol., 87, 343 (1986)

    Article  Google Scholar 

  17. 17.

    A. Aronne, P. Pernice and A. Marotta, J. Mater. Sci. Lett., 10, 1136 (1991)

    CAS  Article  Google Scholar 

  18. 18.

    R. Srinivasan, R. J. De Angelis, G. Ice and B. H. Davis, J. Mater.Res., 6, 1267 (1991)

    Article  Google Scholar 

  19. 19.

    B. Ben-Nissan, M. Anast, J. M. Bell, G. R. Johnston, B. O. West, L. Spiccia, D. de Villiers and I. Watkins, in Proc. 1st Int. Symp. on the Science of Eng. Ceramics, edited by S. Kimura and K. Niihara (The Ceramic Society of Japan, 1991) p 25

  20. 20.

    J. M. Bell, R. W. Cheary, M. Rice, B. Ben-Nissan, J. L. Cocking and G. R. Johnston, in Ceramics: Adding the value. Volume 1, edited by M. J. Bannister, (CSIRO Publ., Melbourne, 1992) p 765

  21. 21.

    T. J. Bell, A. Bendeli, J. S. Fields, M. V. Swain and E. Thwaite, Metrologia, 28, 463 (1991-1992)

    Article  Google Scholar 

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Correspondence to Å. Jômting.

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Jômting, Å., Ben-Nissan, B., Ashcroft, I. et al. Studies of Ultra Micro Indented Multilayered Sol-Gel Zirconia Films. MRS Online Proceedings Library 356, 711–716 (1994). https://doi.org/10.1557/PROC-356-711

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