Pillaring of Layered Double Hydroxides With Cage-Like Polysilicates: a Possible New Class of Base Catalysts or Catalyst Precursors

Abstract

Pillaring of highly basic layered double hydroxides (MgnAl(OH)2n+2Cl, n=2-5) with octameric polysilicate (Si8O208-) has been achieved via a direct ion exchange route.

This is a preview of subscription content, access via your institution.

References

  1. 1.

    F. Cavani, F. Trifiro and A. Vaccari, Catalysis Today 11, 173 (1991).

    CAS  Article  Google Scholar 

  2. 2.

    W.T. Reichle, Chemtech. 58 (1986).

  3. 3.

    A. De Roy, C. Forano, K. El Malki and J.-P. Besse, in Synthesis of Microporous Materials Vol. II;. edited by M.L. Occelli and H. Robson (Van Nostrand Reinhold, New York, 1992), pp. 108–169.

  4. 4.

    W. Jones and M. Chibwe, in Pillared Layered Structures, edited by I.V. Mitchell (Elsevier Applied Science, London, 1990), pp. 67–77.

  5. 5.

    T. J. Pinnavaia, T. Kwon and S.K. Yun, NATO ASI Series, Ser. C. 352, 91 (1992).

    CAS  Google Scholar 

  6. 6.

    G. Engelhardt and D. Michel, High-Resolution Solid-State NMR of Silicates and Zeolites. (John Wiley & Sons, Chichester, 1987), pp. 75–105.

    Google Scholar 

  7. 7.

    Yu.I. Smolin, Yu.F. Shepelev, R. Pomes, D. Hoebbel and W. Wieker, Sov. Phys. Crystallogr. 24, 19 (1979)

    Google Scholar 

  8. 7a.

    M. Wiebcke, M. Grube, H. Koller, G. Engelhardt and J. Felsche, J. Microporous Mater. 2, 55 (1993).

    CAS  Article  Google Scholar 

  9. 8.

    M.D. Drezdon, Inorg. Chem. 27, 4628 (1988).

    Article  Google Scholar 

  10. 9.

    W.T. Reichle, J. Cat 94, 547 (1985)

    CAS  Article  Google Scholar 

  11. 9a.

    C.P. Kelkar, A. Schutz and G. Marcelin, in Perspectives in Molecular Sieve Science, edited by W.F. Flank and T.E. Whyte Jr., (ACS, Washington, 1988), pp. 324–334.

Download references

Author information

Affiliations

Authors

Corresponding author

Correspondence to Colin A. Fyfe.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Fyfe, C.A., Fu, G. & Grondey, H. Pillaring of Layered Double Hydroxides With Cage-Like Polysilicates: a Possible New Class of Base Catalysts or Catalyst Precursors. MRS Online Proceedings Library 346, 907–914 (1994). https://doi.org/10.1557/PROC-346-907

Download citation