Thickness Effect on the Crystallization Kinetics of Electrolessly-Deposited Ni(P) Thin Films


In order to understand thickness and interfacial effects on the crystallization kinetics of amorphous solids, Ni(P) thin films electrolessly deposited on Cu seed layers were annealed at constant heating rates or at constant temperatures in a DSC to obtain activation energies and Avrami exponents. It was found that the activation energy of crystallization in Ni(P) changes as a function of sample thickness when the sample thickness is less than 1.0 μm. Furthermore, the Avrami exponent was found to change not only as a function of thickness but also as a function of annealing temperature.

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  1. 1.

    M.S. Grewal, S.A. Sastri, and B.H. Alexander, Thermochimica Acta, 14, 25 (1976).

    CAS  Article  Google Scholar 

  2. 2.

    M.W. Mahoney and P.J. Dynes, Scripta Metall., 19, 539 (1985).

    CAS  Article  Google Scholar 

  3. 3.

    I. Bakonyi, A. Cziraki, I. Nagy and M. Hosso, Z. Metallkd., 77, 425 (1986).

    CAS  Google Scholar 

  4. 4.

    E. Ma, S. Lu, and P. Li, Thin Solid Films, 166, 273 (1988).

    CAS  Article  Google Scholar 

  5. 5.

    A. Szasz, X.D. Pan, J. Kojnok, and D.J. Fabian, J. Non-Cryst. Solids, 108, 304 (1989).

    CAS  Article  Google Scholar 

  6. 6.

    K.L. Lin and P.J. Lai, J. Electrochem. Soc., 136, 3803 (1989).

    CAS  Article  Google Scholar 

  7. 7.

    R.C. Agarwala and S. Ray, Z. Metallkd., 80, 556 (1989).

    CAS  Google Scholar 

  8. 8.

    R.C. Agarwala and S. Ray, Z. Metallkd., 83, 203 (1992).

    CAS  Google Scholar 

  9. 9.

    A.H. Graham, R.W. Lindsay, and H.J. Read, J. Electrochem. Soc., 112, 401 (1965).

    CAS  Article  Google Scholar 

  10. 10.

    J.P. Randin, P.A. Maire, E. Saurer, and H.E. Hintermann, J. Electrochem. Soc., 114, 442 (1967).

    CAS  Article  Google Scholar 

  11. 11.

    H.E. Kissinger, Anal. Chem., 29, 1702 (1957).

    CAS  Article  Google Scholar 

  12. 12.

    T. Ozawa, J. Thermal Analysis, 2, 301 (1970).

    CAS  Article  Google Scholar 

  13. 13.

    E. Ma and C.V. Thompson, J. Appl. Phys., 69, 2211 (1991).

    CAS  Article  Google Scholar 

  14. 14.

    K.N. Tu, Appl. Phys. A, 53, 32 (1991).

    Article  Google Scholar 

  15. 15.

    J.W. Christian, The Theory of Transformation in Metals and Alloys, 2nd ed. (Pergamon, Oxford, 1975).

    Google Scholar 

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The authors would like to thank J.R. Marino for plating some of the Ni(P) films used, M. Plechaty for determining the composition of the Ni(P) material, K.N. Tu for inspiring and useful disussions, and L.T. Romankiw for a review of the manuscript.

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Correspondence to L.T. Shi.

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Shi, L., O’Sullivan, E. Thickness Effect on the Crystallization Kinetics of Electrolessly-Deposited Ni(P) Thin Films. MRS Online Proceedings Library 321, 319–324 (1993).

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