Skip to main content
Log in

Infrared Spectra of Ultra-Thin SiO2 Grown on Si Surfaces

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

The structure of thin SiO2 films thermally grown on Si(100)and Si(111) surfaces has been characterized by using infrared internal reflection and x-ray photoelectron spectroscopy. It is found that the infrared absorption peak due to the LO phonon mode originating from the Si-O-Si stretching vibration shows a considerable red shift in the thickness range below 30Å. This red shift is interpreted in terms of the compressive stress near the interface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. J. Grunthaner, P. J. Grunthaner, R. P. Vasqueg, B. F. Lewis and J. Maserjian, Phys. Rev. Let. 43 (1979) 1683.

    Article  CAS  Google Scholar 

  2. T. Hattori and T. Suzuki, Appl. Phys. Lett. 43 (1983) 470.

    Article  CAS  Google Scholar 

  3. C. R. Helms, Y F. Strausser and W. E. Spicer, Appl. Phys. Lett. 33 (1978) 767.

    Article  CAS  Google Scholar 

  4. A. Ourmazd, D. W. Taylor, J. A. Rentchlerand J. Bevk, Phys. Rev. Lett. 59 (1987) 213.

    Article  CAS  Google Scholar 

  5. G. Lucovsky, J. T. Fitch, E. Kobeda and E. A. Irene, “The Physics and Chemistry of SiO2 and the Si-SiO2 interface” ed. by C. R. Helms and B. E. Deal (Plenum Press, New York, 1988) p.139.

  6. J. E. Olsen and F. Shimura, J. Appl. Phys. 66 (1989) 1353.

    Article  CAS  Google Scholar 

  7. I. W. Boyd and I. B. Wilson, J. Appl. Phy. 62 (1987) 3195.

    Article  CAS  Google Scholar 

  8. B. Nielsen, K. G. Lynn, D. O. Welch, T. C. Leung and G. W Rubloff, Phys. Rev. B 40 (1989) 1434.

    Article  CAS  Google Scholar 

  9. For example, “The Physics and Chemistry of SiO2 and the Si-SiO2 interface 2” ed. by C. R. Helms and B. E. Deal (Plenum Press, New York, 1993) p.91.

  10. A. Ishizaka, S. Iwata and Y. Kamigaki, Surf. Sci. 84 (1979) 355.

    Article  CAS  Google Scholar 

  11. S. W. de Leeuw and M. F. Thorpe, Phy. Rev. Lett. 55 (1985) 2879.

    Article  Google Scholar 

  12. J. D. E. McIntyre and D. E. Aspnes, Surface Science. 24 (1971) 417.

    Article  CAS  Google Scholar 

  13. C. H. Bjorkman, T. Yamazaki, S. Miyazaki and M. Hirose, Proc. of Intern. Conf. on Advanced Microelectronic Devices and Processing (Sendai, 1994) to be published.

  14. “Handbook of Optical Constants of Solid” ed. by E. D. Palik (Academic Press, Orlando, 1985).

    Google Scholar 

  15. F. L. Galeener, Phys. Rev. B 19 (1979) 4292.

    Article  CAS  Google Scholar 

  16. G. S. Higashi, Y.J. Chabal, G. W. Trucks and Krishnan Raghavachari, Appl. Phy. Lett. 56(1990) 656.

    Article  CAS  Google Scholar 

  17. S. Watanabe, N. Nakaymaand T. Ito, Appl. Phys. Lett. 59 (1991) 1458.

    Article  CAS  Google Scholar 

  18. K. Sawara, T. Yasaka, S. Miyazaki and M. Hirose, Jpn. Appl. Phys. 31 (1992) L1992.

    Article  Google Scholar 

  19. M. Fukuda, T. Yamazaki, S. Miyazaki and M. Hirose, Proc. of Intern. Conf. on Advanced Microelectronic Devices and Processing (Sendai, 1994) to be published.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yamazaki, T., Miyazaki, S., Bjorkman, C.H. et al. Infrared Spectra of Ultra-Thin SiO2 Grown on Si Surfaces. MRS Online Proceedings Library 318, 419–424 (1993). https://doi.org/10.1557/PROC-318-419

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-318-419

Navigation