Abstract
Atomic processes at the interface in regrowth following laser induced melting were investigated by observing behavior of impurity segregation. The interfacial segregation coefficient k* was obtained from depth profiles of solute atoms redistributed by laser irradiation of uniformly doped Si, Ge, and GayAl1−y As crystals. It was found that k*=k0 for B in Si, Ga in Ge in the growth rate range of 1 m/s. It is concluded that rapid growth freezes a state of liquid monolayer adjacent to the interface which has the character of ideal solution from dilute to eutectic composition for dopant-silicon systems and in the entire range of composition for the mixed crystal.
This is a preview of subscription content, access via your institution.
References
- 1
S.U. Campisano, Appl. Phys. A30, 195 (1983).
- 2
J. Chikawa and F. Sato, Jpn. J. Appl. Phys. 19, L577 (1980).
- 3
J. Chikawa, F. Sato and T. Sunada, Materials Letters, to be published.
- 4
V.G. Smith, W.A. Tiller and J.W. Rutter, Can. J. Phys. 33, 723 (1955).
- 5
H.R. Huff, T.G. Digges, Jr. and O.B. Cecil, J. Appl. Phys. 42, 1235 (1971).
- 6
P. Baeri, G. Foti, J.M. Poate, S.U. Compisano and A.G. Cullis, Appl. Phys. Lett. 38, 800 (1981).
- 7
M.B. Panish and M. Ilegems, Progress in Solid State Chemistry Vol. 7 (Oxford University Press, 1972) p. 39.
- 8
B. Giessen and R. Vogel, Z. Metallkd. 50, 274 (1959).
- 9
C.D. Thurmond and M. Kowalchik, Bell System Tech. J. 39, 169 (1960).
- 10
N. Natsuaki, M. Tamura, and T. Tokuyama, J. Appl. Phys. 51, 3373 (1980).
- 11
C.W. White, B.R. Appleton, B. Stritzker, D.M. Zehner and S.R. Wilson, Laser and Electron-Beam Solid Interactions and Materials Processing, edited by J.F. Gibbons, L.D. Hess and T.W. Sigmon (North Holland, New York, 1981) p. 59.
- 12
F.A. Trumbore, Bell System Tech. J. 39, 205 (1960).
- 13
J.W. Cahn, S.R. Coriell, and W.J. Boettinger, Laser and Electron Beam Processing of Materials, edited by C.W. White and P.S. Peercy (Academic Press, New York, 1980), p. 89.
- 14
J. Narayan, J. Appl. Phys. 52, 1289 (1981).
Author information
Affiliations
Rights and permissions
About this article
Cite this article
Chikawa, Ji., Sato, F. & Sunada, T. Concentration-Independent Solute Segregation in Laser Annealing of Semiconductor Crystals. MRS Online Proceedings Library 23, 193–198 (1983). https://doi.org/10.1557/PROC-23-193
Published:
Issue Date: