Abstract
The c-axis sound velocities and attenuations for HOPG, stage 3 and stage 4 SbCl5-graphite were determined by ultrasonic techniques in the temperature range between 4 and 325 °K. The temperature variation of C33 for HOPG agrees closely with the theoretical prediction based on the Lennard-Jones interlayer potential. In SbCl5-graphite, the longitudinal sound attenuation increases sharply and the transverse sound cannot propagate for temperatures above 200 °K, indicating a commensurate-to-incommensurate in-plane phase transition. The stage dependence of C33 at low temperatures indicates that the interlayer forces beyond the nearest layers can not be neglected.
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References
O. L. Blakslee, D. G. Proctor, E. J. Seldin, G. B. Spence and T. Weng, J. Appl. Phys. 41, 3373 (1970).
W. B. Gauster, Phil. Mag. 25, 687 (1972).
J. F. Green, P. Bolsaitis and I. L. Spain, J. Phys. Chem. Solids 34, 1927 (1973).
W. B. Gauster, and I. J. Fritz, J. Appli. Phys. 45, 3309 (1974).
B. T. Kelly and M. J. Duff, Carbon 8, 77 (1970).
J. F. Green and I. L. Spain, J. Phys. Chem. Solids 34, 2177 (1973).
J.F. Green and I.L. Spain, Phys. Rev. B11, 3935 (1975); J.B. Ayasse, C. Ayache, B. Jager, E. Bonjour and I.L. Spain, Solid State Comm. 29, 659 (1979).
B. T. Kelly, Carbon 12, 535 (1974).
W. D. Ellenson, D. Semmingsen, D. Guerard, D. G. Onn and J. E. Fischer, Mat. Sci. Eng. 31, 137 (1977).
J. Rossat-Mignod, D. Fruchart, M. J. Moran, J. W. Milliken and J. E. Fischer, Synthetic Metals 2, 143 (1980).
H. Zabel and A. Magerl, Phys. Rev. B25, 2463 (1982).
J.D. Axe, C.F. Majkrzak, L. Passell, S.K. Satija, G. Dresselhaus and H. Mazurek, in Extended Abstract of the 15th Biennial Conference on Carbon (Pennsylvania State Univ., 1981), p. 52; G. Dresselhaus, R. Al-Jishi, J.D. Axe, C.F. Majkrzak, L. Passell and S.K. Satija, Solid State Commun. 40, 229 1981).
N. Wada, Phys. Rev. B 24, 1065 (1981).
D. M. Hwang, B. F. O’Donnell and A. Y. Wu, in Physics of Intercalation Compounds, ed. by L. Pietronero and E. Tossatti (Springer, Berlin, 1981), p. 193.
G. L. Peterson, B. Chick and W. Junker, Ultrasonic Symposium Proceedings, IEEE Cat. #75 CHO 994-45U (1975).
S. E. Hardcastle and H. Zabel, J. de Physique C 6, 326 (1981).
A. C. Bailey and B. Yates, J. Appl. Phys. 41, 5088 (1970).
E. P. Papadakis, J. Acoust. Soc. Amer. 42, 1046 (1967).
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Hwang, D.M. Ultrasonic Velocity Studies of Graphite and Its Intercalation Compounds. MRS Online Proceedings Library 20, 295 (1982). https://doi.org/10.1557/PROC-20-295
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DOI: https://doi.org/10.1557/PROC-20-295