Metallo-Organics Derived Tractable Resins for Ybco Superconducting Fiber Fabrication


Soluble resins were prepared by controlled hydrolysis of yttrium isopropoxide, barium isopropoxide and copper ethylhexanoate. The resins were converted to cohesive, viscous, fluid and precipitated states by the addition of different combinations of binary polar and non-polar organic solvents. Viscosity and spinnability of the resins were critically dependent on the solvent constituents. Continuous pre-ceramic fibers were spun from these resins and single phase YBa2Cu3Oy superconducting fibers with Tc=91.5K and ΔT=1.5K have been obtained.

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  1. 1.

    T. Goto and M. Kada, J. Mater. Res. 3, 1292 (1988).

    CAS  Article  Google Scholar 

  2. 2.

    R. Enomoto et al., Japan. J. Appl. Phys. 28, L1207 (1989).

    CAS  Article  Google Scholar 

  3. 3.

    T. Umeda, H. Kozuka, and S. Sakka, Advanced Ceramic Materials 3, 520 (1988)

    CAS  Article  Google Scholar 

  4. 4.

    J. C. W. Chien et al, Phys. Rev B 38, 11–835 (1988).

    Google Scholar 

  5. 5.

    H. Konishi, T. Takamura, H. Kaga and Katsuse, Japan. J. Appl. Phys. 28, L241 (1989).

    CAS  Article  Google Scholar 

  6. 6.

    F. Uchikawa and J. D. Mackenzie, J. Mater. Res. 4, 787 (1989).

    CAS  Article  Google Scholar 

  7. 7.

    M. W. Rupich, S. F. Cogan, B. Lagos and J. P. Hachey, Mater Res. Soc. Meeting, Fall 1989 Boston, MA, USA (to be published in MRS Proceeding).

  8. 8.

    K. C. Chen and K. S. Mazdiyasni, Mater. Res. Soc. Meeting, Fall 1989, Boston, MA. (to be published in MRS Proceeding).

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Correspondence to K. C. Chen.

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Chen, K.C., Chen, A.Y. & Mazdiyasni, K.S. Metallo-Organics Derived Tractable Resins for Ybco Superconducting Fiber Fabrication. MRS Online Proceedings Library 180, 913 (1990).

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