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The use of Soluble Metal-Polyselenide Complexes as Precursors to Binary and Ternary Solid Metal Selenides

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Abstract

The use of several soluble metal polychalcogenides to prepare solid state materials is presented. Thermal gravimetric analysis (TGA) data, under inert atmosphere, of the molecular compounds (Ph4P)2[Cd(Se4)2], (Ph4P)4[Cu2Se14], (Ph4P)2[Cu4Se12], (Ph4P)4[In2Se21] and (Et4N)3[M3Se15], (M=In, TI), show that the corresponding binary solid state compounds are formed as single phases at temperatures as low as 530°C. We have grown films of CdSe, Cu2-xSe, β-In2Se3, TISe and CuInSe2 using these complexes as precursors. The films were prepared by pyrolysis of green precursor films, cast from DMF solutions. CuInSe2 was prepared by co-thermolysis of Cu/Sex and In/Sex complexes. The chemical, X-ray, spectroscopic and electron microscopic characterization of these molecular precursor-derived films as well as their charge transport characterization is reported.

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References

  1. Fan, G.; Williams, J. O. J. Chem. Soc. Faraday Trans. 1987, 83, 323–338

    Article  CAS  Google Scholar 

  2. (a) Smith, R.A. in “Semiconductors” pp. 438, Cambridge University Press, 1978. (b) Bartlett, B.E. et al. Infrared Phys. 1969, 9, 35.

  3. Kun, Z. K. Solid State Technology 1988, 31, 77–79.

    CAS  Google Scholar 

  4. Ballman, A.A.; Byer, R.L.; Eimerl, D.; Feigelson, R.S.; Feldman, B.J.; Goldberg, L.S.; Menyuk, N.; Tang, C.L. Applied Optics 1987, 26, 224–227.

    Article  CAS  Google Scholar 

  5. (a) Mickelsen, R.A.; Chen, W.S. in “Ternary and Multinary Compounds,” Proceedings of the 7th Conference, Deb, S.K. and Zunger, A. Eds., Materials Research Society, 1987, pp. 39–47. (b) Steward, J.M.; Chen, W.S.; Devaney, W.E.; Mickelsen, R.A. Deb, S.K. and Zunger, A. Eds., Materials Research Society, 1987, pp. 59–64.

  6. (a) Whittingham, M.S. Science 1976, 192, 1125. (b) Whittingham, M.S. J. Solid State Chem. 1979, 29, 303–310.

    Article  Google Scholar 

  7. (a) Kanatzidis, M. G. Abstracts of 196th ACS National Meeting, Los Angeles 1988, INORG 469. (b) Kim, K.-W., Dhingra, S.; Kanatzidis, M. G. unpublished

  8. (a) Cusick, J.; Scudder, M. L.; Craig, D. C; Dance, I. G. Polyhedron 1989, 8, 1139–1141 (b) Kanatzidis, M. G.; Huang S.-P.; Dhingra, S. unpublished (c) Kanatzidis, M. G.; Dhingra, S. Inorg. Chem. 1989, 28, 2024–2026 (d) Dhingra, S.; Kanatzidis, M. G. submitted for publication

    Article  CAS  Google Scholar 

  9. (a) ß-In2Se3: Popovic, S.; Tonejc, A.; Grzeta-Plenkovic, B.; Celustka, B.; Trojko, R. J. Appl. Crystallogr. 1979, 12, 416–420 (b) TISe: Ketelaar, J. A. A.; t’Hart, W. H.; Moerel, M.; Polder, D. Z. Kristallogr. 1939, 101, 396–405

    Article  CAS  Google Scholar 

  10. SEM-EDS analysis of the CuInSe2 films indicated the presence of traces of P (<0.07 % per weight)

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  1. Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI, 48824, USA

    S. Dhingra & M. G. Kanatzidis

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  1. S. Dhingra
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  2. M. G. Kanatzidis
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Dhingra, S., Kanatzidis, M.G. The use of Soluble Metal-Polyselenide Complexes as Precursors to Binary and Ternary Solid Metal Selenides. MRS Online Proceedings Library 180, 825 (1990). https://doi.org/10.1557/PROC-180-825

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