Abstract
The synthesis and characterization of several polymeric titanates and their conversion to carbon deficient TiC is described. The physical properties of one of these titanates allows it to be drawn into fibers and applied to substrates as thin films. Pyrolysis of these fibers and films to carbon deficient TiC is described.
This is a preview of subscription content, access via your institution.
References
- 1.
Yajima, S.; Hayashi, J.; Omori, M. Chem. Lett., 931 (1975).
- 2.
Yajima, S.; Okamura, K.; Hayashi, J.; Omori, M. J. Am. Chem. Soc., 59, 423 (1976).
- 3.
Yajima, S.; Hasegawa, Y.; Okamura, K.; Matsuzawa, T. Nature, 273, 525, (1978).
- 4.
Wynne, K. J.; Rice, R. W. Ann. Rev. Mat. Sci., 14, 297 (1984).
- 5.
West R. W.; “Ultrastructure Processing of Ceramics, Glasses and Composites,” Hench, L. L; Ulrich, D. R.; (eds.), Wiley, NY, 19 (1984).
- 6.
Yajima. S. Am. Ceram. See. Bull., 62. 893 (1983).
- 7.
Willis, R. R.; Markle, R. A.; Mukherjee, S. P. Am. Ceram. Soc. Bull., 62, 904 (1983).
- 8.
a) Bradley, D. C; Mehrotra, R. C; Gaur, D. P. “Metal Alkoxides,” Academic Press, New York (1978). b) Bradley, D. C. Advan. Inorg. Chem. Radiochem., 15, 259 (1972).
- 9.
Storm, E. K. “The Refractory Carbides,” Margrave, J. L., Ed., Acedemic Press, NY, Chapter 1 (1967)
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ting, S.J., Chu, C.J., Limatta, E. et al. The Formation of thin Films and Fibers of TiC from a Polymeric Titanate Precursor. MRS Online Proceedings Library 180, 457 (1990). https://doi.org/10.1557/PROC-180-457
Published: