X-Ray Reflectivity and Fluorescence Measurements From Polystyrene-Co-Bromostyrene/Polystyrene Interfaces

Abstract

X-ray fluorescence using synchrotron radiation at glancing angles of incidence was used to measure interface widths for the highly immiscible polymer blend system polystyrene/polybromostyrene (PS/PBrxS, with bromination level x = 0.8 bromine atoms per monomer). The interfacial widths are for bilayers annealed for 4 hours and 24 hours at 141±1C are found to be 100± 20Å and 110±20Å respectively.

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Correspondence to J. Sokolov.

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Sokolov, J., Rafailovich, M., Zhao, X. et al. X-Ray Reflectivity and Fluorescence Measurements From Polystyrene-Co-Bromostyrene/Polystyrene Interfaces. MRS Online Proceedings Library 171, 337–342 (1989). https://doi.org/10.1557/PROC-171-337

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