Abstract
The synthesis, structure/property behavior of inorganic-organic hybrid network materials prepared by the sol gel process have been chronologically reviewed with emphasis on those systems prepared in the authors laboratory. Specific features of reactions as well as the nature of reactants are included. The morphological features of these “ceramer” systems formed have many features in common even though the reactants may be quite different. The mechanical properties of the final materials in conjunction with SAXS have proven beneficial in establishing the basics of their morphological texture. Finally, it is demonstrated how microwave radiation in some cases, can serve as an efficient way in processing the ceramer systems.
This is a preview of subscription content, access via your institution.
References
- 1.
G. L. Wilkes, B. Orler and H. Huang, Polymer Prepr. 26(2), 300 (1985).
- 2.
H. Schmidt, Mate. Res. Soc. Symp. Proc. 32, 327 (1984).
- 3.
J. E. Mark, C. Y. Jiang and M. Y. Tang, Hacromol., 17, 2613 (1984).
- 4.
D. W. Schaefer and K. D. Keefer, Hate. Res. Soc. Symp. Proc. 32, 1 (1984).
- 5.
H. Huang, B. Orler and G. L. Wilkes, Polym. Bull. 14, 557 (1985).
- 6.
H. Huang, B. Orler and G. L. Wilkes, Macromolecules 20(6), 1322 (1987).
- 7.
H. Huang and G. L. Wilkes, Polym. Prep. 28(2), 244, (1987).
- 8.
H. Huang, R. H. Glaser and G. L. Wilkes, ACS Symposium on “Inorganic and Organometallic Polymers”, 360, 354 (1987).
- 9.
H. Huang and G. L. Wilkes, Polym. Bull. 18, 455–462 (1987).
- 10.
H. Huang, R. H. Glaser, A. B. Brennan, D. E. Rodrigues and G. L. Wilkes, Symposium on Ultrastructure Processing of Materials Tucson, 1989 in press.
- 11.
H. Huang and G. L. Wilkes, Polym. Prep. 30(2), 105–106 (1989).
- 12.
B. Wang, H. H. Huang, A. B. Brennan and G. L. Wilkes, Polym. Prepr. 30(2), 146–147 (1989).
- 13.
B. Wang, H. H. Huang, A. B. Brennan and G. L. Wilkes, Polym. Prepr. 30(2), 227–228 (1989).
- 14.
B. Wang, A. B. Brennan, H. Huang and G. L. Wilkes, J. Appl. Polym. Sci. submitted.
- 15.
A. B. Brennan and G. L. Wilkes, In preparation.
- 16.
M. Spinu, A. B. Brennan, G. L. Wilkes and J. E McGrath, Mat. Res. Symp. Polym. Based Mol. Comps. (1989).
- 17.
R. H. Glaser, G. L. Wilkes and C. E. Bronnimann, J. Non-Cryst. Solids submitted.
- 18.
John Lee W. Noell, G. L. Wilkes, D. K. Mohanty, J. E. McGrath, J. Appl. Polym. Sci. submitted
- 19.
H. Huang, Ph.D. Dissertation, Virginia Polytechnic Institute & State University, 1987.
- 20.
R. H. Glaser, Ph.D. Dissertation, Virginia Polytechnic Institute & State University, 1988.
- 21.
H. Schmidt, H. Scholze, A. Kaiser, J. Non-Cryst. Solids 63, 1 (1984).
- 22.
B. Wang, A. B. Brennan, H. Huang, D. Rodrigues and G. L. Wilkes, manuscript in preparation.
- 23.
B. Wang and G. L. Wilkes, manuscript in preparation.
- 24.
K. D. Keefer, Mate. Res. Soc. Symp. Proc. 32, 15 (1984).
- 25.
N. G. McCrum, B. E. Reed and G Williams, Anelastic and Dielectric Effects in Polymer Solids, John Wiley & Sons, London (1967).
- 26.
Handbook of Physics and Chemistry, CRC Press, 68, B140 (1987).
- 27.
D. A. Lewis, T. C. Ward, J. D. Summers and J. E. McGrath, Polym. Prepr. 29(1), 174 (1988).
- 28.
A. C. Metaxas and R. J. Meredith, Industrial Microwave Heating, Peter Peregrinus Ltd., London (1988).
- 29.
D. Rodrigues and G. L. Wilkes, manuscript in preparation.
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wilkes, G.L., Brennan, A.B., Huang, HH. et al. The Synthesis, Structure and Property Behavior of Inorganic-Organic Hybrid Network Materials Prepared by The Sol Gel Process. MRS Online Proceedings Library 171, 15–29 (1989). https://doi.org/10.1557/PROC-171-14
Published:
Issue Date: