Abstract
This paper presents proposals for the synthesis of several group III metal organics (In, Ga, Al compounds) and preliminary results on their use in the MOVPE (metal organic vapor phase epitaxy) of III-V semiconductors. The common feature of all these precursors is that they are saturated by interor intramolecular coordination. They are even non-pyrophoric and air resistant which is an interesting aspect with respect to safe handling. In addition, the compounds are liquid at room temperature with a low but sufficient vapor pressure for MOVPE without additional heating of the source.
This is a preview of subscription content, access via your institution.
References
- 1.
M.J. Ludowise, J. Appl. Phys. 58, R31 (1985).
- 2.
M.R. Leys, Cheetronics 2, 155 (1987).
- 3.
K.W. Benz, H. Haspeklo and R. Bosch, J. Phys. 43, Colloq. (C 5), 393 (1982).
- 4.
V.M. Donnelly, M.Geva, J.A. Long, R.F. Karlicek, Appl. Phys. Lett. 44, 951 (1984).
- 5.
R. Karlicek, J.A. Long and V.M. Donnelly, J. Cryst. Growth 58, 123 (1984).
- 6.
J.A. Long, V.G.Riggs and W.D. Johnston jr., J.Cryst. Growth 69, 10 (1984).
- 7.
S. Minagawa, H. Nakaaura and H. Sano, Jpn. J. Appl. Phys. 32, 467 (1984).
- 8.
C. Blaauw, C. Miner, B. Emmerstorfer, A.J. SpringThorpe and M. Gallant, Can. J. Phys. 63, 664 (1985).
- 9.
F. Scholz, P. Wiedemann, U. Nerz, K.W. Benz, G. Traenkle, E. Lach, A. Forchel, G. Laube, and J. Weidlein, J. Cryst. Growth 77, 564 (1986).
- 10.
W. Seiffert, R. Franzheld, F. Boenisch and E. Butter, Cryst. Res. Technol. 21, 9 (1986).
- 11.
M.K. Lee, D.S. Wuu and H.H. Tung, J. Appl. Phys. 62, 3209 (1987); Appl. Phys. Lett. 50, 1805 (1987); Appl. Phys. Lett. 50, 1725 (1987); Ts’ai Liao K’o Hsueh 19, 35 (1987).
- 12.
G. Laube, U. Kohler, J. Weidlein, F. Scholz, K.Streubel, R.J. Dieter, N. Karl and M. Gerdon, J. Cryst. Growth 93, 45 (1988).
- 13.
W. Seiffert, K. Ploska, S. Schwetlick and E. Butter, Cryst. Res. Technol. 24, 29 (1987).
- 14.
P. Speier, F. Scholz, Κ.W. Benz, H. Renz and J. Weidlein, Electronic Letters 19, 728 (1982).
- 15.
V. Frese, G.Κ. Regel, H. Hardtdegen, A. Brauers, P. Balk, M. Hostalek, M. Lokai and L. Pohl, submitted for publication.
- 16.
A. Molassioti, M. Moser, F. Scholz, M. Hostalek and L. Pohl, to be published.
- 17.
M. Hostalek, M. Lokai and L. Pohl, to be published.
- 18.
Ν. Hostalek, Η. Lokai, L. Pohl and H. Schunann, to be published.
- 19.
H. Schumann, Κ.U. Hartmann, A. Dietrich and J. Pickardt, Angew. Chemie 100, 1119 (1988).
- 20.
H. Schumann, to be published.
- 21.
K. Jurkschat, J. Organomet. Chem., 272 C 13 (1984).
- 22.
V. Frese, G.K. Regel, H. Hardtdegen, A. Brauers, P. Balk, M. Hostalek, M. Lokai and L. Pohl, to be published.
- 23.
A. Molassioti, M. Moser, A. Stapor, F. Scholz, M. Hostalek and L. Pohl, Appl. Phys. Lett. 54, 857 (1989).
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hostalhe, M., Pohl, L., Merck, E. et al. New Group III Precursors for the Movpe of GaAs and InP Based Material. MRS Online Proceedings Library 145, 205–210 (1989). https://doi.org/10.1557/PROC-145-205
Published:
Issue Date: