Chemical Treatment Influence on the Glass Substrate to the Growth of V2O5/PANI Thin Film

Abstract

Growth of the vanadium pentoxide xerogel in the presence of the polyaniline thin film (V2O5/PANI) in different chemical treatment on substrate are presented. The in situ characterization studies revealed the presence of a lamellar structure for the V2O5/PANI hybrid material. The intercalation reaction was evidenced on the basis of the increase in the d-spacing as well as the displacement of the absorption bands toward lower energy levels. The growth of V2O5/PANI thin film, from direct reaction, on glasses substrate using pre-treated with cationic surfactant cetyl pyridinium chloride (CPC) and cetyl trimethylammonium bromide (CTAB) presented layers with a surface homogeneous. The UV/ozone and RCA treatment showed that the film had low adhesion on substrate compared with CPC and CTAB treatment. Furthermore, these results suggests that the CTAB and CPC treatment can be used, further, for V2O5/PANI LbL films using V2O5 gel as first layer as well as a promising candidate for applications as sensor for ammonia detection in poultry shed.

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References

  1. 1.

    A.G. McDiarmid, Synth. Met. 125, 11 (2001).

    Article  Google Scholar 

  2. 2.

    R.Q. Ou, R. Samuels, J. Polym. Sci. B Polym. Phys. 37, 3473 (1999).

    CAS  Article  Google Scholar 

  3. 3.

    S.A. Travain, N.C. de Souza, D.T. Balogh, J.A. Giacometti, J. Colloid and Interface Science 316, 292 (2007).

    CAS  Article  Google Scholar 

  4. 4.

    D.R.G. Mitchell, D.J. Attard, G. Triani, Thin Solid Films 441, 85 (2003).

    CAS  Article  Google Scholar 

  5. 5.

    M.R. Wertheimer, L. Martinu, J.E. Klemberg-Sapieha, and G. Czeremuszkin, Adhesion Promotion Techniques in Advanced Technologies (K.L. Mittal and A. Pizzi, Marcel Dekker, New York, 1999), p. 139.

  6. 6.

    W. Kern and D.A. Puotinen, RCA Rev., 187 (1970).

  7. 7.

    W. Kern, J. Electrochem. Soc., 137(6), 1887 (1990).

  8. 8.

    M.L. Sham, J. Li, P.C. Ma and J.-K. Kim, Journal of Composite Mat., 43, 1537 (2009).

    CAS  Article  Google Scholar 

  9. 9.

    E.M. Guerra, G.R. Silva. M. Mulato, Solid State Sciences, 11, 456 (2009).

    CAS  Article  Google Scholar 

  10. 10.

    C.-G. Wu, D.C. DeGroot, H.O. Marcy, J.L. Schindler, C.R. Kannewurf, Y.-J. Liu, W. Hirpo, M.G. Kanatzidis, Chem. Mater. 8, 1992 (1996).

    CAS  Article  Google Scholar 

  11. 11.

    N. Gharbi, C. Sanchez, J. Livage, J. Lemerle, L. Nejem, J. Lefebvre, Inorg. Chem. 21, 2758 (1982).

    CAS  Article  Google Scholar 

  12. 12.

    J. Livage, Chem. Mater. 3, 578 (1991).

    CAS  Article  Google Scholar 

  13. 13.

    E. M. Guerra, K.J. Ciuffi, H.P. Oliveira, J. Solid State Chem. 179, 3814 (2006).

    CAS  Article  Google Scholar 

  14. 14.

    V. Petkov, P.N. Trikalitis, E.S. Bozin, S.J. Bollinge, T. Vogt,M.G. Kanatzidis, J. Am. Chem. Soc. 124, 10157 (2002).

    CAS  Article  Google Scholar 

  15. 15.

    R. Baddour, J.P. Pereira-Ramos, R. Messina, J. Perichon, J. Electroanal. Chem. 314, 81 (1991).

    CAS  Article  Google Scholar 

  16. 16.

    H. P. Oliveira, C. F.O. Graeff, C. A. Brunello, E. M. Guerra, Journal of Non-Crystalline Solids 273, 193 (2000).

    CAS  Article  Google Scholar 

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Correspondence to Elidia M. Guerra.

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Guerra, E.M., Santos, M.C. & Bianchi, R.F. Chemical Treatment Influence on the Glass Substrate to the Growth of V2O5/PANI Thin Film. MRS Online Proceedings Library 1230, 607 (2009). https://doi.org/10.1557/PROC-1230-MM06-07

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