Fabrication of Cu(In,Ga)Se2 films by a combination of mechanochemical synthesis, wet bead milling, and screen-printing/sintering process


We prepared fine Cu(In,Ga)Se2 (CIGS) powder suitable for screen printing using a mechanochemical synthesis and wet bead milling. Particulate precursors were deposited in a layer by a screen-printing technique, and the porous precursor layer was sintered into a dense polycrystalline film by atmospheric-pressure firing in an N2 gas atmosphere. The microstructure of CIGS powder and fired CIGS film were observed in an SEM. The wet bead milling was effective for the reduction and homogenization of the average grain size of CIGS powder. The CIGS grains in the film were well sintered and the size of CIGS grains was as large as about 2 μm. The CIGS solar cell showed an efficiency of 3.1%, withV oc of 0.279 V,J sc of 28.8 mA/cm2 and FF of 0.386.

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  1. 1.

    I. Repins, M. A. Contreras, B. Egaas, C. DeHart, J. Scharf, C. L. Perkins, B. To, R. Noufi Progress in Photovoltaics: Research and Applications 16, 235 (2008).

    CAS  Article  Google Scholar 

  2. 2.

    S. Taunier, J. Sicx-Kurdi, P. P. Grand, A. Chomont, O. Ramdani, L. Parissi, P. Panheleux, N. Naghavi,C. Hubert, M. Ben-Farah, J. P. Fauvarque, J. Connolly, O. Roussel, P. Mogensen, E. Mahé, J. F. Guillemoles, D. Lincot, and O. Kerrec, Thin Solid Films 480/481, 526 (2005).

    Article  Google Scholar 

  3. 3.

    B.M. Basol, M. Pinarbasi, S. Aksu, J. Wang, Y. Matus, T. Johnson, Y. Han, M. Narasimhan, B. Metin, The Proceedings of the 23rd European Photovoltaic Solar Energy Conference, Valencia, Spain, in September 2008, p.2137.

  4. 4.

    M. Kaelin, D. Rudmann, F. Kurdesau, H. Zogg, T. Meyer, and A. N. Tiwari, Thin Solid Films 480-481, 486.

  5. 5.

    D. B. Mitzi, M. Yuan, W. Liu, A. Kellock, S. J. Chey, V. Deline, A. G. Schrott, Advanced Materials 20, 3657 (2008).

    CAS  Article  Google Scholar 

  6. 6.

    V. K. Kapur, A. Bansal, P. Le, and O. I. Asensio, Thin Solid Films 431-432, 53 (2003).

    CAS  Article  Google Scholar 

  7. 7.

    C. Eberspacher, C. Fredric, K. Pauls, and J. Serra, Thin Solid Films 387, 18 (2001).

    CAS  Article  Google Scholar 

  8. 8.

    T. Wada, Y. Matsuo, S. Nomura, Y. Nakamura, A. Miyamura, Y. Chiba, A. Yamada and M. Konagai. phys. stat. sol. (a) 203, 2593–2597 (2006).

    CAS  Article  Google Scholar 

  9. 9.

    S. Nomura, Y. Matsuo and T. Wada, Thin-Film Compound Semiconductor Photovoltaics-2007, edited by T. Gessert, K. Durose, C. Heske, S. Marsillac, T. Wada (Mater. Res. Soc. Symp. Proc. Vol. 1012, Warrendale, PA, 2007), 1012-Y03-15.

  10. 10.

    T. Wada, H. Kinoshita, S. Kawata, Thin Solid Films 431-432, 11–15 (2003).

    CAS  Article  Google Scholar 

  11. 11.

    T. Wada and H. Kinoshita, J. Phys. Chem. Solids 66, 1987 (2005).

    CAS  Article  Google Scholar 

  12. 12.

    H. Miyazaki, R. Mikami, A. Yamada, and M. Konagai, Jpn. J. Appl. Phys. 43, 4244 (2004).

    CAS  Article  Google Scholar 

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Kubo, J., Matsuo, Y., Wada, T. et al. Fabrication of Cu(In,Ga)Se2 films by a combination of mechanochemical synthesis, wet bead milling, and screen-printing/sintering process. MRS Online Proceedings Library 1165, 513 (2009). https://doi.org/10.1557/PROC-1165-M05-13

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