Attempt to Grow α-Rhombohedral Boron Crystals in Copper Solvent

Abstract

An excellent material for thermal neutron detectors is α-rhombohedral boron, due to the large neutron capture cross section of10B, high hole mobility and ability to self-heal from radiation damage, to date, little work has been done on the crystal growth of α-rhombohedral boron. In this investigation, we attempt to grow α-rhombohedral boron by the solution growth method, employing copper as solvent. Well-faceted transparent red crystals several hundreds of microns in size have been made. Elemental analysis of the crystals detected boron, with negligible amounts of copper, suggesting that copper is a promising solvent for the crystal growth of α-rhombohedral boron crystal.

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References

  1. 1.

    G.F.Knoll, Radiation Detection and Measurements 3rd ed (j. Wiley 2000) p.p 505–535

  2. 2.

    Z.W. Bell, D.A. Carpenter, S.S. Cristy, V.E. Lamberti, A. Burger, B.F. Woodfield, T. Niedermayr, I.D. Hau, S.E. Labov, S. Friedrich, W.G. West, K.R. Pohl, and L. van den Berg, Phys. Stat. Sol. C 2 1592 (2005).

    CAS  Google Scholar 

  3. 3.

    C. Lundstedt, A. Harken, E. Day, B.W. Robertson, and S. Adenwalla, Nucl. Inst. Meth. A 562 380 (2006).

    CAS  Article  Google Scholar 

  4. 4.

    M. Carrard, D. Emin, L. Zuppiroli, Phys. Rev. B 51 11,270 (1995).

    Article  Google Scholar 

  5. 5.

    O.A Golikova Chemtronics 5 ,3(1991)

    CAS  Google Scholar 

  6. 6.

    F. Hubbard Horn, J. Electrochem. Soc., Volume 106, Issue 10, pp. 905–906 (1959)

    CAS  Article  Google Scholar 

  7. 7.

    F. Wald, J.Bullitt, “Semiconductor Neutron Detectors”. Defense Technical Information Center, Jan 1973, Accession Number: AD0771526.

  8. 8.

    K. T. Jacob, S. Priya, and Y. Waseda, Metall. Mater. Trans. A 31, 2674 (2000).

    Article  Google Scholar 

  9. 9.

    F. Wald, Electron Technology, Institute of Electron Technology P.A Sci., Warsaw 3, 1/2,103 (1971)

    Google Scholar 

  10. 10.

    D.R. Tallant, T.L. Aselage, A.N. Campbell, and D. Emin, Phys. Rev. B 40, 5649 (1989).

    CAS  Article  Google Scholar 

  11. 11.

    C.L. Beckel, M. Yousaf, M.Z. Fuka, S.Y. Raja, and N. Lu, Phys. Rev. B 44, 2535 (1991).

    CAS  Article  Google Scholar 

  12. 12.

    N. Vast, S. Baroni, G. Zerah, J.M. Besson, A. Polian, M Grimsditch, and I.C. Chervin, Phys. Rev. Lett. 78, 693 (1997).

    Article  Google Scholar 

  13. 13.

    W. Richter, A. Hausen, and H. Binnenbruch, Phys. Stat. Sol. (b) 60, 461 (1973).

    CAS  Article  Google Scholar 

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Correspondence to W. Gao.

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Gao, W., Whiteley, C., Zhang, Y. et al. Attempt to Grow α-Rhombohedral Boron Crystals in Copper Solvent. MRS Online Proceedings Library 1164, 603 (2009). https://doi.org/10.1557/PROC-1164-L06-03

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