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Hybrid Nanocomposites Based on Metal Oxides and Polysiloxanes with Controlled Morphology

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Abstract

Hybrid materials based on polysiloxanes and metal oxides (SiO2, TiO2, ZrO2) were prepared by hydrosilation of allyl acetoacetate (AAA) modified metal alkoxides (M(OR)4; M = Ti, Zr; R = ethyl, isopropyl) or vinyl triethoxysilane with poly(dimethylsiloxane-co-hydrosiloxane) (PDMS-co-PMHS). The obtained compounds acted as single-source precursors in the sol-gel process. Various spectroscopic methods showed the complete functionalization of the polysiloxane chains with the complexes. When alcohols were used as solvents in the sol-gel process, hybrid nanoparticles were obtained, as observed by dynamic light scattering (DLS) measurements, transmission electron microscopy (TEM), and spectroscopic methods such as NMR and FT-IR.

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Authors and Affiliations

  1. Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9-165, Vienna, A1060, Austria

    Sorin Ivanovici, Christoph Rill, Claudia Feldgitscher & Guido Kickelbick

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  1. Sorin Ivanovici
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  2. Christoph Rill
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  3. Claudia Feldgitscher
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  4. Guido Kickelbick
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Ivanovici, S., Rill, C., Feldgitscher, C. et al. Hybrid Nanocomposites Based on Metal Oxides and Polysiloxanes with Controlled Morphology. MRS Online Proceedings Library 1007, 1255 (2007). https://doi.org/10.1557/PROC-1007-S12-55

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  • DOI: https://doi.org/10.1557/PROC-1007-S12-55

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