Hybrid Nanocomposites Based on Metal Oxides and Polysiloxanes with Controlled Morphology

MRS Online Proceedings Library volume 1007, Article number: 1255 (2007) Cite this article

Abstract

Hybrid materials based on polysiloxanes and metal oxides (SiO2, TiO2, ZrO2) were prepared by hydrosilation of allyl acetoacetate (AAA) modified metal alkoxides (M(OR)4; M = Ti, Zr; R = ethyl, isopropyl) or vinyl triethoxysilane with poly(dimethylsiloxane-co-hydrosiloxane) (PDMS-co-PMHS). The obtained compounds acted as single-source precursors in the sol-gel process. Various spectroscopic methods showed the complete functionalization of the polysiloxane chains with the complexes. When alcohols were used as solvents in the sol-gel process, hybrid nanoparticles were obtained, as observed by dynamic light scattering (DLS) measurements, transmission electron microscopy (TEM), and spectroscopic methods such as NMR and FT-IR.

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References

  1. 1.

    Y. Abe and T. Gunji, Prog. Polym. Sci, 29, 149 (2004).

    CAS  Article  Google Scholar 

  2. 2.

    J. E. Mark, Acc. Chem. Res., 37, 946 (2004).

    CAS  Article  Google Scholar 

  3. 3.

    K. Rozga-Wijas, J. Chojnowski, W. Fortuniak, M. Scibiorek, Z. Michalska, and L. Rogalski, Journal of Materials Chemistry, 13, 2301 (2003).

    CAS  Article  Google Scholar 

  4. 4.

    B. Julian, C. Gervais, E. Cordoncillo, P. Escribano, F. Babonneau, and C. Sanchez, Chem. Mat., 15, 3026 (2003).

    CAS  Article  Google Scholar 

  5. 5.

    C. Guermeur, J. Lambard, J.-F. Gerard, and C. Sanchez, J. Mater. Chem., 9, 769 (1999).

    CAS  Article  Google Scholar 

  6. 6.

    N. Huesing, J. Bauer, G. Kalss, G. Garnweitner, and G. Kickelbick, J. Sol-Gel. Sci. Techn, 26, 73 (2003).

    CAS  Article  Google Scholar 

  7. 7.

    M. Nakade, K. Ichihashi, and M. Ogawa, J. Porous Mater., 12, 79 (2005).

    CAS  Article  Google Scholar 

  8. 8.

    C. Sanchez, B. Julian, P. Belleville, and M. Popall, J. Mater. Chem., 15, 3559 (2005).

    CAS  Article  Google Scholar 

  9. 9.

    C. Sanchez and F. Ribot, New J. Chem., 18, 1007 (1994).

    CAS  Google Scholar 

  10. 10.

    U. Schubert, J. Mater. Chem., 15, 3701 (2005).

    CAS  Article  Google Scholar 

  11. 11.

    C. Sanchez, B. Lebeau, F. Ribot, and M. In, J. Sol-Gel. Sci. Techn., 19, 31, (2000).

    CAS  Article  Google Scholar 

  12. 12.

    L. C. Cauro-Gamet, L. G. Hubert-Pfalzgraf, and S. Lecocq, Z. Anorg. Allg. Chem., 630, 2071 (2004).

    CAS  Article  Google Scholar 

  13. 13.

    W. Stoeber ; A. Fink ; E. Bohn . J. Colloid Interface Sci.., 26, 62 (1968).

    CAS  Article  Google Scholar 

  14. 14.

    D. Hoebbel, T. Reinert, H. Schmidt, and E. Arpac, J. Sol-Gel. Sci. Techn, 10, 115–126, (1997).

    CAS  Article  Google Scholar 

  15. 15.

    J. N. Lee, C. Park, and G. M. Whitesides, Anal. Chem., 75, 6544 (2003).

    CAS  Article  Google Scholar 

Download references

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Affiliations

  1. Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9-165, Vienna, A1060, Austria

    Sorin Ivanovici, Christoph Rill, Claudia Feldgitscher & Guido Kickelbick

Authors
  1. Sorin Ivanovici
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  2. Christoph Rill
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  3. Claudia Feldgitscher
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  4. Guido Kickelbick
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Correspondence to Sorin Ivanovici.

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Ivanovici, S., Rill, C., Feldgitscher, C. et al. Hybrid Nanocomposites Based on Metal Oxides and Polysiloxanes with Controlled Morphology. MRS Online Proceedings Library 1007, 1255 (2007). https://doi.org/10.1557/PROC-1007-S12-55

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