Abstract
Microcrystalline silicon (µc-Si:H) was deposited by hot-wire chemical vapor deposition (HWCVD) using a graphite filament on glass substrates with and without a thin 50 nm µc-Si:H seed layer. Increasing silane concentration diluted in H2 led to a decrease in crystalline fraction as well in a decrease in dark conductivity and photo-conductivity. In addition, films deposited with a seed layer were found to have higher dark conductivity and photo-conductivity than those without a seed layer but deposited at slower growth rates. However, Raman spectroscopy showed that use of a seed layer resulted in only a small increase in crystalline fraction at the surface of the films which had thicknesses between 250-400nm. TEM measurements confirmed the crystalline nature of deposited films showing average grain sizes of 25 nm.
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References
- 1
K. Brühne, M. B. Schubert, C. Köhler, J. H. Werner, Thin Solid Films 395, 163–168 (2001).
- 2
D.M.Bhusari, P. Kumar, M. Kupich, B. Schroeder, Mat. Res. Soc.Symp.Proc.Vol. 808, A9.30.1–6 (2004).
- 3
S.Morrison, A.Madan, 28th IEEE Photovoltaic Specialists Conference 2000, 837–40 (2000).
- 4
S.N.Sharma, A.K.Bandyopadhyay, R. Banerjee, A.K. Batabyal, A.K. Barua, Phys. Rev. B, Vol. 41(5), 4503–4506 (1991).
- 5
Van Veen, Marieke Katherine, Ph.D. dissertation, Utrecht University, Netherlands, 23–46 (2003).
- 6
S.Klein, T.Repmann,T.Brammar, Solar Energy 77, 893–908 (2004).
- 7
H.R.Moutinho, et al, Thin Solid Films 430, 135–140 (2003).
- 8
D.B.Williams, C.B.Carter, Transmission Electron Microscopy, (Plenum Press, New York, (1996), pp. 273–275.
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Adachi, M.M., Tse, W., Cluff, G. et al. Effects of HWCVD-deposited Seed Layers on Hydrogenated Microcrystalline Silicon Films on Glass Substrates. MRS Online Proceedings Library 910, 805 (2005). https://doi.org/10.1557/PROC-0910-A08-05
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