Abstract
Layer-by-layer films incorporating single-wall carbon nanotubes (SWNTs) with anionic or cationic coatings have been prepared. The process of self-assembly was monitored using the quartz microbalance technique, while the morphology of the resulting thin layers was studied with atomic force microscopy. A variety of different architectures have been built up. The dc conductivities of the thin films, in-plane and out-of-plane, were measured at room temperature and contrasted with reference architectures. The results show clearly that the incorporation of SWNTs into the multilayers resulted in electrically conductive thin films.
This is a preview of subscription content, access via your institution.
References
- 1
G. Decher, Science, 277, 1232 (1997).
- 2
Multilayer Thin Films-Sequential Assembly of Nanocomposite Materials, ed. G. Decher and J.B. Schlenoff, (Wiley-VCH, 2003).
- 3
P.T. Hammond, Advanced Materials, 16, 1271 (2004).
- 4
S.S. Shiratori and M.F. Rubner, Macromolecules, 33, 4213 (2000).
- 5
M. Palumbo, C. Pearson, and M.C. Petty, Thin Solid Films, 483, 114 (2005).
- 6
S. Iijima, Nature, 354, 56 (1991).
- 7
P.J.F. Harris, Carbon Nanotubes and Related Structures : New Materials for the Twenty-First Century, (Cambridge University Press, 1999).
- 8
A.A. Mamedov, N.A. Kotov, M. Prato, D.M. Guldi, J.P. Wicksted, and A. Hirsch, Nature Materials, 1, 190 (2002).
- 9
M. Olek, J. Ostrander, S. Jurga, H. Mohwald, N. Kotov, K. Kempa, and M. Giersig, Nano Letters, 4, 1889 (2004).
- 10
T. Takahashi, K. Tsunoda, H. Yajima, and T. Ishii, Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers, 43, 3636 (2004).
- 11
S.J. Geelhood, C.W. Frank, and K. Kanazawa, Journal of the Electrochemical Society, 149, H33 (2002).
- 12
C. Lu and O. Lewis, Journal of Applied Physics, 43, 4385 (1972).
- 13
C. Picart, P. Lavalle, P. Hubert, F.J.G. Cuisinier, G. Decher, P. Schaaf, and J.C. Voegel, Langmuir, 17, 7414 (2001).
- 14
V.V. Tsukruk, V.N. Bliznyuk, D. Visser, A.L. Campbell, T.J. Bunning, and W.W. Adams, Macromolecules, 30, 6615 (1997).
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Palumbo, M., Lee, K.U., Ahn, B.T. et al. Layer-by-Layer Thin Films of Carbon Nanotubes. MRS Online Proceedings Library 901, 541 (2005). https://doi.org/10.1557/PROC-0901-Ra05-41-Rb05-41
Received:
Accepted:
Published: