Abstract
Eu2+-doped Li2SrSiO4 phosphors were prepared by two different synthesis processes, the Pechini sol-gel route and solid-state reaction (SSR) method. Their morphology, crystal structure, and luminescence properties have been characterized. Li2SrSiO4:Eu2+ phosphors show broad and intensive excitation in the range of 390–480 nm and emit yellow-orange light extending from 500 to 700 nm. The luminescence efficiency of Li2SrSiO4: Eu2+ phosphors synthesized through the Pechini route is much better than that of phosphors prepared by solid-state reaction method. The application of phosphors from the Pechini route in white light emitting diodes (LEDs) has been investigated. The Commission Internationale de L’Eclairage (CIE) chromaticity coordinates and the correlated color temperature of these white LEDs have been calculated; they are comparable to corresponding values of commercial Y3Al5O12:Ce3+ converted white LEDs.
Similar content being viewed by others
References
S. Nakamura, G. Fasol: The Blue Laser Diode: GaN Based Light Emitters and Lasers Springer-Verlag Berlin, Germany 1997
M.G. Craford: Commercial, Light Emitting Diode Technology Kluwer Academic Publishers Dordrecht, The Netherlands 1996
L.S. Rohwer, A.M. Srivastava: Development of phosphors for LEDs. Electrochem. Soc. Interface 12, 36 2003
J.S. Kim, Y.H. Park, J.C. Choi, H.L. Park: Optical and structural properties of Eu2+ doped (Sr1−xBax)2SiO4 phosphors. J. Electrochem. Soc. 152, H135 2005
J.K. Park, C.H. Kim, S.H. Park, H.D. Park: Application of strontium silicate yellow phosphor for white light-emitting diodes. Appl. Phys. Lett. 85, 1647 2004
R.J. Xie, N. Hirosaki, M. Mitoma, K. Takahashi, K. Sakuma: Highly efficient white-light-emitting diodes fabricated with short-wavelength yellow oxynitride phosphors. Appl. Phys. Lett. 88, 101104 2006
R.J. Xie, N. Hirosaki: Silicon-based oxynitride and nitride phosphors for white LEDs—A review. Sci. Technol. Adv. Mater. 8, 588 2007
H. He, R.L. Fu, X.F. Song, D.L. Wang, J. Chen: White light emitting Mg0.1Sr1.9SiO4:Eu2+ phosphors. J. Lumin. 128, 489 2008
K. Tada, Y. Kawakami, S. Kousaka, Y. Ito, A. Komeno, K. Uematsu, M. Sato: New silicate phosphors for a white LED. IEICE Trans. Electron. E 89-C 1406 2006
M. Saradhi, U.V. Varadaraju: Photoluminescence studies on Eu2+-activated Li2SrSiO4—A potential orange-yellow phosphor for solid-state lighting. Chem. Mater. 18, 5267 2006
H.S. Kang, S.B. Park Synthesis of yellow emitting silicate phosphor particles for white LED (European Aerosol Conference 2007, Salzburg, Abstracted T15A006
B. Haferkorn, G.Z. Meyer: Li2EuSiO4, in Europium(II)-dilitho-silicat: Eu. Anorg. Allg. Chem 624, 1079 1998
S.H.M. Poort, G. Blasse: The influence of the host lattice on the luminescence of divalent europium. J. Lumin. 72, 247 1997
G. Blasse, B.C. Grabmaier: Luminescent Materials Springer-Verlag Berlin, Germany 1994
M.P. Pechini Method of prepared lead and alkaline earth titanates and niobates and coating method using the same to form a capacitor, U.S. Patent No. 3 330 697 (1967)
R.W. Schwartz: Chemical solution deposition of perovskite thin films. Chem. Mater. 9, 2325 1997
Ch. Laberty-Robert, F. Ansart, C. Deloget, M. Gaudo, A. Rousset: Powder synthesis of nanocrystalline ZrO2–8%Y2O3 via a polymerization route. Mater. Res. Bull. 36, 2038 2001
W. Liu, G.C. Farrington, F. Chaput, B. Dunn: Synthesis and electrochemical studies of spinel phase LiMn2O4 cathode materials prepared by the Pechini process. J. Electrochem. Soc. 143, 879 1996
C.A. Kodaira, H.F. Brito, O.L. Malta, O.A. Serra: Luminescence and energy transfer of the europium (III) tungstate obtained via the Pechini method. J. Lumin. 101, 11 2003
J. Rodríguez-Carvajal: An Introduction to the Program FullProf 2000 (Laboratoire Léon Brillouin, CEA-CNRS, Saclay, France, 2001
R.W.G. Hunt: The Reproduction of Color in Photography, Printing & Television Fountain Press London, UK 1987
L.E. Shea, J. McKittrick, O.A. Lopez: Synthesis of red-emitting, small particle size luminescent oxides using an optimized combustion process. J. Am. Ceram. Soc. 79, 3257 1996
Acknowledgments
We thank Prof. Xiaomei Feng and Mr. Sidong Lei for valuable discussion on the experimental data. We also thank Mr. Shenqiang Li from the Quantai Science and Technology Development Co. Ltd., Nanjing, China, for his help with LED packaging.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
He, H., Fu, R., Wang, H. et al. Li2SrSiO4:Eu2+ phosphor prepared by the Pechini method and its application in white light emitting diode. Journal of Materials Research 23, 3288–3294 (2008). https://doi.org/10.1557/JMR.2008.0394
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2008.0394