Skip to main content
SpringerLink
Log in

A study of temperature and pressure-induced structural and electronic changes in SbCl5 intercalated graphite: Part III. Analysis of the T and p dependence of the c-axis resistivity

  • Articles
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

We present experimental data for the c-axis electrical resistivity of SbCl5 intercalated graphite between 20 and 300 K. The data are analyzed together with our previous results for these and other samples [O. E. Andersson et al., J. Mater. Res. 7, 2989 (1992)]. Before the analysis, we correct the experimental data to constant volume, as assumed by theorists. We show that the correction factor is much larger for these materials than for normal metals. Although the original data showed significant nonlinearities with T, the corrected data are linear in T to within the experimental accuracy for low-stage compounds below the intercalate crystallization temperature. We compare our results with several models and conclude that both the temperature dependence, the pressure dependence, and the relative changes in the in-plane and c-axis resistivities associated with intercalate crystallization can be best described by a band conduction model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Lelaurain, J. F. Marêché, E. McRae, O. E. Andersson, and B. Sundqvist, J. Mater. Res. 7, 2978 (1992).

    Article  CAS  Google Scholar 

  2. O. E. Andersson, B. Sundqvist, E. McRae, J. F. Marêché, and M. Lelaurain, J. Mater. Res. 7, 2989 (1992).

    Article  CAS  Google Scholar 

  3. E. McRae, J. F. Marêché, M. Lelaurain, O. E. Andersson, and B. Sundqvist, Mol. Cryst. Liq. Cryst. 245, 61 (1994).

    Article  CAS  Google Scholar 

  4. S. Ono, J. Phys. Soc. Jpn. 40, 498 (1976).

    Article  CAS  Google Scholar 

  5. I. L. Spain, in Chemistry and Physics of Carbon, edited by P. L. Walker and P. A. Thrower (Marcel Dekker, New York, 1981), Vol. 16, p. 119.

    CAS  Google Scholar 

  6. G. J. Morgan and C. Uher, Philos. Mag. 44, 427 (1981).

    Article  CAS  Google Scholar 

  7. C. Uher, R. L. Hockey, and E. Ben-Jacob, Phys. Rev. B 35, 4483 (1987).

    Article  CAS  Google Scholar 

  8. K. Matsubara, K. Sugihara, and T. Tsuzuku, Phys. Rev. B 41, 969 (1990); correction, Phys. Rev. B 46, 1948 (1992).

    Article  CAS  Google Scholar 

  9. R. S. Markiewicz, Solid State Commun. 57, 237 (1986).

    Article  CAS  Google Scholar 

  10. H. Zaleski and W. R. Datars, Phys. Rev. B 35, 7690 (1987).

    Article  CAS  Google Scholar 

  11. R. Powers, A. K. Ibrahim, G. O. Zimmerman, and M. Tahar, Phys. Rev. B 38, 680 (1988).

    Article  CAS  Google Scholar 

  12. K. Sugihara, Phys. Rev. B 29, 5872 (1984).

    Article  CAS  Google Scholar 

  13. K. Sugihara, Phys. Rev. B 37, 4752 (1988).

    Article  CAS  Google Scholar 

  14. K. Sugihara, J. Phys. Soc. Jpn. 62, 624 (1993).

    Article  CAS  Google Scholar 

  15. S. Shimamura, Synth. Met. 12, 365 (1985).

    Article  CAS  Google Scholar 

  16. N. F. Mott and H. Jones, The Theory of the Properties of Metals and Alloys (Dover, New York, 1958).

    Google Scholar 

  17. J. M. Ziman, Electrons and Phonons (Clarendon Press, Oxford, 1960), p. 418; R. A. Matula and P. G. Klemens, High Temp.-High Pressures 10, 105 (1978).

    Google Scholar 

  18. B. Sundqvist, Mod. Phys. Lett. B 7, 491 (1993).

    Article  CAS  Google Scholar 

  19. B. Sundqvist and B. M. Andersso, Solid State Commun. 76,1019 (1990); B. Sundqvist and E. M. C. Nilsson, Phys. Rev. B (1995, in press).

    Google Scholar 

  20. L. Salamanca-Riba and M. S. Dresselhaus, Carbon 24, 261 (1986).

    Article  CAS  Google Scholar 

  21. B. Alzyab, C. H. Perry, C. Zahapoulos, O. A. Pringle, and R. M. Nicklow, Phys. Rev. B 38, 1544 (1988).

    Article  CAS  Google Scholar 

  22. E. G. Steward and B. P. Cook, Nature 185, 78 (1960); E. G. Steward, B. P. Cook, and E. A. Kellett, Nature 187, 1015 (1960).

    Article  CAS  Google Scholar 

  23. M. Hanfiand, H. Beister, and K. Syassen, Phys. Rev. B 39, 12598 (1989); Y. X. Zhao and I. L. Spain, Phys. Rev. 40, 993 (1989).

    Article  Google Scholar 

  24. K. A. Gschneider, Jr., Solid State Phys. 16, 275 (1964).

    Article  Google Scholar 

  25. R. Clarke, M. Elzinga, J. N. Gray, H. Homma, D. T. Morelli, M. J. Winokur, and C. Uher, Phys. Rev. B 26, 5250 (1982).

    Article  CAS  Google Scholar 

  26. N. F. Mott, Proc. Roy. Soc. (London) A 156, 368 (1936).

    CAS  Google Scholar 

  27. D. Marchand, C. Fretigny, M. Lagues, A. P. Legrand, E. McRae, J. F. Marêché, and M. Lelaurain, Carbon 22, 497 (1984).

    Article  CAS  Google Scholar 

  28. W. R. McKinnon, C. M. Hurd, and I. Shiozaki, J. Phys. C 14, L877 (1981); I. Shiozaki, C. M. Hurd, S. P. McAlister, W. R. McKinnon, and P. Strobel, J. Phys. C 14, 4641 (1981).

    Article  Google Scholar 

  29. T. Enoki, N. Sakamoto, K. Nakazawa, K. Suzuki, K. Sugihara, and K. Kobayashi, Phys. Rev. B 47, 10662 (1993).

    Article  CAS  Google Scholar 

  30. P. W. Bridgman, Proc. Am. Acad. Arts Sci. 84, 31 (1957); P. Jacobsson and B. Sundqvist, J. Phys. Chem. Solids 49, 441 (1988).

    Article  Google Scholar 

  31. N. Okuyama, H. Yasunaga, and S. Minomura, Jpn. J. Appl. Phys. 10, 1645 (1971).

    Article  CAS  Google Scholar 

  32. G. Andersson and B. Sundqvist, Solid State Commun. 65, 735 (1988).

    Article  CAS  Google Scholar 

  33. F. Batallan, J. Bok, I. Rosenman, and J. Melin, Phys. Rev. Lett. 41, 330 (1978).

    Article  CAS  Google Scholar 

  34. N. B. Brandt, S. V. Kuvshinnikov, S. G. Ionov, and V. A. Mukhanov, Sov. J. Low Temp. Phys. 10, 379 (1984).

    Google Scholar 

  35. Y. Yosida and S. Tanuma, J. Phys. Soc. Jpn. 54, 650 (1985).

    Article  CAS  Google Scholar 

  36. Y. Yosida, S. Tanuma, and Y. Iye, J. Phys. Soc. Jpn. 54, 2635 (1985).

    Article  CAS  Google Scholar 

  37. Y. Yosida and S. Tanuma, Carbon 23, 381 (1985).

    Article  CAS  Google Scholar 

  38. O. Takahashi, Y. Iye, and S. Tanuma, Solid State Commun. 37, 863 (1981).

    Article  CAS  Google Scholar 

  39. H. Zaleski, P. K. Ummat, and W. R. Datars, Phys. Rev. B 35, 2958 (1987).

    Article  CAS  Google Scholar 

  40. G. Wang, H. Zaleski, P. K. Ummat, and W. R. Datars, Phys. Rev. B 37, 9029 (1988).

    Article  CAS  Google Scholar 

  41. Y. Yosida and S. Tanuma, Synth. Metals 23, 199 (1988).

    Article  Google Scholar 

  42. Y. Iye, O. Takahashi, S. Tanuma, K. Tsuji, and S. Minomura, J. Phys. Soc. Jpn. 51, 475 (1982).

    Article  CAS  Google Scholar 

  43. K. Syassen, R. Sonnenschein, M. Hanfiand, and H. J. Beister, Synth. Metals 34, 293 (1989).

    Article  CAS  Google Scholar 

  44. D. M. Hoffman, R. E. Heintz, G. L. Doll, and P. C. Eklund, Phys. Rev. B 32, 1278 (1985).

    Article  CAS  Google Scholar 

  45. J. Blinowski, N. H. Hao, C. Rigaux, J. P. Vieren, R. Le Toullec, G. Furdin, A. Hérold, and J. Melin, J. Phys. (Paris) 41, 47 (1980); J. Blinowski and C. Rigaux, J. Phys. (Paris) 41, 667 (1980).

    Article  CAS  Google Scholar 

  46. H. Homma and R. Clarke, Phys. Rev. B 31, 5865 (1985).

    Google Scholar 

  47. D. M. Hwang, X. W. Qian, and S. A. Solin, Phys. Rev. Lett. 53, 1473 (1984); R. Levi-Setti, G. Crow, Y. L. Wang, N. W. Parker, R. Mittleman, and D. M. Hwang, Phys. Rev. Lett. 54, 2615 (1985).

    Article  Google Scholar 

  48. B. Houser, H. Homma, and R. Clarke, Phys. Rev. B 30, 4802 (1984).

    Article  CAS  Google Scholar 

  49. B. Sundqvist and B. Lundberg, J. Phys. C 19, 6915 (1986).

    Article  CAS  Google Scholar 

  50. O. E. Andersson, B. Sundqvist, E. McRae, M. Lelaurain, and J. F. Marêché, J. Mater. Res. (1995, in press).

    Google Scholar 

  51. See, for example, L. Forro, V. Ilakovac, J. R. Cooper, C. Ayache, and J-Y. Henry, Phys. Rev. B 46, 6626 (1992); K. E. Gray and D. H. Kim, Phys. Rev. Lett. 70, 1693 (1993); A. G. Rojo and K. Levin, Phys. Rev. B 48, 16861 (1993).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Experimental Physics, Urnea University, S-90187, Urnea, Sweden

    B. Sundqvist & O. E. Andersson

  2. Université de Nancy I, Laboratoire de Chimie du Solide Miéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérate Appliquée, B.P. 239, 54506, Vandoeuvre-lès-Nancy Cédex, France

    E. McRae, M. Lelaurain & J. F. Maréché

Authors
  1. B. Sundqvist
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. E. Andersson
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. McRae
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Lelaurain
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. F. Maréché
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sundqvist, B., Andersson, O.E., McRae, E. et al. A study of temperature and pressure-induced structural and electronic changes in SbCl5 intercalated graphite: Part III. Analysis of the T and p dependence of the c-axis resistivity. Journal of Materials Research 10, 436–446 (1995). https://doi.org/10.1557/JMR.1995.0436

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.1995.0436

Search

Navigation