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UV-induced reduction of Ag+ by diazene sulphonates: new method of metallisation of surfaces

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Abstract

The metallisation of surfaces would be technologically very simple if it were possible to use the properties of the substances that decompose upon UV irradiation and produce species with a strong redox potential. In this work, diazene sulphonates are presented as possible reducing agents for Ag+ in aqueous solutions and in thin solid layers. The photo-formation of Agm+n clusters in the presence of diazene sulphonates in solutions was investigated via UV-VIS spectroscopy. Significant differences were observed in the electrical properties of surfaces after photo reduction; these occurred without any additional reducing agent.

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Correspondence to Oskar Nuyken.

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Dedicated to Prof. Dr. Robert Kerber on the occasion of his 90th birthday

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Baranovicova, E., Stasko, A. & Nuyken, O. UV-induced reduction of Ag+ by diazene sulphonates: new method of metallisation of surfaces. Chem. Pap. 70, 1425–1430 (2016). https://doi.org/10.1515/chempap-2016-0077

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  • DOI: https://doi.org/10.1515/chempap-2016-0077

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