Chemical Papers

, Volume 70, Issue 10, pp 1370–1379 | Cite as

Promotional effect of cobalt addition on catalytic performance of Ce0.5Zr0.5O2 mixed oxide for diesel soot combustion

  • Yan-Hua Zhang
  • Hai-Long Zhang
  • Yi Cao
  • Yi Yang
  • Bao-Qiang Xu
  • Ming Zhao
  • Mao-Chu Gong
  • Hai-Di Xu
  • Yao-Qiang Chen
Original Paper


A series of Co-modified Ce0.5Zr0.5O2 catalysts with different concentrations of Co (mass %: 0, 2, 4, 6, 8, 10) was investigated for diesel soot combustion. Ce0.5Zr0.5O2 was prepared using the coprecipitation method and Co was loaded onto the oxide using the incipient wetness impregnation method. The activities of the catalysts were evaluated by thermogravimetric (TG) analysis and temperature-programmed oxidation (TPO) experiments. The results showed the soot combustion activities of the catalysts to be effectively improved by the addition of Co, 6 % Co/Ce0.5Zr0.5O2 and that the 8 % Co/Ce0.5Zr0.5O2 catalysts exhibited the best catalytic performance in terms of lower soot ignition temperature (Ti at 349°C) and maximal soot oxidation rate temperature (Tm at 358°C). The reasons for the improved activity were investigated by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), H2 temperature-programmed reduction (H2-TPR), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). These results revealed that the presence of Co could lower the reduction temperature due to the synergistic effect between Co and Ce, thereby improving the activity of the catalysts in soot combustion. The 6 % Co catalyst exhibited the best catalytic performance, which could be attributed to the greater amounts of Co3+ and surface oxygen species on the catalyst.


Co3O4 Ce0.5Zr0.5O2 catalytic performance diesel soot combustion 


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Supplementary material

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Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2016

Authors and Affiliations

  • Yan-Hua Zhang
    • 1
  • Hai-Long Zhang
    • 2
  • Yi Cao
    • 1
  • Yi Yang
    • 1
  • Bao-Qiang Xu
    • 1
  • Ming Zhao
    • 1
  • Mao-Chu Gong
    • 1
  • Hai-Di Xu
    • 3
  • Yao-Qiang Chen
    • 1
    • 4
    • 5
  1. 1.Key Laboratory of Green Chemistry and Technology of the Ministry of Education, College of ChemistrySichuan UniversityChengduChina
  2. 2.College of Chemical EngineeringSichuan UniversityChengduChina
  3. 3.Institute of New Energy and Low-Carbon TechnologySichuan UniversityChengduChina
  4. 4.Sichuan Provincial Vehicular Exhaust Gases Abatement Engineering Technology CenterChengduChina
  5. 5.Sichuan Provincial Environmental Catalytic Material Engineering Technology CenterChengduChina

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