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Synthesis and properties of new N,N′-phenyltetrazole podand

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Abstract

The synthesis of a new chromogenic N,N′-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity and sensitivity of these electrodes towards alkali, alkali-earth, transition and heavy metal cations in aqueous solution were tested. The relation between the carrier structure and membrane plasticisers was investigated.

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Authors and Affiliations

  1. Department of Chemistry and Technology of Functional Materials, Gda´nsk University of Technology, Narutowicza St. 11/12, 80-233, Gda´nsk, Poland

    Agnieszka Pazik, Beata Kami´nska & Anna Skwierawska

  2. Department of Analytical Chemistry, Faculty of Chemistry, University of Gda´nsk, Wita Stwosza St. 63, 80-952, Gdansk, Poland

    Sandra Nakonieczna & Tadeusz Ossowski

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  1. Agnieszka Pazik
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  2. Beata Kami´nska
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  3. Anna Skwierawska
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  4. Sandra Nakonieczna
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  5. Tadeusz Ossowski
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Correspondence to Agnieszka Pazik.

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Pazik, A., Kami´nska, B., Skwierawska, A. et al. Synthesis and properties of new N,N′-phenyltetrazole podand. Chem. Pap. 70, 253–264 (2016). https://doi.org/10.1515/chempap-2015-0209

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