Abstract
In this study, trimetallic catalysts were prepared via the co-precipitation and impregnation methods. In order to investigate the effect of impregnation on the catalytic activity and crystallite size, a trimetallic catalyst, Fe—Ni—Ce, was prepared through the co-precipitation method in one set of experiments, and cerium was impregnated with the Ni—Fe mixture in the final stage of the preparation in another set. Fourier transform infrared spectroscopy was employed to confirm the formation of trimetallic catalysts and the success of the impregnation method. The Brunauer-Emmett-Teller nitrogen adsorption isotherm exhibits a high specific surface area (approximately 39 m2 g−1) for the nanoparticles obtained by the impregnation method. The crystallography and morphology of the trimetallic catalysts thus prepared were characterised by X-ray diffraction and scanning electron microscopy. UV-VIS spectroscopy and methylene blue dye degradation tests were also performed to investigate the catalytic activity of the synthesised catalysts. The crystalline size was found to be smaller for the catalysts prepared by the impregnation method. In addition, the samples synthesised using the cerium impregnation method showed superior activity in the methylene blue dye degradation test. The effect of the catalyst dosage on dye degradation, as well as the effect of the initial dye concentration on the catalyst activity, was also studied for both methods.
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Aguila, G., Guerrero, S., & Araya, P. (2013). Effect of the preparation method and calcination temperature on the oxidation activity of CO at low temperature on CuO—CeO2/SiO2 catalysts. Applied Catalysis A: General, 462–463, 56–63. DOI: 10.1016/j.apcata.2013.04.032.
Ahmed, R., Jamil, R., & Ansari, M. S. (2014). Synthesis and characterization of ternary Pt-Ni-M/C (M = Cu, Fe, Ce, Mo, W) nano-catalysts for low temperature fuel cells. IOP Conference Series: Materials Science and Engineering, 60, 012044. DOI: 10.1088/1757-899x/60/1/012044.
Allaedini, G., Tasirin, S. M., Aminayi, P., Yaakob, Z., & Talib, M. Z. M. (2015a). Bulk production of bamboo-shaped multi-walled carbon nanotubes via catalytic decomposition of methane over tri-metallic Ni—Co—Fe catalyst. Reaction Kinetics, Mechanisms and Catalysis. DOI: 10.1007/s11144-015-0897-1. (in press)
Allaedini, G., Aminayi, P., & Tasirin, S. M. (2015b). The effect of alumina and magnesia supported germanium nanoparticles on the growth of carbon nanotubes in the chemical vapor deposition method. Journal of Nanomaterials, 961231.
Anderson, J. A. (2011). Supported metals in catalysis. Singapore, Singapore: World Scientific.
Ansari, A., & Kaushik, A. (2010). Synthesis and optical properties of nanostructured Ce(OH)4. Journal of Semiconductors, 31, 033001. DOI: 10.1088/1674-4926/31/3/033001.
Bae, E. Y., & Choi, W. Y. (2002). Highly enhanced photoreductive degradation of perchlorinated compounds on dye-sensitized metal/TiO2 under visible light. Environmental Science & Technology, 37, 147–152. DOI: 10.1021/es025617q.
Bhatt, A. S., Bhat, D. K., Santosh, M. S., & Tai, C. W. (2011). Chitosan/NiO nanocomposites: a potential new dielectric material. Journal of Materials Chemistry, 21, 13490–13497. DOI: 10.1039/c1jm12011e.
Channei, D., Inceesungvorn, B., Wetchakun, N., Ukritnukun, S., Nattestad, A., Chen, J., & Phanichphant, S. (2014). Photocatalytic degradation of methyl orange by CeO2 and Fe-doped CeO2 films under visible light irradiation. Scientific Reports, 4, 5757. DOI: 10.1038/srep05757.
Chen, C., Cao, J. J., Cargnello, M., Fornasiero, P., & Gorte, R. J. (2013). High-temperature calcination improves the catalytic properties of alumina-supported Pd@ceria prepared by self assembly. Journal of Catalysis, 306, 109–115. DOI: 10.1016/j.jcat.2013.06.013.
Cong, Y., Zhang, J. L., Chen, F., Anpo, M., & He, D. N. (2007). Preparation, photocatalytic activity, and mechanism of nano-TiO2 co-doped with nitrogen and iron (III). The Journal of Physical Chemistry C, 111, 10618–10623. DOI: 10.1021/jp0727493.
Contreras, C., Sugita, S., & Ramos, E. (2006). Preparation of sodium aluminate from basic aluminum sulfate. AZojomo, 8, 122. DOI: 10.2240/azojomo0220.
Costa, N. J. S., & Rossi, L. M. (2012). Synthesis of supported metal nanoparticle catalysts using ligand assisted methods. Nanoscale, 4, 5826–5834. DOI: 10.1039/c2nr31165h.
de Jong, K. P. (2009). Synthesis of solid catalysts. New York, NY, USA: Wiley.
Dong, Y. R., Ren, X. R., Wang, M. J., He, Q., Chang, L. P., & Bao, W. R. (2013). Effect of impregnation methods on sorbents made from lignite for desulfurization at middle temperature. Journal of Energy Chemistry, 22, 783–789. DOI: 10.1016/s2095-4956(13)60104-7.
Ertl, G., Knözinger, H., & Weitkamp, J. (2008). Preparation of solid catalysts. New York, NY, USA: Wiley.
Gaber, A., Abdel-Rahim, M., Abdel-Latief, A., & Abdel-Salam, M. N. (2014). Influence of calcination temperature on the structure and porosity of nanocrystalline SnO2 synthesized by a conventional precipitation method. International Journal of Electrochemistry Science, 9, 81–95.
Georgakilas, V., Gournis, D., Tzitzios, V., Pasquato, L., Guldi, D. M., & Prato, M. (2007). Decorating carbon nanotubes with metal or semiconductor nanoparticles. Journal of Materials Chemistry, 17, 2679–2694. DOI: 10.1039/b700857k.
Gurbani, A., Ayastuy, J. L., González-Marcos, M. P., Herrero, J. E., Guil, J. M., & Gutiérrez-Ortiz, M. A. (2009). Comparative study of CuO—CeO2 catalysts prepared by wet impregnation and deposition-precipitation. International Journal of Hydrogen Energy, 34, 547–553. DOI: 10.1016/j.ijhydene.2008.10.047.
Harraz, F. A., Mohamed, R. M., Rashad, M. M., Wang, Y. C., & Sigmund, W. (2014). Magnetic nanocomposite based on titania-silica/cobalt ferrite for photocatalytic degradation of methylene blue dye. Ceramics International, 40, 375–384. DOI: 10.1016/j.ceramint.2013.06.012.
Inoishi, A., Ida, S., Uratani, S., Okano, T., & Ishihara, T. (2013). Ni—Fe—Ce(Mn,Fe)O2 cermet anode for rechargeable Fe-Air battery using LaGaO3 oxide ion conductor as electrolyte. RSC Advances, 3, 3024–3030. DOI: 10.1039/c2ra23370c.
Jeong, S. W., Son, S. Y., & Lee, D. H. (2010). Synthesis of multi-walled carbon nanotubes using Co—Fe—Mo/Al2O3 catalytic powders in a fluidized bed reactor. Advanced Powder Technology, 21, 93–99. DOI: 10.1016/j.apt.2009.10.008.
Junploy, P., Thongtem, T., Thongtem, S., & Phuruangrat, A. (2014). Decolorization of methylene blue by Ag/SrSnO3 composites under ultraviolet radiation. Journal of Nanomaterials, 2014, 261395. DOI: 10.1155/2014/261395.
Kalwar, N. H., Sirajuddin, Soomro, R. A., Sherazi, S. T. H., Hallam, K. R., & Khaskheli, A. R. (2014). Synthesis and characterization of highly efficient nickel nanocatalysts and their use in degradation of organic dyes. International Journal of Metals, 2014, 126103. DOI: 10.1155/2014/126103.
Kathyayini, H., Reddy, K. V., Nagy, J., & Nagaraju, N. (2008). Synthesis of carbon nanotubes over transition metal ions supported on Al(OH)3. Indian Journal of Chemistry, 47, 663–668.
Khantimerov, S. M., Kukovitsky, E. F., Sainov, N. A., & Suleimanov, N. M. (2013). Fuel cell electrodes based on carbon nanotube/metallic nanoparticles hybrids formed on porous stainless steel pellets. International Journal of Chemical Engineering, 2013, 157098. DOI: 10.1155/2013/157098.
Kumar, M., & Ando, Y. (2010). Chemical vapor deposition of carbon nanotubes: a review on growth mechanism and mass production. Journal of Nanoscience and Nanotechnology, 10, 3739–3758. DOI: 10.1166/jnn.2010.2939.
Lee, S., & Choi, S. U. S. (1996). Application of metallic nanoparticle suspensions in advanced cooling systems. In Proceedings of the International Mechanical Engineering Congress and Exhibition, November 17–22, 1996. Atlanta, GA, USA: Argonne National Lab.
Li, Y., Cui, R. L., Ding, L., Liu, Y., Zhou, W. W., Zhang, Y., Jin, Z., Peng, F., & Liu, J. (2010). How catalysts affect the growth of single-walled carbon nanotubes on substrates. Advanced Materials, 22, 1508–1515. DOI: 10.1002/adma.200904366.
Li, D. L., Sakai, S., Nakagawa, Y., & Tomishige, K. (2012). FTIR study of CO adsorption on Rh/MgO modified with Co, Ni, Fe, or CeO2 for the catalytic partial oxidation of methane. Physical Chemistry Chemical Physics, 14, 9204–9213. DOI: 10.1039/c2cp41050h.
Lu, A. H., Salabas, E. L., & Schüth, F. (2007). Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angewandte Chemie International Edition, 46, 1222–1244. DOI: 10.1002/anie.200602866.
Maruyama, S., Kojima, R., Miyauchi, Y., Chiashi, S., & Kohno, M. (2002). Low-temperature synthesis of high-purity single-walled carbon nanotubes from alcohol. Chemical Physics Letters, 360, 229–234. DOI: 10.1016/s0009-2614(02)00838-2.
McCready, D. E., Mattigod, S. V., Young, J. S., & McGrail, B. P. (2004). X-ray powder diffraction data for Na 8 (AlSiO 4 )6(ReO 4 ) 2 . Richland, WA, USA: P. N. N. L.
Misi, S. E. E., Ramli, A., & Rahman, F. H. (2011). Characterization of the structure feature of bimetallic Fe—Ni catalysts. Journal of Applied Sciences, 11, 1297–1302. DOI: 10.3923/jas.2011.1297.1302.
Mohamed, R. M., Mkhalid, I. A., Baeissa, E. S., & Al-Rayyani, M. A. (2012). Photocatalytic degradation of methylene blue by Fe/ZnO/SiO2 nanoparticles under visiblelight. Journal of Nanotechnology, 2012, 329082. DOI: 10.1155/2012/329082.
Morss, L. R., Lewis, M. A., Richmann, M. K., & Lexa, D. (2000). Cerium, uranium, and plutonium behavior in glass-bonded sodalite, a ceramic nuclear waste form. Journal of Alloys and Compounds, 303–304, 42–48. DOI: 10.1016/s09258388(00)00601-0.
Mou, X. L., Zhang, B. S., Li, Y., Yao, L. D., Wei, X. J., Su, D. S., & Shen, W. J. (2012). Rod-shaped Fe2O3 as an efficient catalyst for the selective reduction of nitrogen oxide by ammonia. Angewandte Chemie International Edition, 51, 2989–2993. DOI: 10.1002/anie.201107113.
Nunan, J. G. (2000). U.S. Patent No. 6,040,265. Washington, DC, USA: US Patent and Trademark Office.
Ostafin, A., Hoefelmeyer, J., Philippot, K., Pal, T., Knecht, M., Liu, P., & Alonso, F. (2014). Metal nanoparticles for catalysis: Advances and applications (Vol. 17). London, UK: Royal Society of Chemistry.
Paganini, M. C., Chiesa, M., Giamello, E., Coluccia, S., Martra, G., Murphy, D. M., & Pacchioni, G. (1999). Colour centres at the surface of alkali-earth oxides. A new hypothesis on the location of surface electron traps. Surface Science, 421, 246–262. DOI: 10.1016/s0039-6028(98)00795-x.
Pérez-Mendoza, M., Valles, C., Maser, W., Martinez, M., Langlois, S., Sauvajol, J., & Benito, A. (2005). Ni—Y/Mo catalyst for the large-scale CVD production of multi-wall carbon nanotubes. Carbon, 43, 3034–3037. DOI: 10.1016/j.carbon.2005.05.048.
Peternel, I. T., Koprivanac, N., Božić, A. M. L., & Kušić, H. M. (2007). Comparative study of UV/TiO2, UV/ZnO and photo-Fenton processes for the organic reactive dye degradation in aqueous solution. Journal of Hazardous Materials, 148, 477–484. DOI: 10.1016/j.jhazmat.2007.02.072.
Pirola, C., Di Fronzo, A., Comazzi, A., Galli, F., Di Michele, A., & Bianchi, C. (2013). Co based bimetallic catalysts for Fischer-Tropsch synthesis prepared by high power ultrasound. In Proceedings of the Europacat European Congress on Catalysis, September 1–6, 2013, Lyon, France: Institutional Research Information System.
Potti, P. R., & Srivastava, V. C. (2013). Effect of dopants on ZnO mediated photocatalysis of dye bearing wastewater: A review. Materials Science Forum, 757, 165–174. DOI: 10.4028/www.scientific.net/MSF.757.165.
Qi, S. C., Wei, X. Y., Zong, Z. M., & Wang, Y. K. (2013). Application of supported metallic catalysts in catalytic hydrogenation of arenes. RSC Advances, 3, 14219–14232. DOI: 10.1039/c3ra40848e.
Sarkar, A., Dozier, A. K., Graham, U. M., Thomas, G., O’Brien, R. J., & Davis, B. H. (2007). Precipitated iron Fischer-Tropsch catalyst: Effect of carbidization on the morphology of iron oxyhydroxide nanoneedles. Applied Catalysis A: General, 326, 55–64. DOI: 10.1016/j.apcata.2007.03.034.
Shanthi, M., & Kuzhalosai, V (2012). Photocatalytic degradation of an azo dye, Acid Red 27, in aqueous solution using nano ZnO. Indian Journal of Chemistry, 51, 428–434.
Sharma, V K., Siskova, M. K., & Zboril, R. (2013). Magnetic bimetallic Fe/Ag nanoparticles: Decontamination and antimicrobial agents. In R. A. Doong, V K. Sharma, & H. Kim (Eds.). Interactions of nanomaterials with emerging environmental contaminants (Vol. 1150, pp. 193–209). Washington, DC, USA: American Chemical Society.
Síma, J., & Hasal, P. (2013). Photocatalytic degradation of textile dyes in a TiO2/UV system. Chemical Engineering, 32, 79–84. DOI: 10.3303/cet1332014.
Solomon, R., Lydia, I. S., Merlin, J. P., & Venuvanalingam, P. (2012). Enhanced photocatalytic degradation of azo dyes using nano Fe3O4. Journal of the Iranian Chemical Society, 9, 101–109. DOI: 10.1007/s13738-011-0033-8.
Suib, S. L. (2013). New and future developments in catalysis: Catalysis for remediation and environmental concerns. Amsterdam, The Netherlands: Elsevier.
Tessonnier, J. P., & Su, D. S. (2011). Recent progress on the growth mechanism of carbon nanotubes: A review. ChemSusChem, 4, 824–847. DOI: 10.1002/cssc.201100175.
Tkachev, A. G., Melezhik, A. V., Smykov, M. A., Filatova, E. Y., Shuklinov, A. V., D’yachkova, T. P., Stolyarov, A., & Ivanova, I. V. (2012). Synthesis of multi-walled carbon nanotube bundles on the Fe—Co—Mo/Al2O3 catalyst. Theoretical Foundations of Chemical Engineering, 46, 406–412. DOI: 10.1134/s0040579511050150.
Velmurugan, K., Venkatachalapathy, V. S. K., & Sendhilnathan, S. (2010). Synthesis of nickel zinc iron nanoparticles by coprecipitation technique. Materials Research, 13, 299–303. DOI: 10.1590/s1516-14392010000300005.
Vinu, R., & Madras, G. (2010). Environmental remediation by photocatalysis. Journal of the Indian Institute of Science, 90, 189–230.
Wildgoose, G. G., Banks, C. E., & Compton, R. G. (2006). Metal nanoparticles and related materials supported on carbon nanotubes: Methods and applications. Small, 2, 182–193. DOI: 10.1002/smll.200500324.
Wrobleski, J. T., & Boudart, M. (1992). Preparation of solid catalysts: an appraisal. Catalysis Today, 15, 349–360. DOI: 10.1016/0920-5861(92)85002-4.
Wu, H. T., Hu, R. H., Zhou, T. T., Li, C., Meng, W. W., & Yang, J. (2015). A novel efficient boron-doped LaFeO3 photocatalyst with large specific surface area for phenol degradation under simulated sunlight. CrystEngComm, 17, 3859–3865. DOI: 10.1039/c5ce00288e.
Zhang, H., Zong, R. L., & Zhu, Y. F. (2009). Photocorrosion inhibition and photoactivity enhancement for zinc oxide via hybridization with monolayer polyaniline. The Journal of Physical Chemistry C, 113, 4605–4611. DOI: 10.1021/jp810748u.
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Allaedini, G., Tasirin, S.M. & Aminayi, P. Synthesis of Fe—Ni—Ce trimetallic catalyst nanoparticles via impregnation and co-precipitation and their application to dye degradation. Chem. Pap. 70, 231–242 (2016). https://doi.org/10.1515/chempap-2015-0190
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DOI: https://doi.org/10.1515/chempap-2015-0190