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Synthesis of lanthanide-based SBA-15 mesoporous hybrids by a novel route

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Abstract

The ligand N2, N6-bis(2-hydroxyethyl)pyridine-2,6-dicarboxamide (L or BHPC) was synthesised by modification of 2,6-pyridinedicarboxylic acid then used to construct the lanthanide-based mesoporous material Tb-BHPC-SBA-15. In the structure of the resulting Tb-BHPC-SBA-15, lanthanide ions were chelated by the BHPC ligand and the Tb-BHPC complexes were anchored into the SBA-15 host formed by the reaction between the hydroxyl group and the active Si-OH. The mesoporous material Tb-BHPC-SBA-15 was characterised by UV, small-angle X-ray diffraction (SAXRD) patterns, nitrogen adsorption/desorption isotherms and fluorescence spectra. The results indicate that the ligand and lanthanide ions were introduced into the SBA-15 host and the mesoporous material Tb-BHPC-SBA-15 exhibited the characteristic luminescence of Tb3+.

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Authors and Affiliations

  1. Department of Chemistry, College of Food Science & Technology, Shanghai Ocean University, Shanghai, 201306, China

    Zheng Li, Jing-Jian Zhou, Si-Yu Zuo, Xiao Yuan, Chen-Chen Ma & Yi-Shan Song

  2. State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai, 200092, China

    Hua Zhang

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  1. Zheng Li
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  2. Jing-Jian Zhou
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  3. Si-Yu Zuo
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  4. Xiao Yuan
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  5. Chen-Chen Ma
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  6. Yi-Shan Song
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  7. Hua Zhang
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Correspondence to Yi-Shan Song.

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Li, Z., Zhou, JJ., Zuo, SY. et al. Synthesis of lanthanide-based SBA-15 mesoporous hybrids by a novel route. Chem. Pap. 69, 1625–1632 (2015). https://doi.org/10.1515/chempap-2015-0172

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