Chemical Papers

, Volume 69, Issue 9, pp 1211–1218 | Cite as

Polymeric ionic liquids: a strategy for preparation of novel polymeric materials

  • Manoochehr FarzinEmail author
  • Keyvan Nosratzadegan
  • Jamshid Azarnia
  • Mohammad Ferdosi
Original Paper


A novel polymeric ionic liquid (PIL), bearing high C-N and N-N content, potentially suitable for new safe energetic materials and catalyst supports was introduced. The PIL was prepared by way of radical co-polymerisation of 1-vinyl-3-p-nitrobenzylimidazolium bromide and 1-vinylimidazole at 80°C using azobisisobutyronitrile (AIBN) as an initiator. The PIL thus produced was successfully transformed into NO3@PIL and N3@PIL for potential application as safe energetic materials and/or catalyst supports. The polymers were obtained in quantitative yields and were characterised by NMR, FTIR, DSC and TGA data. This study reveals the adequate thermal stability of novel salt-based nitrogen-rich polymeric ionic liquids for application as safe energetic materials and/or supports in heterogeneous catalysis.


energetic salts polyionic liquid polymer nitrogen-rich polymer catalyst supports 


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Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2015

Authors and Affiliations

  • Manoochehr Farzin
    • 1
    Email author
  • Keyvan Nosratzadegan
    • 1
  • Jamshid Azarnia
    • 2
  • Mohammad Ferdosi
    • 1
  1. 1.Chemistry DepartmentMalek Ashtar University of TechnologyShahinshahr, IsfahanIran
  2. 2.Chemistry DepartmentTarbiat Modares University of TechnologyTehranIran

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