Abstract
Poly(2-fluoroaniline) was prepared by both chemical and electrochemical polymerization in acidic medium. Characterization of poly(2-fluoroaniline) was accomplished experimentally using ultraviolet-visible, Fourier transform infrared, differential scanning calorimetry, thermal gravimetric analysis, and X-ray diffraction techniques, respectively. Scanning electron microscopy studies revealed globular morphology of chemically synthesized poly(2-fluoroaniline). The cyclic voltammetric studies revealed diffusion-controlled phenomenon in electrochemically synthesized poly(2-fluoroaniline).
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Kim, E., Lee, K. Y., Lee, M. H., Shen, J. S., and Rhee, S. B. (1997), Synth. Met. 85, 1367, 1368.
Kittlesen, G. P., White, H. S., and Wrighton M. S. (1984), J. Am. Chem. Soc. 106, 7389–7396.
Huang, W. S. and Park, J. M. (1987), J. Chem. Soc. Chem. Commun. 856–858.
Aldissi, M. (1984), J. Chem. Soc. Chem. Commun. 1347, 1348.
Pandey, S. S., Annapoorni, S., and Malhotra, B. D. (1993), Macromolecules 26, 3190–3193.
Inoue, H. and Yoneyama, H. (1987), J. Electroanal. Chem. 233, 291–294.
Chen, J. C. W., Wnek, E., Karasz, F. E., and Hirsch, J. A. (1981), Macromolecules 14, 479–482.
Haupt, S. G., Riley, D. R., Zhao, J., and McDevitt, J. T. (1993), J. Phys. Chem. 97, 7796–7799.
Yoshino, K., Nakajima, S., and Sugimoto, R. (1987), Jpn. J. Appl. Phys. 26, L-1038, L-1039.
Dao, L. H., Leclerc, M., Guay, J., and Chenalier, J. W. (1989), Synth. Met. 29, E377-E382.
Leclerc, M., Guay, J., and Dao, L. H. (1989), Macromolecules 22, 649–653.
Gruger, A., Novak, A., Regis, A., and Colomban, P. (1994), J. Mol. Struct. 328, 153–167.
Snauwaert, P., Lazzaroni, R., Riga, J., and Verbist, J. J. (1887), Synth. Met. 18, 335–340.
Kang, D.-P. and Yun, M.-S. (1989), Synth. Met. 29, E343-E348.
Prasad, B. M., Singh, D., and Mishra, R. A. (1996), J. Polym. Mater. 13, 305–311.
Ray, A., Asturias, G. E., Kershner, D. L., Richter, A. F., Epstein, A. J., and MacDiarmid, A. G., (1989), Synth. Met. 29, E141-E150.
Huang, W. S. and MacDiarmid, A. G. (1993), Polymer 34, 1833–1845.
Penneau, J. P., Lapkowski, M., and Genies, E. M. (1989), N. J. Chem. 13, 449–453.
Cattarin, S., Doubova, L., Mangoli, G., and Zotti, G. (1988), Electrochemica Acta 33, 1077–1084.
Pouget, J. P., Jozefowicz, M. E., Epstein, A. J., Tang, X., and MacDiarmid, A. G. (1991), Macromolecules 24(3), 779–789.
Kaneto, K. and Yoshino, K. (1987), Jpn. J. Appl. Phys. 26, L1842-L1844.
Pandey, S. S., Gerard, M., Sharma, A. L., and Malhotra, B. D. (2000), J. Appl. Polym. Sci. 75, 149–155.
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Sharma, A.L., Gerard, M., Singhal, R. et al. Synthesis and characterization of fluoro-substituted polyaniline. Appl Biochem Biotechnol 96, 155–165 (2001). https://doi.org/10.1385/ABAB:96:1-3:155
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DOI: https://doi.org/10.1385/ABAB:96:1-3:155