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Comparison of Analytical Properties of Two Liquid Crystalline Stationary Phases by Capillary GC

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Abstract

Two related novel liquid crystals used as gas chromatographic stationary phases were evaluated for their analytical properties and separation capabilities, 2-(1-ethyloctyloxy)-4-(4′-(4-butoxybenzoyloxy)-benzoyloxy)-4′-ethyl-azobenzene (LCC) and azo-(4-ethylbenzyl)-3-(2-(1-ethyloctyloxy)-4-(4-(4-butyloxybenzoyloxy)benzoyloxy)pyridino (LCN). The thermal properties of LCC and LCN were established with differential scanning calorimetry and polarizing microscopy. The comparative study of the retention behavior for the both liquid crystals was also reported. The study of the chromatographic performance of a column coated with liquid crystals in the solid, nematic and liquid state was done using a series of appropriate solutes. The mesogenic compounds exhibit interesting separation for some positional and geometrical isomers in aromatic hydrocarbons, phenols, volatile aromatic compounds and polyaromatic hydrocarbons.

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References

  1. Kelker H (1963) Z Anal Chem 198:254–266. doi:10.1007/BF00486441

    Article  CAS  Google Scholar 

  2. Dewar MJS, Shroeder JP (1964) J Am Chem Soc 86:5235–5239. doi:10.1021/ja01077a039

    Article  CAS  Google Scholar 

  3. Kelker H, Von Schivizhoffen E (1968) Advances in chromatography, vol 6. Marcel Dekker, New York, pp 247–297

    Google Scholar 

  4. Janini GM, Muschik GM, Hanlon CM (1979) Mol Cryst Liq Cryst (Phila Pa) 53:15–27. doi:10.1080/00268947908083980

    Article  CAS  Google Scholar 

  5. Janssen F, Kalidin T (1982) J Chromatogr A 235:323–336. doi:10.1016/S0021-9673(00)85897-5

    Article  CAS  Google Scholar 

  6. Witkiewicz Z (1989) J Chromatogr A 466:37–87. doi:10.1016/S0021-9673(01)84616-1

    Article  CAS  Google Scholar 

  7. Jones BA, Bradshaw JS, Hishioka M, Lee ML (1984) J Org Chem 49:4947–4951. doi:10.1021/jo00199a038

    Article  CAS  Google Scholar 

  8. Ryoo JJ, Jeong YH, Lee KP, Han SO, Lee JH, Kuen JK, Han SC, Hyun MH (2001) Microchem J 68:127–133. doi:10.1016/S0026-265X(00)00139-9

    Article  CAS  Google Scholar 

  9. Shillcock IM, Price GJ (2003) Polymer (Guildf) 44:1027–1034. doi:10.1016/S0032-3861(02)00903-5

    Article  CAS  Google Scholar 

  10. Mazur J, Witkiewiez Z, Dabrowski R (1992) J Chromatogr A 600:123–127. doi:10.1016/0021-9673(92)85446-Z

    Article  CAS  Google Scholar 

  11. Betts TJ (1991) J Chromatogr A 588:231–237. doi:10.1016/0021-9673(91)85028-E

    Article  CAS  Google Scholar 

  12. Witkiewicz Z, Goca B (1987) J Chromatogr A 402:73–85. doi:10.1016/0021-9673(87)80006-7

    Article  CAS  Google Scholar 

  13. Szulc J, Witkiewiez Z, Ziolek A (1983) J Chromatogr A 262:161–174. doi:10.1016/S0021-9673(01)88095-X

    Article  CAS  Google Scholar 

  14. Perez F, Berdagué P, Bayle JP, Courtieu J, Boudah S, Guermouche MH, Sebih S (1996) Bull Soc Chim Fr 133:427–433

    CAS  Google Scholar 

  15. Perez F, Berdagué P, Courtieu J, Bayle JP, Boudah S, Guermouche MH (1996) J Chromatogr A 746:247–254. doi:10.1016/0021-9673(96)00320-2

    Article  CAS  Google Scholar 

  16. Meddour A, Courtieu J, Abdelhadi O, Guermouche S, Guermouche MH (1996) Chromatographia 43:387–392. doi:10.1007/BF02271016

    Article  CAS  Google Scholar 

  17. Perez F, Berdagué P, Bayle JP, Courtieu J, Boudah S, Sebih S, Guermouche MH (1997) J High Resolut Chromatogr 20:379–384. doi:10.1002/jhrc.1240200707

    Article  CAS  Google Scholar 

  18. Ammar-Khodja F, Guermouche S, Guermouche MH, Buerdagué P, Bayle JP (1999) Chromatographia 50:338–345. doi:10.1007/BF02490839

    Article  CAS  Google Scholar 

  19. Saïdat B, Guermouche MH, Canlet C, Berdagué P, Bayle JP (2002) Chromatographia 55:55–61. doi:10.1007/BF02492315

    Article  Google Scholar 

  20. Belaïdi D, Sebih S, Guermouche MH, Bayle JP, Boudah S (2002) C R Chimie 5:591–598

    Google Scholar 

  21. Belaïdi D, Sebih S, Guermouche MH, Bayle JP, Boudah S (2003) Chromatographia 57:207–212. doi:10.1007/BF02491718

    Article  Google Scholar 

  22. Belaïdi D, Sebih S, Boudah S, Guermouche MH, Bayle JP (2005) J Chromatogr A 1087:52–56. doi:10.1016/j.chroma.2005.05.022

    Article  Google Scholar 

  23. Witkiewiec Z (2005) J Chromatogr A 1062:155–174. doi:10.1016/j.chroma.2004.11.042

    Article  Google Scholar 

  24. Janini GM (1982) Advances in chromatography, vol vol. 17. Marcel Dekker, New York, pp 231–277

    Google Scholar 

  25. Betts TJ (1993) J Chromatogr A 641:189–193. doi:10.1016/0021-9673(93)83475-8

    Article  CAS  Google Scholar 

  26. Gritti F, Felix G (2002) Chromatographia 55:523–531. doi:10.1007/BF02492897

    Article  CAS  Google Scholar 

  27. Mossner SG, Lopez de Alda MJ, Sander LC, Lee ML, Wise SA (1999) J Chromatogr A 841:207–228. doi:10.1016/S0021-9673(99)00363-5

    Article  CAS  Google Scholar 

  28. Sander LC, Schneider M, Wise SA, Woolley C (1994) J Microcol Sep 6:115–125

    Article  CAS  Google Scholar 

  29. Poole CF (2003) The essence of chromatography, Elsevier Science, P.O. Box 211, 1000 AE Amsterdam, The Netherlands, p 839

  30. Berdagué P, Perez F, Courtieu J, Bayle JP (1993) Bull Soc Chim Fr 130:475–480

    Google Scholar 

  31. Hassner A, Alexanian V (1978) Tetrahedron Lett 19:4475–4478. doi:10.1016/S0040-4039(01)95256-6

    Article  Google Scholar 

  32. Naikwadi KP, McGovern AM, Karasek FW (1987) Can J Chem 65:970–975. doi:10.1139/v87-165

    Article  CAS  Google Scholar 

  33. Xiaotian Q, Zaide Z, Minggui X, Yongchang Z, Ying T (1998) Talanta 46:45–51. doi:10.1016/S0039-9140(97)00257-9

    Article  CAS  Google Scholar 

  34. Naikwadi KP, Wadgaonkar PP (1998) J Chromatogr A 811:97–103. doi:10.1016/S0021-9673(98)00209-X

    Article  CAS  Google Scholar 

  35. Krupcik J, Valachovicova M, Kraus G (1994) J Chromatogr A 665:111–116. doi:10.1016/0021-9673(94)87038-1

    Article  CAS  Google Scholar 

  36. Dai RJ, Fu RN, Zhou W (1995) J Microcol Sep 7:455–460

    Article  CAS  Google Scholar 

  37. Cook LE, Spangelo RC (1974) Anal Chem 46:122–126. doi:10.1021/ac60337a020

    Article  CAS  Google Scholar 

  38. Witkiewicz Z (1982) J Chromatogr A 251:311–337. doi:10.1016/S0021-9673(00)87023-5

    Article  CAS  Google Scholar 

  39. Abdul-Munem Ali MH, Al-Haidary AA, Al-Mehdaoui MTS (2003) Turk J Chem 27:259–264

    Google Scholar 

Download references

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Authors and Affiliations

  1. Laboratoire de Chromatographie, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediène, B.P. 32, El-Alia, 16111, Bab-Ezzouar, Alger, Algeria

    Mohamed Dahmane, Fatiha Athman, Saïd Sebih, Moulay-Hassane Guermouche & Soulimane Boudah

  2. Laboratoire de Chimie Structurale Organique, Bt. 410, Orsay, Université Paris Sud., 91405, Paris, France

    Jean-Pierre Bayle

Authors
  1. Mohamed Dahmane
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  2. Fatiha Athman
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  3. Saïd Sebih
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  4. Moulay-Hassane Guermouche
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  5. Jean-Pierre Bayle
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  6. Soulimane Boudah
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Correspondence to Soulimane Boudah.

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Dahmane, M., Athman, F., Sebih, S. et al. Comparison of Analytical Properties of Two Liquid Crystalline Stationary Phases by Capillary GC. Chroma 70, 489–495 (2009). https://doi.org/10.1365/s10337-009-1209-6

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  • DOI: https://doi.org/10.1365/s10337-009-1209-6

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