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Synthesis, Characteristics and Evaluation of a New Monolithic Silica Column Prepared from Copolymer Pluronic F127

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Abstract

Monolithic silica columns were prepared via a sol–gel process using tri-block copolymer Pluronic F127 as structure-directing reagent. In this reaction, F127 induced phase separation but also acted as a template leading to a continuous structure of silica skeletons and textural pores as well as the formation of mesopores. The morphology of the monolithic materials was studied by scanning electron microscopy. The capability of separation and loading on this column were demonstrated. Phosphatidylcholine was separated from soy lecithin, demonstrating fast and efficient performance when the column was used for normal phase liquid chromatography.

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References

  1. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nat 359:710–712

    Article  CAS  Google Scholar 

  2. Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL (1992) J Am Chem Soc 114:10834–10843

    Article  CAS  Google Scholar 

  3. Davis ME (2002) Nature 417:813–821

    Article  CAS  Google Scholar 

  4. Stein A (2003) Adv Mater 15:763–775

    Article  CAS  Google Scholar 

  5. Nakanishi K, Soga N (1992) J Non-Cryst Solids 139:1–13

    Article  CAS  Google Scholar 

  6. Feng PY, Bu X, Stucky GD, Pine DJ (2000) J Am Chem Soc 122:994–995

    Article  CAS  Google Scholar 

  7. Liang D, Dai S, Guiochon G (2002) Chem Commun 22:2680–2681

    Article  Google Scholar 

  8. Maekawa H, Esquena J, Bishop S, Solans C, Chmelka BF (2003) Adv Mater 15:591–596

    Article  CAS  Google Scholar 

  9. Zhi-Guo S, Yu-Qi F, Xu L, Shi-Lu D, Yao-Yao R (2004) Microporous Mesoporous Mater 68:55–59

    Article  Google Scholar 

  10. Mohamed FR (2008) Food Sci Technol Int 41:581–587

    Google Scholar 

  11. Yoon CH, Shin BS, Chang HS, Kwon LS, Kim HY, Yoo SE, Yoo SD (2004) Chromatographia 60:399–404

    Article  CAS  Google Scholar 

  12. Sun GY, Horrocks LA (1969) J Lipid Res 10:153–157

    CAS  Google Scholar 

  13. Murphy EJ, Stephens R, Jurkowitz-Alexander M, Horrocks LA (1993) Lipids 28:565–568

    Article  CAS  Google Scholar 

  14. Abidi SL, Mounts TL (1997) J Chromatogr A 773:93–101

    Article  CAS  Google Scholar 

  15. Ignacio DM, Annick R, Didier B (1999) J Chromatogr A 840:31–38

    Article  Google Scholar 

Download references

Acknowledgments

The authors gratefully appreciate the financial support by the National Natural Science Foundation of China (20375010, 20675084), the funds from Hebei Province Programs for Science and Technology Development (NO. 06276479B, 07276407D) and “Bai Ren Project” of Chinese Academy of Sciences.

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Authors and Affiliations

  1. College of Pharmacy, Hebei University, Baoding, 071002, China

    Gengliang Yang, Fengxin Li, Lijuan Wang, Haiyan Liu, Ligai Bai, Weimin Cao & Tao Zhu

  2. Institutes of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China

    Gengliang Yang

  3. Center for Advanced Bioseparation Technology, Department of Chemical Engineering, Inha University, 253 Yonghyun-Dong, Nam-Ku, Incheon, 402-751, South Korea

    Kyung Ho Row

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  1. Gengliang Yang
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  2. Fengxin Li
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  3. Lijuan Wang
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  4. Kyung Ho Row
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  5. Haiyan Liu
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  6. Ligai Bai
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  7. Weimin Cao
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  8. Tao Zhu
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Correspondence to Gengliang Yang.

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Yang, G., Li, F., Wang, L. et al. Synthesis, Characteristics and Evaluation of a New Monolithic Silica Column Prepared from Copolymer Pluronic F127. Chroma 68, 27–31 (2008). https://doi.org/10.1365/s10337-008-0663-x

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  • DOI: https://doi.org/10.1365/s10337-008-0663-x

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