Chromatographia

, Volume 68, Issue 1–2, pp 123–127 | Cite as

CZE Determination of Calixarenes and Related Derivatives Using Acetonitrile as a Modifier

  • Hui Yang
  • Rongjie Zhang
  • Yanyan Lu
  • Baoxian Ye
  • Yangjie Wu
  • Shusheng Zhang
Full Short Communication

Abstract

The applications of third-generation host compound calixarenes have been restricted due to their high price and shortage of supply. To obtain high pure calixarenes with high yield, synthesis strategy and analytical method investigations are necessary. The present work describes capillary zone electrophoresis (CZE) for the separation and determination of calixarene derivatives under the optimized CZE conditions within 20 min. The CZE method was evaluated with linear ranges, detection limits, recoveries and repeatability. The results indicated that the method was accurate and reproducible. As expected, it could be utilized to separate and evaluate calixarene derivatives during their synthesis and purification.

Keywords

Capillary zone electrophoresis Calixarene derivatives 

Notes

Acknowledgments

The authors would like to show their appreciation of the support of Henan University Innovation People Grant of 2004 and NSFs of China (20575060, 20775073). And also thank Dr. Julie Rimes for assistance with editing the text.

References

  1. 1.
    Cadogan F, Kane P, McKervey MA, Diamond D (1999) Anal Chem 71:5544–5548CrossRefGoogle Scholar
  2. 2.
    Kimura K, Yajima S, Tatsumi K, Yokoyama M, Oue M (2000) Anal Chem 72:5290–5294CrossRefGoogle Scholar
  3. 3.
    Kim TH, Lee JK, Bok JH, Kim JS, Kim H (2004) Electrochim Acta 49:3759–3763CrossRefGoogle Scholar
  4. 4.
    Zheng H, Dong H, Yan Z, Wen L, Zhang SS, Ye BX (2006) Electrochemistry 18:2115–2120Google Scholar
  5. 5.
    Kivlehan F, Mace WJ, Moynihan HA, Arrigan DWM (2007) Anal Chim Acta 585:154–160CrossRefGoogle Scholar
  6. 6.
    Sakly H, Mlika R, Bonnamour I, Aouni F, Ben Ouada H, Jaffrezic N (2007) Electrochim Acta 52:3697–3703CrossRefGoogle Scholar
  7. 7.
    Shohat D, Grahka E (1994) Anal Chem 66:747–752CrossRefGoogle Scholar
  8. 8.
    Pena MS, Zhang Y, Warner IM (1997) Anal Chem 69:3239–3245CrossRefGoogle Scholar
  9. 9.
    Wang Z, Chen Y, Yuan H, Huang Z, Liu G (2000) Electrophoresis 21:1620–1626CrossRefGoogle Scholar
  10. 10.
    Wu X, Liu HX, Liu H, Zhang SS, Haddad PR (2003) Anal Chim Acta 478:191–197CrossRefGoogle Scholar
  11. 11.
    Sokoliess T, Gronau M, Menyes U (2003) Electrophoresis 24:1648–1657CrossRefGoogle Scholar
  12. 12.
    Lim HJ, Lee HS, Kim LW (1998) Chromatographia 48:422–427CrossRefGoogle Scholar
  13. 13.
    Kolchenko OL, Lipkowski J, Kalchenko VL (1998) J Chromatogr Sci 36:269–276Google Scholar
  14. 14.
    Yu XD, Fang H, Lin L, Han HM, Wu CY (2001) Chromatographia 53:519–526CrossRefGoogle Scholar
  15. 15.
    Li LS, Da SL, Feng YQ, Liu M (2004) J Chromatogr A 1040:53–58CrossRefGoogle Scholar
  16. 16.
    Dong C, Zeng Z, Li X (2005) Talanta 66:721–727CrossRefGoogle Scholar
  17. 17.
    Ding C, Qu K, Li Y, Hu K, Liu H, Ye B, Wu Y, Zhang SS (2007) J Chromatogr A 1170:73–81CrossRefGoogle Scholar
  18. 18.
    Ludwiq FJ, Bailie AG (1984) Anal Chem 56:2081–2085CrossRefGoogle Scholar
  19. 19.
    Saito Y, Ohta H, Terasaki H (1995) JHRC 19:475–477CrossRefGoogle Scholar
  20. 20.
    Bianco A, Gasparrini F, Maggini M (1997) J Am Chem Soc 119:7550–7554CrossRefGoogle Scholar
  21. 21.
    Kalchenko OI, Lipkowski J, Nowakowski R, Kalchenko VI, Visotsky MA, Markosky LN (1997) J Chromatogr Sci 35:49–54Google Scholar
  22. 22.
    Thibodeaux SJ, Sanchez PM, Zhang Y, Shamsi SA, Warner IM (1999) Chromatographia 49:142–147CrossRefGoogle Scholar
  23. 23.
    Zhang Y, Warner IM (1994) J Chromatogr A 688:293–300CrossRefGoogle Scholar
  24. 24.
    Ding C, Han P, Song J, Liu HX, Zhang SS, Ye B, Wu Y (2006) Anal Chim Acta 566:246–252CrossRefGoogle Scholar
  25. 25.
    Wang F, Khaledi MG (1999) J Chromatogr B 731:187–194CrossRefGoogle Scholar
  26. 26.
    Li Y, Cui S, Cheng Y, Chen X, Hu Z (2004) Anal Chim Acta 508:17–24CrossRefGoogle Scholar
  27. 27.
    Gutsche CD, Iqbal M (1990) Org Synth 68:234–237Google Scholar
  28. 28.
    Gutsche CD, Dhawan B, Leonis M, Stewart D (1990) Org Synth 68:238–242Google Scholar
  29. 29.
    Munch JH, Gutsche CD (1990) Org Synth 68:243–247Google Scholar
  30. 30.
    Gutsche CD, Lin LG (1986) Tetrahedron 42:1633–1639CrossRefGoogle Scholar
  31. 31.
    Zhang SS (2000) Postodctoral Report of Zhengzhou University of ChinaGoogle Scholar

Copyright information

© Vieweg+Teubner | GWV Fachverlage GmbH 2008

Authors and Affiliations

  • Hui Yang
    • 1
  • Rongjie Zhang
    • 2
  • Yanyan Lu
    • 1
  • Baoxian Ye
    • 1
  • Yangjie Wu
    • 1
  • Shusheng Zhang
    • 1
  1. 1.Chemistry Department, Key Laboratory of Chemical Biology and Organic Chemistry of HenanZhengzhou UniversityZhengzhouChina
  2. 2.Center of Disease Control and Prevention of HenanZhengzhouChina

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