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Enantioseparation of Binaphthol and Its Derivatives on Cellulose Tris(3,5-dimethylphenyl carbamate)

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Abstract

A Chiralcel OD-H column was used for the normal phase enantioseparation of binaphthol and its derivatives. Unexpectedly, binaphthol and its dibromo-substituted analogue could not be enantioseparated fully, whereas its ether and ester derivatives gave complete or partial resolution. Aspects of the chiral recognition are discussed further through calculated thermodynamic parameters.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (No. 20705031), the Natural Science Foundation of Fujian Province of China (No. U0750017), and the Education Bureau of Fujian Province of China (No. JA05301).

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Authors and Affiliations

  1. Department of Chemistry and Environmental Science, Zhangzhou Normal University, Zhangzhou, 363000, China

    Wen Weng, Fengping Zhan, Jing Fu, Ting Li & Xiaojian Chen

  2. College of Oceanography and Environmental Science, Xiamen University, Xiamen, 361005, China

    Xiaojia Huang

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  1. Wen Weng
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  2. Fengping Zhan
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  3. Jing Fu
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  4. Ting Li
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  5. Xiaojian Chen
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  6. Xiaojia Huang
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Correspondence to Wen Weng.

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Weng, W., Zhan, F., Fu, J. et al. Enantioseparation of Binaphthol and Its Derivatives on Cellulose Tris(3,5-dimethylphenyl carbamate). Chroma 67, 119–123 (2008). https://doi.org/10.1365/s10337-007-0456-7

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  • DOI: https://doi.org/10.1365/s10337-007-0456-7

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