Chromatographia

, Volume 67, Issue 1–2, pp 119–123 | Cite as

Enantioseparation of Binaphthol and Its Derivatives on Cellulose Tris(3,5-dimethylphenyl carbamate)

  • Wen Weng
  • Fengping Zhan
  • Jing Fu
  • Ting Li
  • Xiaojian Chen
  • Xiaojia Huang
Full Short Communication

Abstract

A Chiralcel OD-H column was used for the normal phase enantioseparation of binaphthol and its derivatives. Unexpectedly, binaphthol and its dibromo-substituted analogue could not be enantioseparated fully, whereas its ether and ester derivatives gave complete or partial resolution. Aspects of the chiral recognition are discussed further through calculated thermodynamic parameters.

Keywords

Column liquid chromatography Enantiomer separation Binaphthyl compound Apparent thermodynamic parameter 

Notes

Acknowledgments

The project was supported by the National Natural Science Foundation of China (No. 20705031), the Natural Science Foundation of Fujian Province of China (No. U0750017), and the Education Bureau of Fujian Province of China (No. JA05301).

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Copyright information

© Friedr. Vieweg & Sohn Verlag/GWV Fachverlage GmbH 2007

Authors and Affiliations

  • Wen Weng
    • 1
  • Fengping Zhan
    • 1
  • Jing Fu
    • 1
  • Ting Li
    • 1
  • Xiaojian Chen
    • 1
  • Xiaojia Huang
    • 2
  1. 1.Department of Chemistry and Environmental ScienceZhangzhou Normal UniversityZhangzhouChina
  2. 2.College of Oceanography and Environmental ScienceXiamen UniversityXiamenChina

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