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Chromatographia

, Volume 61, Issue 3–4, pp 197–200 | Cite as

A Large Volume Injection Procedure for GC-MS Determination of PAHs and PCBs

  • Z. Večeřa
  • A. Bartošíková
  • J. Sklenská
  • P. Mikuška
Article

Abstract

A simple on-column injection system for large volume of liquid samples for the GC-MS determination of traces of PAHs and PCBs has been investigated. A deactivated fused silica capillary 20 m × 0.53 mm I.D. and 2 meters of an HP5 column (0.53 mm,1 μm film thickness) were used as retention gaps. Injection volumes of 80 μL for PAHs and 90 μL for PCBs, allow determination of 5–50 ng L−1 PAHs and 11–44 ng L−1 PCBs in hexane solution with an RSD of < 10%. The method has been used for the determination of PCBs and PAHs in soil sample.

Keywords

Gas chromatography-mass spectrometry Large volume injection Polycyclic aromatic hydrocarbons Polychlorinated biphenyls Soil samples 

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Notes

Acknowledgments.

This work was carried out under grants of GA ČR No. 526/03/1182 and No. 525/04/0011.

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Copyright information

© Friedr. Vieweg&Sohn/GWV Fachverlage GmbH 2004

Authors and Affiliations

  • Z. Večeřa
    • 1
  • A. Bartošíková
    • 1
  • J. Sklenská
    • 1
  • P. Mikuška
    • 1
  1. 1.Institute of Analytical ChemistryAcademy of Sciences of the Czech RepublicBrnoCzech Republic

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