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Journal of Phase Equilibria

, 19:426 | Cite as

Phase relationships in the systems RE2O3-Al2O3-SiO2 (RE = rare earth element, Y, and Sc)

  • U. Kolitsch
  • H. J. Scifert
  • F. Aldinger
Section I: Basic and Applied Research

Abstract

A literature survey and recent results on phase relationships in the quasi-ternary systems RE2O3-Al2O3-SiO2 are given. The investigated systems exhibit extended ternary solid solutions, RE9.33+2x(Si1_xAlxO4)6O2 (withx up to ~0.33) and/or RE4Al2(1_X)Si2xO9+x (withx up to ~0.3), which are based on the quasi-binary phases RE9.33(SiO4)6O2 and RE4A12O9, respectively. The former is encountered only in systems with laige RE3+ ions (e.g., La3+), whereas the latter is found in systems with small RE3+ ions (e.g., Yb3+); in systems with medium-sized KE3+ ions (e.g., Gd3+) both types exist Quasi-ternary compounds are known only in the La, Ce, and Sc systems. Severe discrepancies in reported ternary eutectic temperatures led to a need for their accurate redeteimination.

Keywords

Phase Equilibrium Isothermal Section Eutectic Temperature Sialon Glass Phys 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© ASM International 1998

Authors and Affiliations

  • U. Kolitsch
    • 1
  • H. J. Scifert
    • 1
  • F. Aldinger
    • 1
  1. 1.Institut für Nichtmetallische Anorganische Materialien, Pulvermetallurgisches LaboratoriumMax-Planck-Institutfür Metallforschung, and UniversitÄt StuttgartStuttgartGermany

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