Modification to the van der waals equation of state
In this paper, we modify the VDW equation of state by adding a temperature factor to it. As a result, we produce a good phase diagram and the correlation of the reduced pressure and the reduced temperature when a balanced liquid-gas coexistence canonical argon-like system is considered.
KeywordsTemperature Factor Canonical System Canonical Partition Function Mean Spherical Approximation Tiny Region
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- 4.H. Eyring, D. Henderson, B. Jones Stover, and E.M. Eyring: “Statistical Mechanics and Dynamics,” 1978, pp. 620–21.Google Scholar
- 5.Jianxiang Tian, Yuanxing Gui, Guanghai Guo, Yan Lv, Suhong Zhang, and Wei Wang: “General Relativity and Gravitation,” 2003, 35, gr-qc/0304009. In press.Google Scholar
- 6.E.A. Guggenheim: J. Chem. Phys., 1945, 13(7).Google Scholar
- 7.E.A. Guggenheim: Thermodynamics, North-Holland Physics Publishing, 1967, pp. 138–39.Google Scholar