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Journal of Phase Equilibria

, 23:409 | Cite as

Thermodynamic assessment of the Cu-In binary system

  • H. S. Liu
  • Y. Cui
  • K. Ishida
  • X. J. Liu
  • C. P. Wang
  • I. Ohnuma
  • R. Kainuma
  • Z. P. Jin
Basic And Applied Research

Abstract

On the basis of thermodynamic properties and phase diagram data, the Cu-In binary system was thermodynamically assessed. The phases in this system were modeled using the Redlich-Kister expression for the Gibbs energies of the solution phases, adopting three-sublattice models for γ and η′, and assuming stoichiometric compounds for other intermetallic phases. Then a set of consistent parameters was obtained by the CALPHAD method, by which reasonable agreement can be realized between the thermodynamic properties for various phases and phase relations of this system.

Keywords

Gibbs Energy Invariant Reaction Liquid Copper Phase Diagram Data Molar Gibbs Energy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1934Wei:.
    F. Weibke and H. Eggers: “The Phase Diagram of the System Copper-Indium,” Z. Anorg. Allg. Chem., 1934, 220, pp. 273–92.CrossRefGoogle Scholar
  2. 1940Hum:.
    W. Hume-Rothery, G.V. Raynor, and H.K. Packer: “The Constitution and Structure of Alloys of Intermediate Composition in the Systems Copper-Indium, Copper-Aluminum, Copper-Germanium, Silver-Aluminum, and Silver-Germanium,” J. Inst. Met., 1940, 66, pp. 209–39.Google Scholar
  3. 1949Owe:.
    E.A. Owen and D.P. Morris: “The Application of X-Ray Methods to the Determination of Phase Boundaries in Metallurgical Equilibrium Diagrams,” J. Inst. Met., 1949, 76, pp. 145–68.Google Scholar
  4. 1951Rey:.
    J. Reynolds, W.A. Wiseman, and W. Hume-Rothery: “The Equilibrium Diagram of the System Copper-Indium in the Region 25–35 at.% Indium,” J. Inst. Met., 1951, 80, pp. 637–40.Google Scholar
  5. 1953Jon:.
    R.O. Jones and E.A. Owen: “X-Ray Determination of the Alpha-Phase Boundary of the Copper-Indium Alloy System,” J. Inst. Met., 1953, 82, pp. 445–48.Google Scholar
  6. 1956Kle:.
    O.J. Kleppa: “Heat of Formation of Solid and Liquid Binary Alloys of Copper With Cadmium, Indium, Tin, and Antimony at 450 °C,” J. Phys. Chem., 1956, 60, pp. 852–58.CrossRefGoogle Scholar
  7. 1969Str:.
    M.E. Straumanis and L.S. Yu: “Lattice Parameters, Densities, Expansion Coefficients, and Perfection of Structure of Cu and of Cu-In α Phase,” Acta Crystallogr., 1969, 25A, pp. 676–82.ADSGoogle Scholar
  8. 1969Aza:.
    T. Azakami and A. Yazama: “Activities of Arsenic and Indium in Liquid Copper Base Binary Alloys,” J. Min. Metall. Inst. Jpn., 1969, 85, pp. 97–102.Google Scholar
  9. 1971Ita:.
    K. Itagaki, and A. Yazawa: “Measurements of Heats of Mixing in Liquid Copper Binary Alloys,” J. Jpn. Inst. Met., 1971, 35, pp. 383–89.Google Scholar
  10. 1972Jai:.
    K.C. Jain, M. Ellner, and K. Schubert: “On the Phases Occurring Near the Composition Cu64In36,” Z. Metallkd., 1972, 63, pp. 456–61.Google Scholar
  11. 1972Pre:.
    B. Predel and U. Schallner: “Thermodynamic Investigations of the Systems Copper-Gallium, Copper-Indium, Copper-Germanium, and Copper-Tin,” Mater. Sci. Eng., 1972, 10, pp. 249–58.CrossRefGoogle Scholar
  12. 1973Jac:.
    K.T. Jacob and C.B. Alcock: “Activity of Indium in α-Solid Solutions of Cu+In, Au+In, and Cu+Au+In Alloys,” Acta Metall., 1973, 21, pp. 1011–16.CrossRefGoogle Scholar
  13. 1974Jag:.
    K.P. Jagananathan and A. Ghosh: “Thermodynamic Measurements in Liquid Copper-Indium Alloys,” Trans. Ind. Inst. Met., 1974, 27, pp. 298–302.Google Scholar
  14. 1974Bha:.
    D. Bhattacharya and D.B. Masson: “Thermodynamic Properties of α Cu-In Alloys by the Method of Atomic Absorption,” Metall. Trans., 1974, 5, pp. 1357–61.CrossRefGoogle Scholar
  15. 1975Ita:.
    K. Itagaki and A. Yazawa: “Heats of Mixing in Liquid Copper or Gold Binary Alloys,” Trans. Jpn. Inst. Met., 1975, 16, pp. 679–86.Google Scholar
  16. 1975Mas:.
    D.B. Masson and D. Bhattacharya: “The Effect of Excess Entropy on the Activity Coefficient of Indium in α Cu-In Alloys,” Scripta Metall., 1975, 9, pp. 207–10.CrossRefGoogle Scholar
  17. 1976Kan:.
    T. Kang, H.V. Kehaiain, and R. Castanet: “Thermodynamic Study of the Copper-Indium Binary System. I. Calorimetric Study,” J. Calorim. Anal. Therm., 1976, 7, pp. 1–14 (in French).Google Scholar
  18. 1976Vin:.
    G.A. Vinokurova and V.A. Geiderikh: “Thermodynamic Properties of Indium-Copper Alloys,” Zh. Fiz. Khim., 1976, 50, pp. 2782–86 (in Russian).Google Scholar
  19. 1977Kan:.
    T. Kang, H.V. Kehaiain, and R. Castanet: “Thermodynamic Study of the Copper-Indium Binary System. 2. Potentiometric Study,” J. Less-Com. Met., 1977, 53, pp. 153–66.CrossRefGoogle Scholar
  20. 1980Kim:.
    H.S. Kim: “Crystal Structure Studies of Alloys InMn3, γ Cu-In, δ Cu-In, and γ3 Au-Zn,” Ph.D. Dissertation, University of Waterloo, Waterloo, Ontario, Canada, 1980.Google Scholar
  21. 1981Wal:.
    P.C. Wallbrecht, R. Blachnik, and K.C. Mills: “The Heat Capacity and Enthalpy of Some Hume-Rothery Phases Formed by Copper, Silver, and Gold. Part III. Cu+Ga, Ag+Ga, Au+Ga, Cu+In, Ag+In, and Au+In Systems,” Thermochim. Acta, 1981, 48, pp. 69–82.CrossRefGoogle Scholar
  22. 1981Raj:.
    T.P. Rajasekharan and K. Schubert: “Crystal Structure of Cu11In9,” Z. Metallkd., 1981, 72, pp. 275–78.Google Scholar
  23. 1983Kut:.
    I.B. Kutsenok, V.A. Geiderikh, Y.I. Gerasimov, and K.K. Yalkanen: “Study of the Thermodynamic Properties of Indium-Copper Alloys by an Instantaneous EMF Recording Method,” Zh. Fiz. Khim., 1983, 57, pp. 2712–16 (in Russian).Google Scholar
  24. 1986Kep:.
    W. Keppner, R. Wesche, T. Klas, J. Voigt, and G. Schatz: “Studies of Compound Formation at Cu-In, Ag-In, and Au-In Interfaces With Perturbed Gamma-Gamma-Angular Correlations,” Thin Solid Films, 1986, 143, pp. 201–15.CrossRefADSGoogle Scholar
  25. 1989Sub:.
    P.R. Subramanian and D.E. Laughlin: “The Cu-In (Copper-Indium) System,” Bull. Alloy Phase Diagram, 1989, 10, pp. 554–68.CrossRefGoogle Scholar
  26. 1990Kam:.
    K. Kameda: “Activity Measurements of Liquid Cu-In Alloys by EMF Using Zirconia Electrolyte,” J. Jpn. Inst. Metals, 1990, 54, pp. 54–60.Google Scholar
  27. 1991Che:.
    J.S. Chen, E. Kolawa, and M.-A. Nicolet: “Cu/In Deposited at Room Temperature—Morphology, Phases, and Reactions,” Solar Cells, 1991, 30, pp. 451–58.CrossRefGoogle Scholar
  28. 1991Din:.
    A.T. Dinsdale: “SGTE Data for Pure Elements,” CALPHAD, Vol 15, 1991, pp. 317–425.CrossRefGoogle Scholar
  29. 1993Kao:.
    C.R. Kao, A. Bolcavage, S.-L. Chen, S.W. Chen, Y.A. Chang, and A.D. Romig Jr: “Phase Equilibria of the Cu-In System. I. Experimental Investigation,” J. Phase Equilibria, 1993, 14, pp. 22–30.CrossRefGoogle Scholar
  30. 1993Bol:.
    A. Bolcavage, S.W. Chen, C.R. Kao, Y.A. Chang, and A.D. Romig Jr: “Phase Equilibria of the Cu-In System. I. Experimental Investigation,” J. Phase Equilibria, 1991, 14, pp. 14–21.CrossRefGoogle Scholar
  31. 1993Tak:.
    S. Takeuchi, O. Uemura, and S. Ikeda: Proc. Int. Conf. (2nd) Prop. Liq. Met., S. Takeuchi, ed., Taylor and Francis, London, 1993, p. 489.Google Scholar
  32. 1994Oka:.
    H. Okamoto: “Comment on Cu-In (Copper-Indium),” J. Phase Equilibria, 1994, 15, pp. 226–27.CrossRefGoogle Scholar
  33. 1996Shi:.
    J.H. Shim, C.S. Oh, B.J. Lee, and D.N. Lee: “Thermodyanmic Assessment of Cu-Sn System,” Z. Metallkd., 1996, 87, pp. 205–12.Google Scholar
  34. 1999Bah:.
    Z. Bahari, E. Dichi, and B. Legendre: “Heat Content and Heat Capacity of Cu0.7In0.3 From 298K to 1273K,” Z. Metallkd., 1999, 90, pp. 55–59.Google Scholar
  35. 2000Dic:.
    E. Dichi and B. Legendre: “Enthalpy of Formation of Cu0.7In0.3 and Cu0.64In0.36 Phase by Solution Calorimetry,” Z. Metallkd., 2000, 91, pp. 47–50.Google Scholar
  36. 2000Orb:.
    N. Orbey, G.A. Jones, R.W. Birkmire, and T.W.F. Russell: “Copper-Indium Alloy Transformations,” J. Phase Equilibria, 2000, 21, pp. 509–13.Google Scholar

Copyright information

© ASM International 2002

Authors and Affiliations

  • H. S. Liu
    • 1
  • Y. Cui
    • 1
  • K. Ishida
    • 1
  • X. J. Liu
    • 2
  • C. P. Wang
    • 2
  • I. Ohnuma
    • 2
  • R. Kainuma
    • 2
  • Z. P. Jin
    • 3
  1. 1.NICHe (New Industry Creation Hatchery Center)Tohoku UniversitySendaiJapan
  2. 2.Department of Materials Science, Graduate School of EngineeringTohoku UniversitySendaiJapan
  3. 3.Department of Materials Science and EngineeringCentral-South UniversityChangShaP.R.China

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