Growth of well-characterized KY(WO4)2 single crystals using a bridgman-type technique and based on the K2O-Y2O3-WO3 ternary system knowledge

  • C. Goutaudier
  • E. Gallucci
  • G. Boulon
  • M. TH. Cohen-Adad
Basic And Applied Research


KY(WO4)2 single crystals are studied for their civilian applications as laser host materials. In order to determinate the best growth conditions and their reproducibility, the investigation of the K2O-Y2O3-WO3 ternary system was undertaken. It was shown that the compound is not stoichiometric: its stability domain and crystallization field were defined through the study of three isoplethic sections. The preparation of single crystals was performed by a flux method. Their composition depends on the flux one; therefore, these differences do not alter the structure and the spectroscopic properties.


Ternary System Tungsten Trioxide Crystallization Field Constitutional Supercooling Nucleation Frequency 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


  1. 1953Her:.
    C. Herring: Structure and Properties of Solid Surfaces, R. Gomer and C.S. Smith, eds., England, 1953, pp. 5–72.Google Scholar
  2. 1956Tur:.
    D. Turnbull: Solid State Physics, Academic Press, New York, NY, 1956, vol. 3, pp. 225–306.MATHGoogle Scholar
  3. 1966Pas:.
    P. Pascal: Nouveau Traité de Chimie Minérale, Masson et Cie Editeurs, France, 1966.Google Scholar
  4. 1968Bor:.
    S.V. Borisov and R.F. Kletsova: Sov. Phys. Cryst., 1968, vol. 13 (3), p. 420.Google Scholar
  5. 1968Bur:.
    J. Burke: Cinetique des Changements de Phase Dans les Métaux, Masson & Cie, France, 1968, p. 123.Google Scholar
  6. 1993Cla:.
    N. Clavaguera and J.A. Diego: Intermetallic, 1993, vol. 1.Google Scholar
  7. 1993Wen:.
    H. Wenzl, W.A. Oates, and K. Mika: Handbook of Crystal Growth, Hurle, North-Holland, 1993, vol. 1a, p. 123.Google Scholar
  8. 1993Zve:.
    P.G. Zverev, J.T. Murray, R.C. Powell, and T.T. Basiev: Opt. Commun., 1993, vol. 97, p. 59.CrossRefADSGoogle Scholar
  9. 1997Gal:.
    E. Gallucci, C. Goutaudier, M.T. Cohen-Adad, and G. Boulon: Eur. J. Solid State Inorg. Chem., 1997, vol. 34, (10), p. 1107.Google Scholar
  10. 1998Gal:.
    E. Gallucci, C. Goutaudier, M.T. Cohen-Adad, and G. Boulon: Eur. J. Solid State Inorg. Chem., 1998, vol. 35 (6–7), p. 433.CrossRefGoogle Scholar
  11. 2000Gal1:.
    E. Gallucci, C. Goutaudier, B.F. Mentzen, M.T. Cohen-Adad, and G. Boulon: J. Cryst. Growth, 2000, vol. 209, p. 895.CrossRefADSGoogle Scholar
  12. 2000Gal2:.
    E. Gallucci, C. Goutaudier, B.F. Mentzen, M.T. Cohen-Adad, and T. Hansen: J. Alloys Compounds, 2000, vol. 306, p. 227.CrossRefGoogle Scholar

Copyright information

© ASM International 2001

Authors and Affiliations

  • C. Goutaudier
    • 1
  • E. Gallucci
    • 1
  • G. Boulon
    • 1
  • M. TH. Cohen-Adad
    • 1
  1. 1.Laboratoire de Physico-Chimie des Matériaux Luminescents, U.M.R.C.N.R.S. 5620Université Claude Bernard Lyon IVilleurbanne CedexFrance

Personalised recommendations