Thermodynamic assessment of the Fe-Zn system

  • G. Reumont
  • P. Perrot
  • J. M. Fiorani
  • J. Hertz
Basic And Applied Research

Abstract

The Fe-Zn binary system is assessed thermodynamically. A two-sublattice model is adopted to describe the intermetallic compounds, which are treated as nonstoichiometric. A set of parameters consistent with most of the available experimental data on both phase diagram and activities measurements is obtained through optimization. A comparison with previous work is also presented.

Keywords

Gibbs Energy Zinc Activity Intermediate Solid Solution Calculated Solidus Zinc Chemical 

References

  1. 1936Tru:.
    E.C. Truesdale, R.L. Wilcox, and J.L. Rodda: Trans. AIME, 1936, vol. 122, pp. 192–230.Google Scholar
  2. 1937Sch:.
    J. Schramm: Z. Metallkd., 1937, vol. 27 (7), pp. 222–24 (in German).Google Scholar
  3. 1964Spe:.
    G.R. Speich, L. Swell, and H.A. Wriedt: Trans. AIME, 1964, vol. 230, pp. 939–40.Google Scholar
  4. 1967Wri:.
    H.A. Wriedt: Trans. AIME, 1967, vol. 239, pp. 1120–28.Google Scholar
  5. 1972Bud:.
    V.S. Budurov, P. Kovatchev, N. Stojcev, and Z. Kamenova: Z. Metallkd., 1972, vol. 63, pp. 348–50 (in German).Google Scholar
  6. 1973Hul:.
    R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, K.K. Kelley, and D.D. Wagman: Selected Values of the Thermodynamic Properties of Binary Alloys, American Society for Metals, Metals Park, OH, 1973, pp. 905–07.Google Scholar
  7. 1973Kir:.
    G. Kirchner, H. Harvig, K.R. Moquist, and M. Hillert: Arch. Eisenhuttenwes., 1973, vol. 44, pp. 227–34 (in German).Google Scholar
  8. 1974Bas:.
    G.F. Bastin, F.J.J. Van Loo, and G.D. Rieck: Z. Metallkd., 1974, vol. 65, pp. 656–60.Google Scholar
  9. 1978Hil:.
    M. Hillert and M. Jarl: CALPHAD, 1978, vol. 2, pp. 227–38.CrossRefGoogle Scholar
  10. 1979Nis:.
    T. Nishizawa, M. Hasebe, and M. Ko: Acta Metall., 1979, vol. 27, pp. 817–28.CrossRefGoogle Scholar
  11. 1980Gel1:.
    P.J. Gellings, G. Gierman, D. Koster, and J. Kuit: Z. Metallkd., 1980, vol. 71 (2), pp. 70–75.Google Scholar
  12. 1980Gel2:.
    P.J. Gellings, D. Koster, J. Kuit, and T. Franzen: Z. Metallkd., 1980, vol. 71 (3), pp. 150–54.Google Scholar
  13. 1980Reu:.
    P.D. Reutner and H.J. Engell: Arch. Eisenhüttenwes., 1980, vol. 51, pp. 457–62 (in German).Google Scholar
  14. 1981Tom:.
    M. Tomita, A. Azakami, L.M. Timberg, and J.M. Toguri: Trans. Jpn. Inst. Met., 1981, vol. 22, pp. 717–22Google Scholar
  15. 1984Jan:.
    B. Jansson: Ph.D. Thesis, Royal Institute of Technology, Stockholm, 1984.Google Scholar
  16. 1982Dau:.
    J.Y. Dauphin and P. Perrot: Ann. Chim., Sci. Mater., 1982, vol. 7, pp. 681–88 (in French)Google Scholar
  17. 1987Dau:.
    J.Y. Dauphin, P. Perrot, and U.G. Tchissambot: Mem. Et. Sci. Rev. Métall., 1987, vol. 84, pp. 329–36 (in French).Google Scholar
  18. 1988Per:.
    P. Perrot: CALPHAD, 1988, vol. 12, pp. 33–40.CrossRefGoogle Scholar
  19. 1988Pet:.
    S. Petersen, P.S. Spencer, and K. Hack: Thermochim. Acta, 1988, vol. 129, pp. 77–87.CrossRefGoogle Scholar
  20. 1990Ham:.
    M. Hämäläinen, R. Luoma, and P. Taskinen: Thermodynamic Analysis of the System Iron-Lead-Zinc, Helsinki University of Technology, Helsinki, 1990.Google Scholar
  21. 1991Din:.
    A.T. Dinsdale: CALPHAD, 1991, vol. 15, pp. 319–427.CrossRefGoogle Scholar
  22. 1993Bur:.
    P.B. Burton and P. Perrot: Phase Diagram of Binary Iron Alloys, American Society for Metals, Metals Park, OH, 1993, pp. 459–66.Google Scholar
  23. 1993Kow:.
    M. Kowalski and P.J. Spencer: J. Phase Equilibria, 1993, vol. 14, pp. 432–38.CrossRefGoogle Scholar
  24. 1995Nis:.
    T. Nishizawa: J. Phase Equilibria, 1995, vol. 16, pp. 379–89.CrossRefGoogle Scholar
  25. 1995Tak:.
    T. Takayama, S. Shinohara, K. Ishida, and T. Nishizawa: J. Phase Equilibria, 1995, vol. 16, pp. 390–95.CrossRefGoogle Scholar
  26. 1999Cos:.
    A. Costa e Silva, R.R. Avillez, and K. Marques: Z. Metallkd., 1999, vol. 90, pp. 38–43.Google Scholar

Copyright information

© ASM International 2000

Authors and Affiliations

  • G. Reumont
    • 1
  • P. Perrot
    • 1
  • J. M. Fiorani
    • 2
  • J. Hertz
    • 2
  1. 1.Laboratoire de Métallurgie Physique et Génie des Matériaux, UMR CNRS 8517Université de Lille 1Villenuve d’Ascq CedexFrance
  2. 2.Laboratoire de Thermodynamique Métallurgique, UMR CNRS 7555Université de Nancy 1Vandoeuvre les Nancy CedexFrance

Personalised recommendations