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Journal of Phase Equilibria

, 21:432 | Cite as

Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems

  • X. J. Liu
  • C. P. Wang
  • I. Ohnuma
  • R. Kainuma
  • K. Ishida
Basic And Applied Research

Abstract

Thermodynamic assessments have been made for the Cu-Sb and Sb-Zn binary systems by means of the CALPHAD technique. The Gibbs energies of the liquid, bcc, and fcc phases are described by a substitution solution model and a Redlich-Kister formalism. All of the compounds were treated as stoichiometric compounds. Moreover, the liquidus temperatures of the Zn-rich portion in the Sb-Zn system were measured to check the unusual shape reported by previous work. It was confirmed that the liquidus line is not peculiar but smooth. A consistent set of the thermodynamic parameters was optimized to obtain a better fit between calculated results and experimental data including phase diagram and thermodynamic quantities.

Keywords

Gibbs Energy Phase Equilibrium Invariant Reaction Thermodynamic Assessment Calculated Phase Diagram 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© ASM International 2000

Authors and Affiliations

  • X. J. Liu
    • 1
  • C. P. Wang
    • 1
  • I. Ohnuma
    • 1
  • R. Kainuma
    • 1
  • K. Ishida
    • 1
  1. 1.Department of Materials Science, Graduate School of EngineeringTohoku UniversitySendaiJapan

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