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Synthesis of carbon nanotube arrays using ethanol in porous anodic aluminum oxide template

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Chinese Science Bulletin

Abstract

Carbon nanotube (CNT) arrays confined by porous anodic aluminum oxide (AAO) template were synthesized using ethanol as reactant carbon source at low pressure. Images by scanning electron microscope (SEM) and low magnification transmission electron microscopy (TEM) show that these CNTs have highly uniform outer diameter and length, absolutely controlled by the diameter and depth of nano-channel arrays of the AAO. High resolution transmission electron microscopy (HRTEM) imaging indicates that the graphitization of the CNT walls is better than the results reported on this kind of template-based CNT arrays, although it is not so good as that of multiwalled carbon nanotubes (MWCNTs) synthesized by catalysis. CNTs synthesized using acetylene as reactant gas show much less graphitization than those prepared using ethanol by comparing the results of HRTEM and Raman spectroscopy. The etching effects of decomposed OH radicals on the amorphous carbon and the roughness of AAO nano-channel arrays on the CNTs growth were employed to explain the graphitization and growth of the CNTs.

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Authors and Affiliations

  1. Shanghai Institute of Applied Physics, Graduate School of the Chinese Academy of Sciences, 201800, Shanghai, China

    Guojun Yu, Sen Wang, Jinlong Gong, Dezhang Zhu, Suixia He, Yulan Li & Zhiyuan Zhu

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  1. Guojun Yu
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  2. Sen Wang
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  3. Jinlong Gong
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  4. Dezhang Zhu
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  5. Suixia He
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  6. Yulan Li
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  7. Zhiyuan Zhu
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Correspondence to Jinlong Gong.

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Yu, G., Wang, S., Gong, J. et al. Synthesis of carbon nanotube arrays using ethanol in porous anodic aluminum oxide template. Chin.Sci.Bull. 50, 1097–1100 (2005). https://doi.org/10.1360/982004-68

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  • DOI: https://doi.org/10.1360/982004-68

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