Research on Chemical Intermediates

, Volume 23, Issue 9, pp 829–839 | Cite as

Absorption and fluorescence spectra of 9-anthrol and its chemical species in solution

  • Tsuneo Fujii
  • Shozi Mishima
  • Nobuaki Tanaka
  • Osamu Kawauchi
  • Kazuhiko Kodaira
  • Hiromasa Nishikiori
  • Yoshinobu Kawai
Article

Abstract

The absorption, fluorescence, and fluorescence-excitation spectra of 9-anthrol (and/or anthrone) have been observed in various solvents, one of which includes a silicon-aluminium ester (diisobutoxyaluminium triethyl silane[(OBu)2−Al−O−Si−(OEt)3 SAE]). The fluorescence spectra of 9-anthrol shows peak wavelengths at 442 nm in benzene, 454 nm in methanol, 539 nm in triethylamine, and 550 nm in basic solution, which can be assigned to a neutral, a hydrogen-bonded neutral, an ion pair, and an anionic species of 9-anthrol, respectively. In ethanol solution including SAE, on the other hand, a new fluorescence peak appears at 473 nm. This new band originates from a complex formed between 9-anthrol and SAE. The excited-state ion pair is formed through the hydrogen-bonded form in water and the complex form in triethylamine. CNDO/S calculations support the experimental results.

Keywords

Fluorescence Spectrum Basic Solution Anthrone Vibrational Peak Triethyl Silane 

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Copyright information

© Springer 1997

Authors and Affiliations

  • Tsuneo Fujii
    • 1
  • Shozi Mishima
    • 2
  • Nobuaki Tanaka
    • 1
  • Osamu Kawauchi
    • 1
  • Kazuhiko Kodaira
    • 1
  • Hiromasa Nishikiori
    • 1
  • Yoshinobu Kawai
    • 1
  1. 1.Department of Chemistry and Materials Engineering, Faculty of EngineeringShinshu UniversityNaganoJapan
  2. 2.Cooperative Research CenterShinshu UniversityNaganoJapan

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