Skip to main content
SpringerLink
Log in

Introduction of vanadium species in β zeolite by solid-state reaction: spectroscopic study of V speciation and molecular mechanism

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

V-containing β zeolites were prepared by solid-state reaction between V2O5 and β zeolite. The zeolite structure was analysed by XRD and N2 physisorption. The V speciation was studied by chemical analysis and different spectroscopies (FT-IR, 27Al-NMR, UV-Vis, EPR, photoluminescence). After calcination of V2O5-β zeolite mechanical mixtures at 500°C, three kinds of V species were identified: (i) oligomeric vanadates with octahedral V5+ easily removed by treatment with NH4OAc, (ii) isolated vanadyl (V=O)2+ ions in axially distorted octahedral or square pyramidal environment, interacting with framework and/or extraframework Al nuclei and (iii) isolated V5+ in tetrahedral and octahedral environments, localized in framework defect sites. The amount of the latter species is higher when water vapor is present during calcination and when parent β zeolite contains a high concentration of defect sites generated by a strong acid pretreatment. Isolated V5+ are easily reduced to tetrahedral V4+ or to square pyramidal (V=O)2+. Possible models of the mechanism of formation of V species by solid-state reaction and further reduction are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. Notari, Adv. Catal. 41, 253 (1996).

    CAS  Google Scholar 

  2. M. Sasidharan and R. Kumar, J. Catal. 220, 326 (2003).

    Article  CAS  Google Scholar 

  3. A. Thangaraj, S. Sivasanker and P. Ratnasamy, J. Catal. 131, 394 (1991).

    Article  CAS  Google Scholar 

  4. R. J. Saxton, J. G. Zajacek and G. L. Crocco, US Patent 5,374,747 (1994).

  5. C. Perego, A. Carati, P. Ingallina, M. A. Mantegazza and G. Bellussi, Appl. Catal. A 221, 63 (2001).

    Article  CAS  Google Scholar 

  6. C. B. Khouw and M. E. Davis, J. Catal. 151, 77 (1995).

    Article  CAS  Google Scholar 

  7. G. C. Bond, A. J. Sarkany and G. D. Parfitt, J. Catal. 57, 476 (1979).

    Article  CAS  Google Scholar 

  8. G. Centi, F. Trifiro, J. R. Ebner and V. M. Franchetti, Chem. Rev. 88, 55 (1988).

    Article  CAS  Google Scholar 

  9. M. S. Rigutto and H. van Bekkum, Appl. Catal. 68, L1 (1991).

    Article  CAS  Google Scholar 

  10. G. Centi, S. Perathoner, F. Trifiro, A. Aboukais, C. F. Aissi and M. Guelton, J. Phys. Chem. 96, 2617 (1992).

    Article  CAS  Google Scholar 

  11. P. R. H. Rao, A. V. Ramaswamy and P. Ratnasamy, J. Catal. 137, 225 (1992).

    Article  CAS  Google Scholar 

  12. B. I. Whittington and J. R. Anderson, J. Phys. Chem. 97, 1032 (1993).

    Article  CAS  Google Scholar 

  13. K. M. Reddy, I. Moudrakovski and A. Sayari, J. Chem. Soc., Chem. Commun., 1491 (1994).

  14. J. M. Lopez Nieto, Topics Catal. 15, 189 (2001).

    Article  Google Scholar 

  15. T. Sen, M. Chatterjee and S. Sivasanker, J. Chem. Soc., Chem. Commun., 207 (1995).

  16. A. Tuel and Y. Ben Taârit, Appl. Catal. 102, 201 (1993).

    Article  CAS  Google Scholar 

  17. El-M. El-Malki, B. Manohar, A. Davidson, P. Massiani, S. Sivasanker and M. Che, J. Chim. Phys. 94, 1848 (1997).

    CAS  Google Scholar 

  18. T. Sen, V. Ramaswamy, S. Ganapathy, P. R. Rajamohanan and S. Sivasanker, J. Phys. Chem. 100, 3809 (1996).

    Article  CAS  Google Scholar 

  19. P. R. H. Rao and A. V. Ramaswamy, Appl. Catal. A 93, 123 (1993).

    Article  CAS  Google Scholar 

  20. C. Ferrini and H. W. Kouwenhoven, Stud. Surf. Sci. Catal. 55, 53 (1990).

    Google Scholar 

  21. B. Kraushaar and J. H. C. van Hooff, Catal. Lett. 1, 81 (1988).

    Article  CAS  Google Scholar 

  22. S. Dzwigaj, M. J. Peltre, P. Massiani, A. Davidson, M. Che, T. Sen and S. Sivasanker, J. Chem. Soc. Chem. Commun., 87 (1998).

  23. S. Dzwigaj, P. Massiani, A. Davidson and M. Che, J. Mol. Catal. A 155, 169 (2000).

    Article  CAS  Google Scholar 

  24. J. A. Rabo, M. L. Poutsma and G. W. Skeels, in: Proceedings of the 5th International Congress on Catalysis, J. W. Hightower (Ed.), p. 1353. North-Holland, New York, NY (1973).

    Google Scholar 

  25. A. Clearfield, C. H. Saldarriaga and R. C. Buckley, in: Proceedings of the 3rd International Conference on Molecular Sieves, J. B. Uytterhoeven (Ed.), p. 241. University of Leuwen Press, Leuven (1973).

    Google Scholar 

  26. H. G. Karge, Stud. Surf. Sci. Catal. 105, 1901 (1997).

    Google Scholar 

  27. C. Stolz, A. Sauvage, P. Massiani and R. Kramer, Appl. Catal. A 167, 113 (1998).

    Article  CAS  Google Scholar 

  28. J. Weitkamp, S. Ernst, T. Bock, A. Kiss, P. Kleinschmit, Stud. Surf. Sci. Catal. 94, 278 (1995).

    CAS  Google Scholar 

  29. G. L. Price and V. Kanazirev, J. Catal. 126, 267 (1990).

    Article  CAS  Google Scholar 

  30. P. Mériaudeau and C. Naccache, Appl. Catal. 73, L13 (1991).

    Article  Google Scholar 

  31. J. L. G. Fierro, J. C. Conesa and A. Lopez Agudo, J. Catal. 108, 334 (1987).

    Article  CAS  Google Scholar 

  32. R. Haase, H. G. Jerschkewitz, G. Ohlmann, J. Richter-Mendau and J. Scheve, Stud. Surf. Sci. Catal.. 3, 615 (1979).

    CAS  Google Scholar 

  33. A. V. Kucherov and A. A. Slinkin, Zeolites 7, 583 (1987).

    Article  CAS  Google Scholar 

  34. A. V. Kucherov, A. A. Slinkin, G. K. Beyer and G. Borbely, J. Chem. Soc. Faraday Trans. 85, 2737 (1989).

    Article  CAS  Google Scholar 

  35. M. Huang, S. Yuan, Y. Li and Q. Wang, Zeolites 10, 772 (1990).

    Article  CAS  Google Scholar 

  36. R. Dimitrova, Y. Neinska, M. Mihalyi, G. Pal-Borbely and M. Spassova, Appl. Catal. A 266, 123 (2004).

    Article  CAS  Google Scholar 

  37. El-M. El-Malki, S. Dzwigaj, P. Massiani, A. Davidson and M. Che, in: Proceedings of the 12th International Zeolite Conference, M. M. J. Treacy, B. K. Marcus, M. E. Bischer and J. B. Higgins (Eds), p. 2171 (1999).

  38. D. M. Templeton, F. Ariese, R. Cornelis, L. G. Danielson, H. Muntan, H. P. Van Leeuwen and R. Lobinski, Pure Appl. Chem. 72, 1453 (2000).

    Article  CAS  Google Scholar 

  39. K. Dyrek, A. Madej, E. Mazur and A. Rokosz, Coll. Surf. 45, 135 (1990).

    Article  CAS  Google Scholar 

  40. S. Dzwigaj, El-M. El-Malki, M. J. Peltre, P. Massiani, A. Davidson and M. Che, Top. Catal. 11–12, 379 (2000).

    Article  Google Scholar 

  41. El-M. El-Malki, PhD Thesis. University Pierre & Marie Curie, Paris (1998).

  42. M. Maache, A. Janin, J. C. Lavalley, J. F. Joly and E. Benazzi, Zeolites 13, 419 (1993).

    Article  CAS  Google Scholar 

  43. A. Jia, P. Massiani and D. Barthomeuf, J. Chem. Soc. Faraday Trans. 89, 3659 (1993).

    Article  CAS  Google Scholar 

  44. R. B. Borade and A. Clearfield, J. Phys. Chem. 96, 6729 (1992).

    Article  CAS  Google Scholar 

  45. I. Kiricsi, C. Flego, G. Pazzuconi, W. O. Parker Jr., R. Millini, C. Perego and G. Bellussi, J. Phys. Chem. 98, 4627 (1994).

    Article  CAS  Google Scholar 

  46. K. Yamagishi, S. Namba and T. Yashima, J. Phys. Chem. 95, 872 (1991).

    Article  CAS  Google Scholar 

  47. R. M. Dessau, K. D. Schmitt, G. T. Kerr, G. L. Woolery and L. B. Alemany, J. Catal. 104, 484 (1987).

    Article  CAS  Google Scholar 

  48. B. Kraushaar, J. W. De Haan and J. H. C. van Hooff, J. Catal. 109, 407 (1988).

    Article  Google Scholar 

  49. El-M. El-Malki, R. van Santen and W. H. M. Sachtler, J. Phys. Chem. B 103, 4611 (1999).

    Article  CAS  Google Scholar 

  50. E. Bourgeat-Lami, P. Massiani, F. Di Renzo, F. Espiau and F. Fajula, Appl. Catal. 72, 139 (1991).

    Article  CAS  Google Scholar 

  51. A. B. P. Lever, Inorganic Electronic Spectroscopy. Elsevier, New York, NY (1984).

    Google Scholar 

  52. G. Rasch, H. Bogel and C. Rein, Z. Phys. Chem. 259, 955 (1978).

    CAS  Google Scholar 

  53. G. Lischke, W. Hanke, H. G. Jerschkewitz and G. Ohlmann, J. Catal. 91, 54 (1985).

    Article  CAS  Google Scholar 

  54. L. Brus, J. Phys. Chem. 90, 2555 (1986).

    Article  CAS  Google Scholar 

  55. T. Blasco, P. Concepcion, J. M. Lopez Nieto and J. Perez-Pariente, J. Catal. 152, 1 (1995).

    Article  CAS  Google Scholar 

  56. J. Kornatowski, B. Wichterlova, J. Jirkovsky, E. Loffler and W. Pilz, J. Chem. Soc., Faraday Trans. 92, 1067 (1996).

    Article  CAS  Google Scholar 

  57. M. Morey, A. Davidson, H. Eckert and G. Stucky, Chem. Mater. 8, 486 (1996).

    Article  CAS  Google Scholar 

  58. Z. Luan, J. Xu, H. He, J. Klinowski and L. Kevan, J. Phys. Chem. 100, 19595 (1996).

  59. J. Selbin, Chem. Rev. 65, 153 (1965).

    Article  CAS  Google Scholar 

  60. N. Gharbi, C. Sanchez, J. Livage, J. Lemerle, L. Nejem and J. Lefebvre, Inorg. Chem. 21, 2758 (1982).

    Article  CAS  Google Scholar 

  61. E. C. Alyea and D. C. Bradley, J. Chem Soc. A. 16, 2330 (1969).

    Article  Google Scholar 

  62. D. C. Crans, H. Chen and R. A. Felty, J. Am. Chem. Soc. 114, 4543 (1992).

    Article  CAS  Google Scholar 

  63. F. Cartan and C. N. Caughlan, J. Phys. Chem. 64, 1756 (1960).

    Article  CAS  Google Scholar 

  64. M. Anpo, M. Sunamoto and M. Che, J. Phys. Chem. 93, 1187 (1989).

    Article  CAS  Google Scholar 

  65. M. Anpo, M. Sunamoto, T. Fujii, H. H. Patterson and M. Che, Res. Chem. Intermed. 11, 245 (1989).

    Article  CAS  Google Scholar 

  66. M. Anpo, I. Tanahashi and Y. Kubokawa, J. Phys. Chem. 84, 3440 (1980).

    Article  CAS  Google Scholar 

  67. M. Anpo and M. Che, Adv. Catal. 44, 119 (1999).

    CAS  Google Scholar 

  68. H. H. Patterson, J. Cheng, S. Despres, M. Sunamoto and M. Anpo, J. Phys. Chem. 95, 8813 (1991).

    Article  CAS  Google Scholar 

  69. M. Iwamoto, H. Furukawa, K. Matsukami, T. Takenaka and S. Kagawa, J. Am. Chem. Soc. 105, 3719 (1983).

    Article  CAS  Google Scholar 

  70. M. Anpo, S. G. Zhang, H. Mishima, M. Matsuoka and H. Yamashita, Catal. Today 39, 159 (1997).

    Article  CAS  Google Scholar 

  71. S. Dzwigaj, M. Matsuoka, R. Franck, M. Anpo and M. Che, J. Phys. Chem. B 102, 6309 (1998).

    Article  CAS  Google Scholar 

  72. S. Dzwigaj, M. Matsuoka, R. Franck, M. Anpo and M. Che, J. Phys. Chem. B 104, 6012 (2000).

    Article  CAS  Google Scholar 

  73. S. Dzwigaj, M. Matsuoka, M. Anpo and M. Che, Res. Chem. Intermed. 29, 665 (2003).

    Article  CAS  Google Scholar 

  74. A. Kahn, J. Livage and R. Collongues, Phys. Status Solidi A 26, 175 (1974).

    Article  CAS  Google Scholar 

  75. G. Busca, G. Centi, L. Marchetti and F. Trifiro, Langmuir 2, 568 (1986).

    Article  CAS  Google Scholar 

  76. B. A. Goodman and J. B. Raynor, Adv. Inorg. Chem. Radiochem. 13, 135 (1970).

    CAS  Google Scholar 

  77. C. J. Ballhausen and H. B. Gray, Inorg. Chem. 1, 111 (1962).

    Article  CAS  Google Scholar 

  78. F. E. Mabbs and D. J. Machin, Magnetism and Transition Metal Complexes. Chapman and Hall, London (1973).

    Google Scholar 

  79. V. K. Sharma, A. Wokaun and A. Baiker, J. Phys. Chem. 90, 2715 (1986).

    Article  CAS  Google Scholar 

  80. U. Scharf, M. Schraml-Marth, A. Wokaun and A. Baiker, J. Chem. Soc. Faraday Trans. 87, 3299 (1991).

    Article  CAS  Google Scholar 

  81. C. E. Sass, X. Chen and L. Kevan, J. Chem. Soc. Faraday Trans. 86, 189 (1990).

    Article  CAS  Google Scholar 

  82. M. Che, B. Canosa and A. R. Gonzalez-Elipe, J. Phys. Chem. 90, 618 (1986).

    Article  CAS  Google Scholar 

  83. S. Digregorio, M. Greenblatt, J. H. Pifer and M. D. Sturge, J. Chem. Phys. 76, 2931 (1982).

    Article  CAS  Google Scholar 

  84. E. Fritsch, F. Babonneau, C. Sanchez and G. Calas, J. Non-Cryst. Solids 92, 282 (1987).

    Article  CAS  Google Scholar 

  85. C. E. Holloway, F. E. Mabbs and W. R. Smail, J. Chem. Soc. A 12, 2980 (1968).

    Article  Google Scholar 

  86. G. F. Kokoszka, H. C. Allen and G. Gordon, Inorg. Chem. 5, 91 (1966).

    Article  CAS  Google Scholar 

  87. J. Dedecek and B. Wichterlova, J. Phys. Chem. B 103, 1462 (1999).

    Article  CAS  Google Scholar 

  88. D. Hoenicke and J. Xu, J. Phys. Chem. 92, 4699 (1988).

    Article  CAS  Google Scholar 

  89. H. Knoezinger and E. Taglauer, Catalysis 10, 1 (1993).

    Article  CAS  Google Scholar 

  90. O. Glemser and H. G. Wendlandt, Angew. Chem. 75, 949 (1963).

    Article  Google Scholar 

  91. J. Leyrer, R. Margraf, E. Taglauer and H. Knoezinger, Surface Sci. 201, 603 (1988).

    Article  CAS  Google Scholar 

  92. E. Z. Muller, Chem. Ind. Koll. 8, 302 (1911).

    Article  CAS  Google Scholar 

  93. N. L. Yannopoulos, J. Phys. Chem. 72, 3293 (1968).

    Article  CAS  Google Scholar 

  94. O. Glemser and A. Muller, Z. Anorg. Allg. Chem. 325, 220 (1963).

    Article  CAS  Google Scholar 

  95. K. Yamagishi, S. Namba and T. Yashima, J. Catal. 121, 47 (1990).

    Article  CAS  Google Scholar 

  96. P. Wu and T. Komatsu, J. Phys. Chem. 99, 10923 (1995).

  97. S. Namba, K. Yamagishi and T. Yashima, Chem. Lett., 1109 (1987).

  98. P. R. H. Rao, A. A. Belhekar, S. H. Egde, A. V. Ramaswamy and P. Ratnasamy, J. Catal. 141, 595 (1993).

    Article  CAS  Google Scholar 

  99. B. I. Whittington and J. R. Anderson, J. Phys. Chem. 95, 3306 (1991).

    Article  CAS  Google Scholar 

Download references

Author information

Author notes

  1. El-Mekki El-Malki

    Present address: Exxon Mobil Research and Engineering Company, 1545 Route 22 East, Clinton Township, Annandale, NJ, 08801, USA

Authors and Affiliations

  1. Laboratorie de Réactivité de Surface, UMR 7609 CNRS, Université Pierre et Marie Curie, casier 178, 4 place Jussieu, 75252, Paris Cedex 05, France

    El-Mekki El-Malki & Pascale Massiani

  2. Institut Universitaire de France, Paris, France

    Michel Che

Authors
  1. El-Mekki El-Malki
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pascale Massiani
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Michel Che
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Pascale Massiani.

Rights and permissions

Reprints and permissions

About this article

Cite this article

El-Malki, EM., Massiani, P. & Che, M. Introduction of vanadium species in β zeolite by solid-state reaction: spectroscopic study of V speciation and molecular mechanism. Res Chem Intermed 33, 749–774 (2007). https://doi.org/10.1163/156856707782169327

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1163/156856707782169327

Keywords

Search

Navigation