Research on Chemical Intermediates

, Volume 26, Issue 5, pp 483–488 | Cite as

Formation of new monomeric Pd(III) complex species with 8-aminoquinoline

  • M. Nichkova
  • M. Mitewa
Article
  • 41 Downloads

Abstract

By means of EPR and magnetochemical methods the formation of 3 new Pd(III) complex species is proved resulting from the reaction of PdCl4 2− and 8-aminoquinoline (8-AQ) in basic (aqueous or aqueous-methanolic) medium. Elemental analysis, visible and IR data for the complexes are also obtained.

Keywords

Complex Species Elemental Analysis Data Tetramethyl Ammonium Tetramethyl Ammonium Hydroxide Magnetochemical Measurement 

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References

  1. 1.
    M. Mitewa and G. Gencheva, Res. Chem. Intermed. 18, 115 (1992).Google Scholar
  2. 2.
    M. Mitewa, Coord. Chem. Revs. 140, 1 (1995).CrossRefGoogle Scholar
  3. 3.
    M. Mitewa, G. Gencheva, and N. Mincheva, Proc. 15th Conf. Coord. Chem. In: G. Ondrejovich and A. Sirota, Current Trends in Coordination Chemistry, Slovak Technical University Press, Bratislava, 1995, p. 145.Google Scholar
  4. 4.
    N. Mincheva, G. Gencheva, M. Mitewa, G. Gochev, and D. Mechandjiev, Synth. React. Inorg. Met.-Org. Chem. 27, 1191 (1997).CrossRefGoogle Scholar
  5. 5.
    N. Mincheva, D. Mehankjiev, and M. Mitewa, J. Chem. Research (S) 434 (1998).Google Scholar
  6. 6.
    G. Gencheva, Sv. Bobev, and M. Mitewa, Res. Chem. Intermed. 23, 101 (1997).Google Scholar
  7. 7.
    M. Mitewa, G. Gencheva, Sv. Bobev, G. Gochev, D. Mechandjiev and I. Wawer, Res. Chem. Intermed. 25, 431 (1999).Google Scholar
  8. 8.
    J.C. Fanning and L.T. Taylor, J. Inorg. Nucl. Chem. 27, 2217 (1965).CrossRefGoogle Scholar
  9. 9.
    V.K. Gustin and T.R. Sweet, Anal. Chem. 35, 44 (1963).CrossRefGoogle Scholar
  10. 10.
    K.A. Jensen and P.H. Nielsen, Acta Chem. Scand. 18, 1 (1964).Google Scholar
  11. 11.
    H.A. Hudalli, J.V. Kingston, and H.A. Tayim, Inorg. Chem. 18, 1391 (1979).CrossRefGoogle Scholar
  12. 12.
    P. Umapathy, R.A. Harnesswala, and C.S. Dorai, Polyhedron 4, 1595 (1985).CrossRefGoogle Scholar
  13. 13.
    C. Engelter, G.E. Jackson, C.L. Knight, and D.A. Thornton, J. Coord. Chem. 20, 289 (1989).CrossRefGoogle Scholar
  14. 14.
    A. Tressaud, S. Khairon, J.M. Dance, and P. Hagenmuller, Z. Anorg. Allg. Chem. 517, 43 (1984).CrossRefGoogle Scholar
  15. 15.
    A. MacAuley and T.W. Whitecombe, Inorg. Chem. 27, 3090 (1988).CrossRefGoogle Scholar

Copyright information

© VSP 2000

Authors and Affiliations

  • M. Nichkova
    • 1
  • M. Mitewa
    • 1
  1. 1.Department of ChemistryUniversity of SofiaSofiaBulgaria

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