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Ni-exchanged AlSBA-15 mesoporous materials as outstanding catalysts for ethylene oligomerization

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Abstract

Ni-exchanged mesoporous materials with SBA-15 topology were prepared by post-synthesis alumination of SBA-15 silica with sodium aluminate at room temperature, followed by ion exchange with nickel. Exploration of various parameters resulted in a simple preparation method for catalysts with perfect pore system and aluminium tetrahedrally coordinated in the silica framework for Si/Al > 6. These properties were proved by using appropriate characterisation techniques, including powder X-ray diffraction, N2 sorption, TEM, and 27Al MAS NMR. Ni-AlSBA-15 exhibited outstanding catalytic properties in the oligomerization reaction of ethylene performed at 150 ∘C and 3.5 MPa. Activity up to 175 g of oligomers per gram of catalyst per hour was the highest reported to date with Ni-based solid catalysts.

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Authors and Affiliations

  1. Institut Charles Gerhardt Montpellier, UMR 5253, CNRS-UM2-ENSCM-UM1, Matériaux Avancés pour la Catalyse et la Santé, 8 rue de l’Ecole Normale, 34296, Montpellier Cedex 5, France

    R.D. Andrei, C. Cammarano, F. Fajula & V. Hulea

  2. Faculty of Chemical Engineering and Environment Protection, Technical University of Iasi, 71 D. Mangeron Ave., 700050, Iasi, Romania

    R.D. Andrei & M.I. Popa

  3. Faculty of Chemistry, University of Craiova, 165 Calea Bucuresti, 200144, Craiova, Romania

    M. Mureseanu

Authors
  1. R.D. Andrei
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  2. M. Mureseanu
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  3. M.I. Popa
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  4. C. Cammarano
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  5. F. Fajula
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  6. V. Hulea
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Correspondence to V. Hulea.

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Andrei, R., Mureseanu, M., Popa, M. et al. Ni-exchanged AlSBA-15 mesoporous materials as outstanding catalysts for ethylene oligomerization. Eur. Phys. J. Spec. Top. 224, 1831–1841 (2015). https://doi.org/10.1140/epjst/e2015-02502-0

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  • DOI: https://doi.org/10.1140/epjst/e2015-02502-0

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