The European Physical Journal Special Topics

, Volume 224, Issue 9, pp 1817–1830 | Cite as

Methanol and ethanol conversion into hydrocarbons over H-ZSM-5 catalyst

  • S. Hamieh
  • C. Canaff
  • K. Ben Tayeb
  • M. Tarighi
  • S. Maury
  • H. Vezin
  • Y. Pouilloux
  • L. Pinard
Regular Article
Part of the following topical collections:
  1. Advances in Design and Modeling of Porous Materials

Abstract

Ethanol and methanol are converted using H-ZSM-5 zeolite at 623 K and 3.0 MPa into identical hydrocarbons (paraffins, olefins and aromatics) and moreover with identical selectivities. The distribution of olefins as paraffins follows the Flory distribution with a growth probability of 0.53. Regardless of the alcohol, the catalyst lifetime and selectivity into hydrocarbons C3+ are high in spite of an important coke content. The coke that poisons the Brønsted acid sites without blocking their access is composed in part of radical polyalkylaromatics. The addition of hydroquinone, an inhibitor of radicals, to the feed, provokes an immediate catalyst deactivation.

Keywords

Zeolite MeOH Electron Paramagnetic Resonance EtOH European Physical Journal Special Topic 

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Copyright information

© EDP Sciences and Springer 2015

Authors and Affiliations

  • S. Hamieh
    • 1
  • C. Canaff
    • 1
  • K. Ben Tayeb
    • 2
  • M. Tarighi
    • 1
  • S. Maury
    • 3
  • H. Vezin
    • 2
  • Y. Pouilloux
    • 1
  • L. Pinard
    • 1
  1. 1.IC2MP, UMR 7285 CNRS – Université de PoitiersTSA 51106France
  2. 2.LASIR, UMR 8516 CNRS – Université de Lille 1Villeneuve d’Ascq CedexFrance
  3. 3.IFP Energies Nouvelles, Rond-point de l’échangeur de SolaizeSolaizeFrance

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