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Electrokinetic and hydrodynamic properties of charged-particles systems

From small electrolyte ions to large colloids

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Abstract

Dynamic processes in dispersions of charged spherical particles are of importance both in fundamental science, and in technical and bio-medical applications. There exists a large variety of charged-particles systems, ranging from nanometer-sized electrolyte ions to micron-sized charge-stabilized colloids. We review recent advances in theoretical methods for the calculation of linear transport coefficients in concentrated particulate systems, with the focus on hydrodynamic interactions and electrokinetic effects. Considered transport properties are the dispersion viscosity, self- and collective diffusion coefficients, sedimentation coefficients, and electrophoretic mobilities and conductivities of ionic particle species in an external electric field. Advances by our group are also discussed, including a novel mode-coupling-theory method for conduction-diffusion and viscoelastic properties of strong electrolyte solutions. Furthermore, results are presented for dispersions of solvent-permeable particles, and particles with non-zero hydrodynamic surface slip. The concentration-dependent swelling of ionic microgels is discussed, as well as a far-reaching dynamic scaling behavior relating colloidal long- to short-time dynamics.

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Authors and Affiliations

  1. Institute of Complex Systems (ICS-3), Research Centre Jülich, 52425, Jülich, Germany

    G. Nägele

  2. Institut für Theoretische Physik II: Weiche Materie, Heinrich-Heine-Universität Düsseldorf, 40225, Düsseldorf, Germany

    M. Heinen

  3. FaMAF, Universidad Nacional de Córdoba, and IFEG-CONICET, Ciudad Universitaria, X5000HUA, Córdoba, Argentina

    A. J. Banchio

  4. División de Ciencias e Ingenierías, Universidad de Guanajuato Campus León, 37150, León, México

    C. Contreras-Aburto

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  1. G. Nägele
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  2. M. Heinen
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  4. C. Contreras-Aburto
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Nägele, G., Heinen, M., Banchio, A.J. et al. Electrokinetic and hydrodynamic properties of charged-particles systems. Eur. Phys. J. Spec. Top. 222, 2855–2872 (2013). https://doi.org/10.1140/epjst/e2013-02062-3

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