Biosynthesised ZnO : Dy3+ nanoparticles: Biodiesel properties and reusable catalyst for N-formylation of aromatic amines with formic acid

  • L. S. Reddy Yadav
  • M. Raghavendra
  • K. H. Sudheer Kumar
  • N. Dhananjaya
  • G. Nagaraju
Regular Article
  • 8 Downloads

Abstract.

ZnO nanoparticles doped with trivalent dysprosium ions (Dy3+) were prepared through the green combustion technique using E. tirucalli plant latex as a fuel. The fundamental and optical properties of the samples are examined via the X-ray diffraction, FTIR, UV-visible analytical methods and morphology by scanning electron microscope and transmission electron microscope. Rietveld refinement results show that the ZnO : Dy3+ were crystallized in the wurtzite hexagonal structure with space group P63mc (No. 186). The average particle size of ZnO : Dy3+ prepared with the different concentration of latex was found to be in the range 30-38nm, which is also confirmed by TEM analysis. A rapid and convenient method for the one-pot preparation of N-formamide derivatives aromatic amines and amino acid esters has been developed using Dy3+ doped ZnO as a catalytic agent. This method provides an efficient and much improved modification over reported protocols regarding yield, clean and work-up procedure milder reaction conditions. In this work, Pongamiapinnata oil was recycled for the preparation of biodiesel via Dy3+ doped ZnO as a catalytic agent.

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Copyright information

© Società Italiana di Fisica and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • L. S. Reddy Yadav
    • 1
    • 2
  • M. Raghavendra
    • 2
  • K. H. Sudheer Kumar
    • 1
  • N. Dhananjaya
    • 3
  • G. Nagaraju
    • 2
  1. 1.Department of ChemistryB.M.S. Institute of TechnologyBangaloreIndia
  2. 2.Department of ChemistrySiddaganga Institute of TechnologyTumkurIndia
  3. 3.Department of PhysicsB.M.S. Institute of TechnologyBangaloreIndia

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